Abstract
To explore the silicate lattice-based nanophosphors, a series of Eu3+-doped Z2Si3O8 (Z = Mg, Ca and Sr) materials were prepared by sol–gel procedure. The metal nitrates and silica powder were used as precursor components for the synthesis of these luminescent materials. Photoluminescence (PL) emission spectra, powder X-ray diffraction (PXRD), energy-dispersive X-ray spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM) spectroscopic techniques were applied for the characterization of the fabricated materials. Three peaks were observed at 589, 613 and 650–652 nm corresponding to 5D0 → 7F1-3 transition in PL emission spectra. Upon 395 nm excitation and at 0.03 mol Eu3+, these nanophosphors displayed optimum photoluminescence with the most intense peak analogous to 5D0 → 7F2 transition of dopant ion. The as-prepared phosphor materials were re-heated at 1050 and 1150 °C to observe the consequences of higher temperatures on the emission intensity and crystal lattice. XRD analysis confirmed that all the synthesized materials were of crystalline nature, and the crystallinity was observed to be improved by increasing the temperature. In the FTIR spectrum, peaks at 483 and 610 cm−1 proved the existence of SiO4 group in Ca2Si3O8, and the peak centered at 417 cm−1 confirmed the presence of MgO6 octahedral in Mg2Si3O8 materials. TEM images were used to determine the particle size (13–35 nm) and to study the three-dimensional structure of nanophosphor materials. The experimental studies indicate that these materials may be promising as red-emitting nanophosphors for white light-emitting diodes.
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Lee SP, Chan TS, Chen TM. Novel reddish-orange-emitting BaLa2Si2S8:Eu2+ thiosilicate phosphor for LED lighting. ACS Appl Mater Interfaces. 2015;7(1):40.
Tian B, Chen B, Tian Y, Li X, Zhang J, Sun J, Zhong H, Cheng L, Fu S, Zhong H, Wang Y, Zhang X, Xia H, Hua R. Excitation pathway and temperature dependent luminescence in color tunable Ba5Gd8Zn4O21:Eu3+ phosphors. J Mater Chem C. 2013;1(12):2338.
Tian Y, Chen B, Hua R, Sun J, Cheng L, Zhong H, Li X, Zhang J, Zheng Y, Yu T, Huang L, Yu H. Optical transition, electron-phonon coupling and fluorescent quenching of La2(MoO4)3:Eu3+ phosphor. J Appl Phys. 2011;109(5):053511.
Singh V, Rai VK, Al-Shamerya K, Nordmann J, Haase M. NIR to visible in Er3+/Yb3+ co-doped CaYAl3O7 phosphor obtained by solution combustion process. J Lumin. 2011;131(12):2679.
Chang C, Li W, Huang X, Wang Z, Chen X, Qian X, Guo R, Ding Y, Mao D. Photoluminescence and afterglow behavior of Eu2+, Dy3+ and Eu3+, Dy3+ in Sr3Al2O6 matrix. J Lumin. 2010;130(3):347.
Dutta DP, Tyagi AK. Inorganic phosphor materials for soid state white light generation. Solid State Phenom. 2009;155:113.
Singh D, Tanwar V, Simantilke AP, Mari B, Kadyan PS, Singh I. Rapid synthesis and photoluminescent characterization of MAl2O4: Eu2+, Dy3+(M = Ca/Ca + Ba/Ca + Mg) blue nanophosphors for white lighting display applications. Adv Mater Lett. 2016;7(1):47.
Liu B, Ding D, Liu Z, Chen F, Xia C. Synthesis and electrical conductivity of various melilite-type electrolytes Ln1+xSr1−xGa3O7+x/2. Solid State Ion. 2011;191(1):68.
Yu H, Yu X, Xu X, Jiang T, Yang P, Jiao Q, Zhou D, Qiu J. Excitation band extended in CaYAl3O7:Tb3+ phosphor by Ce3+ co-doped for NUV light-emitting diodes. Opt Commun. 2014;317:78.
Mahakhode JG, Dhoble SJ, Joshi CP, Moharil SV. Combustion synthesis of phosphor for plasma display panels. J Alloy Compd. 2007;438(1–2):293.
Mo F, Zhou L, Pang Q, Lan Y, Liang Z. Synthesis and luminescent properties of Zn0.890Nb2O6:Eu 3+0.05 , Bi 3+0.005 , M +0.055 (M = Li, Na, K) phosphors. Curr Appl Phys. 2013;13(2):331.
Bandi VR, Nien YT, Lu TH, Chen IG. Effect of calcination and concentration on luminescence properties of Novel Ca3Y2Si3O12: Eu phosphor. J Am Ceram Soc. 2009;92(12):2953.
Kadukar MR, Yawalkar PW, Choithrani R, Dhoble SJ. Mechnoluminescence, thermoluminescence, photoluminescence studies on Ca3Y2Si3O12:RE3+ (RE3+ = Dy3+ and Eu3+) phosphors. J BioluminChemilumin. 2015;30(8):1219.
Park JK, Choi KJ, Kang HG, Kim JM, Kim CH. Silicates phosphors for white LEDs identified through combinatorial chemistry. Electrochem Solid-State Lett. 2007;10(2):J15.
