Skip to main content
Log in

Recovery of bismuth and antimony metals from pressure-leaching slag

  • Published:
Rare Metals Aims and scope Submit manuscript

Abstract

The leaching behavior of metals from a pressure-leaching slag was investigated using a desulphurization-leaching-hydrolysis process for the recovery of bismuth and antimony. Various parameters were studied, including the amount of acid added, temperature, time, addition of NaCl and solid-liquid ratio in the leaching process. The experimental results show that the contents of bismuth and antimony are mostly enriched in the process of kerosene desulphurization. More than 98% Sb and 96% Bi are extracted under the determined conditions. In the process of hydrolysis, the precipitation rates of bismuth and antimony are 97.80% and 94.59%, respectively. Under the optimum experimental conditions, the recovery rate of bismuth and antimony can be up to 95.80% and 90.80%, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Stephen H., and Stephen T., Solubilities of Inorganic and Organic Compounds, Edited by Stephen H., Stephen T, Oxford, 1979: 613.

  2. Wang J.K., and Zhou T.X., Technology and Industrialization of Zinc Concentrates Oxygen Pressure Leaching, Edited by Wang J.K., Zhou T.X., Metallurgical Industry Press, Beijing, 2008: 16.

    Google Scholar 

  3. Dong S.L., The separation of valuable elements from arsenic filter-cake, Sulfuric acid Eng., 1994, 4(5): 3.

    Google Scholar 

  4. Li L., Jiang K.X., and Liu D.X., Oxidative pressure leaching of arsenic sulfide residues, Mining & Metallurgy, 1998, 7(4): 46.

    CAS  Google Scholar 

  5. Wang L.G., Metallurgy of Bismuth, Edited by Wang L.G., Metallurgical Industry Press, Beijing, 1986.

    Google Scholar 

  6. Zhao T.C., Antimony, Edited by Zhao T.C., Beijing, 1987.

  7. Jankola W.A., Zinc Pressure leaching at Cominco, Hydrometallurgy, 1995, 39(3): 63.

    Article  CAS  Google Scholar 

  8. Berezowsky R.M.G.S., Collins M.J., and Kerfoot D.G.E., Thecommercial status of pressure leaching technology, Journal of Met., 1991, 43(2): 9.

    CAS  Google Scholar 

  9. Ozberk E., Collins M.J., and Makwana M., Zinc pressure leaching at the ruhr-zinc refinery, Hydrometallurgy, 1995, 39(2): 53.

    Article  CAS  Google Scholar 

  10. Vizsolyi A., Veltman H., and Warren I.H., Copper and elemental sulphur from chalcopyrite by perssure leaching, Journal of Met., 1967, 18(11): 22.

    Google Scholar 

  11. Zhang B.Y., and Wang J.K., The technological research on pre-treating copper anode slime with pressure acid leaching method, Mining and Metallurgical Eng., 2007, 27(5): 41.

    Google Scholar 

  12. Gu Y.Y., Xu W.Y., and Yang T.Z., Comprehensive treatment of the secondary pyrite tailings by oxidizing-reducing roast ing, Multipurpose Utilization of Mineral Resource, 2008, (4): 41.

  13. Wang B.L., Li J.F., and Xu M., Technical study on recovery of sulfur from copper pyrites residue leached by acid, Journal of Xiamen University(Natural Science), 2008, 47(4): 552.

    CAS  Google Scholar 

  14. Qin Y.H., and Wang Y.Y., Thermodynamic equilibrium of Bi3+-Cl-H2O system, The Chinese Journal of Nonferrous Met., 2000, 10(2): 245.

    Google Scholar 

  15. Zheng G.Q., Tang M.T., and Zhao T.C., Fundamental study on hydromentallurgy on bismuth in the chloride system, Journal of Central South University of Tech., 1997, 28(1): 34.

    CAS  Google Scholar 

  16. Zheng G.Q., and Tang M.T., Phases of residue in distillation of BiCl3-HCl-H2O system, The Chinese Journal of Nonferrous Met., 2000, 10(2): 250.

    CAS  Google Scholar 

  17. Wang Y.Y., and Peng W.J., Thermodynamic equilibrium study of BiCl3-HCl-H2O system, Journal of Central South University of Tech., 2001, 32(2): 139.

    CAS  Google Scholar 

  18. Liao Y.L., and Liu Z.H., Investigation on technology of sodium antimonate synthesis from antimony concentrate by chloridizing leaching process, The Chinese Journal of Nonferrous Met., 2007, 59(2): 46.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Qian Li.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhang, B., Li, Q., Shen, W. et al. Recovery of bismuth and antimony metals from pressure-leaching slag. Rare Metals 31, 102–106 (2012). https://doi.org/10.1007/s12598-012-0471-1

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12598-012-0471-1

Keywords

Navigation