Skip to main content
Log in

Solvent extraction of molybdenum from acidic leach solution of Ni–Mo ore

  • Published:
Rare Metals Aims and scope Submit manuscript

Abstract

A P204 (D2EHPA) diluted with sulfonated kerosene was used for the selective extraction of molybdenum from an acidic Ni–Mo ore leach solution that was reduced using sodium thiosulfate. The results indicate that P204 (D2EHPA) is an effective extractant for the extraction of molybdenum. The extraction of Mo is more than 90 % at pH of 0.5, contact time of 10 min, and organic-to-aqueous phase (O/A) ratio of 1:1 with 10 vol% P204 (D2EHPA). Molybdenum in the loaded organic phase can be effectively stripped with ammonium acid carbonate solution, and the stripping of molybdenum with 60 g·L−1 ammonium acid carbonate solution is 94.67 % at O/A ratio of 2:1 and contact time of 10 min.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Zhang B, Xia XM, Li Q. Preparation of single-phase ammonium dimolybdate by combination process. Rare Met. 2012;31(5):517.

    Article  Google Scholar 

  2. Bao ZX, Wan RJ, Bao JM. Metallogenic characteristics and genesis of the Ni–Mo deposits in northwestern Hunan. Hubei Geol Min Resour. 2001;15(1):14.

    Google Scholar 

  3. Li QG, Xiao LS, Zhang QX. Process and practice of ammonium molybdate production from Ni–Mo ore by hydrometallurgy. Chin J Rare Met. 2007; 31(S):85.

    Google Scholar 

  4. Wang MY, Wang XW, Liu WL. A novel technology of molybdenum extraction from low grade Ni–Mo ore. Hydrometallurgy. 2009;97:126.

    Article  Google Scholar 

  5. Zhao ZW, Li JT, Cao CF, Huo GS, Zhang G, Li HG. Recovery and purification of molybdenum from Ni–Mo ore by direct air oxidation in alkaline solution. Hydrometallurgy. 2010;103:68.

    Article  Google Scholar 

  6. Peng JR, Yang DJ, Chen JX, Yan JF. Experimental study on alkaline leaching of crude molybdenite under pressure of oxygen. Chin J Rare Met. 2007;31(S):111.

    Google Scholar 

  7. Pi GH, Xu H, Chen BZ, Shi XC, Li JL. Study on recovering molybdenum from refractory Ni–Mo ore. Hunan Nonferr Met. 2007;23(1):9.

    Google Scholar 

  8. Wang MY, Wang XW. Extraction of molybdenum and nickel from carbonaceous shale by oxidation roasting, sulphation roasting and water leaching. Hydrometallurgy. 2010;102:50.

    Article  Google Scholar 

  9. Wang MY, Zhang GQ, Wang XW, Zhang JL. Solvent extraction of vanadium from sulfuric acid solution. Rare Met. 2009;28(3):209.

    Article  Google Scholar 

  10. Zhu W, Xiao LS, Xiao C, Gong BF. Molybdenum extraction with N235 from the sulphuric acid leach liquor in Ni–Mo ore. Rare Met Cem Carbides. 2010;38(1):1.

    Google Scholar 

  11. Li WH, Yang YH, Sun SX. Liquid–liquid extraction of molybdenum(VI) from nitric acid solution by primary amine N1923. Rare Met Cem Carbides. 1998;2:1.

    Google Scholar 

  12. Cheng BH, Xiao LS. Solvent extraction of molybdenum from acidic chloride leaching solution. Chin Molybd Ind. 2010;34(1):29.

    Google Scholar 

  13. Kononova ON, Kholmogorov AG, Kachin SV, Kalyakina OP, Sadovskaya EV. Ion exchange recovery of molybdenum from nitric acidic solutions using macroporous anion exchangers with long-chained cross-linking agents. Hydrometallurgy. 2003;68:83.

    Article  Google Scholar 

  14. Wang MY, Wang XW, Xiao CL, Xie H, Liu LH. Extraction separation vanadium and molybdenum from stone coal acidic leach solution. Nonferr Met Sci Eng. 2012;3(5):14.

    Article  Google Scholar 

  15. Lu ZL. Investigation and industrial practice on extraction of V2O5 from stone coal containing vanadium by acid process. Hydrometall Chin. 2002;21(4):175.

    Google Scholar 

Download references

Acknowledgments

This project was financially supported by the National Natural Science Foundation of China (No. 51104186).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ming-Yu Wang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, MY., Wang, XW., Jiang, CJ. et al. Solvent extraction of molybdenum from acidic leach solution of Ni–Mo ore. Rare Met. 33, 107–110 (2014). https://doi.org/10.1007/s12598-013-0061-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12598-013-0061-x

Keywords

Navigation