Thakur J, Dutta DP, Bagla H, Tyagi AK. Effect of host structure and concentration on the luminescence of Eu3+ and Tb3+ in borate phosphors. J Am Ceram Soc. 2012;95(2):696.
Dutta DP, Roy M, Tyagi AK. Dual function of rare earth doped nano Bi2O3: white light emission and photocatalytic properties. Dalton Trans. 2012;41(34):10238.
Singh D, Sheoran S, Singh J. Optical characterization of Eu3+ doped MLSiO4 (M = Ca, Sr, Ba and L = Mg) phosphor materials for display devices. J Mater Sci: Mater Electron. 2018;29(1):294.
Kumada N, Yanagida S, Takei T, Hong B. Hydrothermal synthesis and crystal structure of new red phosphors, KNaMF7:Mn4+ (M: Nb, Ta). Mater Res Bull. 2019;115:170.
Chen Y, Wang M, Wang J, Wu M, Wang C. A high color purity red emitting phosphor CaYAlO4:Mn4+ for LEDs. J Solid State Light. 2014;1:15.
Singh D, Kadyan S. Synthesis and optical characterization of trivalent europium doped M4Al2O9 (M = Y, Gd and La) nanomaterials for display applications. J Mater Sci: Mater Electron. 2017;28(15):11142.
Singh D, Tanwar V, Samantilleke AP, Mari B, Bhagwan S, Singh KC, Kadyan PS, Singh I. Synthesis of Sr(1-x-y)Al4O7:Eu 2+x , Ln 3+y (Ln = Dy, Y, Pr) nanophosphors using rapid gel combustion process and their down conversion characteristics. Electron Mater Lett. 2017;13(3):222.
Rao RP. Preparation and characterization of fine-grain yttrium-based phosphors by sol–gel process. J Electrochem Soc. 1996;143(1):189.
Singh D, Sheoran S. Synthesis and luminescent characteristics of M3Y2Si3O12:Eu3+ (M = Ca, Mg, Sr and Ba) nanomaterials for display applications. J Mater Sci: Mater Electron. 2016;27(12):12707.
Singh D, Kadyan S, Bhagwan S. Structural and photoluminescence characteristics of M3Al5O12:Eu3+ (M = Y, Gd and La) nanophosphors for optoelectronic applications. J Mater Sci: Mater Electron. 2017;28(18):13478.
Hertle E, Chepyga L, Batentschuk M, Zigan L. Influence of codoping on the luminescence properties of YAG: Dy for high temperature phosphor thermometry. J Lumin. 2017;182:200.
Matos MG, Pereira PFS, Calefi PS, Ciuffi KJ, Nassar EJ. Preparation of a GdCaAl3O7 matrix by the non-hydrolytic sol–gel route. J Lumin. 2009;129(10):1120.
Singh J, Baitha PK, Manam J. Influence of heat treatment on the structural and optical properties of SrGd2O4:Eu3+ phosphor. J Rare Earths. 2015;33(10):1040.
Sahu IP, Bisen DP, Brahme N, Tamrakar RK, Shrivastava R. Luminescence studies of dysprosium doped strontium aluminate white light emitting phosphor by combustion route. J Mater Sci: Mater Electron. 2015;26(11):8824.
Xiao F, Xue YN, Zhang QY. Bluish-green color emitting Ba2Si3O8:Eu2+ ceramic phosphors for white light-emitting diodes. Spectrochim Acta A Mol Biomol Spectrosc. 2009;74(3):758.
Chen M, Xia Z, Molokeev MS, Liu Q. Insights into Ba4Si6O16 structure and photoluminescence tuning of Ba4Si6O16:Ce3+, Eu2+ phosphors. J Mater Chem C. 2015;3:12477.
Shrivastava R, Kaur J, Chandra BP. Mechanoluminescence of Ba2MgSi2O7 doped with Eu2+ and Dy3+ phosphor by impulsive deformation. J BioluminChemilumin. 2015;30(8):1207.
Fang YC, Kao PC, Yang YC, Chu SY. Two-Step Synthesis of SrSi2O2N2:Eu2+ Green oxynitride phosphor: electron-phonon coupling and thermal quenching behavior. J Electrochem Soc. 2011;158(8):J246.
Naik R, Prashantha SC, Nagabhushana H, Sharma SC, Nagaswarupa HP, Anantharaju KS, Nagabhushana BM, Premkumar HB, Girish KM. A single phase, red emissive Mg2SiO4:Sm3+ nanophosphor prepared via rapid propellant combustion route. Spectrochim Acta Part A Mol Biomol Spectrosc. 2015;140:516.
Mondal K, Kumari P, Manam J. Influence of doping and annealing temperature on the structural and optical properties of Mg2SiO4:Eu3+ synthesized by combustion method. Curr Appl Phys. 2016;16(7):707.
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Sheoran, S., Singh, K., Tanwar, V. et al. Synthesis and spectroscopic investigations of trivalent europium-doped Z2Si3O8 (Z = Mg, Ca and Sr) nanophosphors for display applications. Rare Met. 40, 2610–2617 (2021). https://doi.org/10.1007/s12598-020-01391-8
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DOI: https://doi.org/10.1007/s12598-020-01391-8