Abstract
Nanostructured AgI/TiO2 photocatalyst was synthesized through deposition-precipitation using AgNO3, KI and Ti(OBU)4. Then the photocatalyst was further treated by PdCl2 solution, which resulted in a color change from yellow to green and PdCl2 reacted with AgI as indicated by X-ray diffraction analyses. The diffusive reflectance UV-vis spectroscopy of this modified photocatalyst shows a remarkable enhancement of the absorption intensity in the range of visible light. As nanostructured AgI/TiO2 shows a considerable visible light photocatalytic activity for the photodegradation of methylene blue, PdCl2-modified AgI/TiO2 exhibits a much larger visible light photocatalytic activity for the photodegradation of methylene blue.
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References
Gao L., Zheng S., and Zhang Q.H., Nanostructured TiO 2 Photocatalyst and Its Applications. Chemical Industry Press, Beijing, 2002.
Zang L., Lange C., Abraham I., Storck S., Maier W. F., and Kishc H., Amorphous microporous titania modified with platinum(IV) chloride — A new type of hybrid photocatalyst for visible light detoxification, J. Phys. Chem. B, 1998, 102(52): 10765].
Bosc F., Ayral A., Keller N., and Keller V., Room temperature visible light oxidation of CO by high surface area rutile TiO2-supported metal photocatalyst, Appl. Catal. B, 2007, 69(3–4): 133.
Yamashita H., Honda M., Harada M., Ichihashi Y., Anpo M., Hirao T., Itoh N., and Iwamoto N., Preparation of titanium oxide photocatalysts anchored on porous silica glass by a metal ion-implantation method and their photocatalytic reactivities for the degradation of 2-propanol diluted in water, J. Phys. Chem. B, 1998, 102(52): 10707.
Wu C.G., Chao C.C., and Kuo F.T., Enhancement of the photo catalytic performance of TiO2 catalysts via transition metal modification, Catal. Today, 2004, 97(2–3): 103.
Anpo M., and Takeuchi M., The design and development of highly reactive titanium oxide photocatalysts operating under visible light irradiation, J. Catal., 2003, 216(1–2): 505.
Asahi R., Morikawa T., Ohwaki T., Aoki K., and Taga Y., Visible-light photocatalysis in nitrogen-doped titanium oxides, Science, 2001, 293(5528): 269.
Burda C., Lou Y., Chen X., Samia A.C.S., Stout J., and Gole J.L., Enhanced nitrogen doping in TiO2 nanoparticles, Nano. Lett, 2003, 3(8): 1049.
Livraghi S., Paganini M.C., Giamello E., Selloni A., Di Valentin C., and Pacchioni G., Origin of photoactivity of nitrogen-doped titanium dioxide under visible light, J. Am. Chem. Soc., 2006, 128(49): 15666.
Reyes-Garcia E.A., Sun Y.P., Reyes-Gil K., and Raftery D., N-15 solid state NMR and EPR characterization of N-doped TiO2 photocatalysts, J. Phys. Chem. C, 2007, 111(6): 2738.
Irie H., Watanabe Y., and Hashimoto K., Carbon-doped anatase TiO2 powders as a visible-light sensitive photocatalyst, Chem. Lett., 2003, 32(8): 772.
Mohapatra S.K., Misra M., Mahajan V.K., and Raja K.S., A novel method for the synthesis of titania nanotubes using sonoelectrochemical method and its application for photoelectrochemical splitting of water J. Catal., 2007, 246(2): 362.
Tachikawa T., Tojo S., Kawai K., Endo M., Fujitsuka M., Ohno T., Nishijima K., Miyamoto Z., and Majima T., Photocatalytic oxidation reactivity of holes in the sulfur- and carbon-doped TiO2 powders studied by time-resolved diffuse Reflectance Spectroscopy, J. Phys. Chem. B., 2004, 108(50): 19299.
Li Y., Hwang D., Lee N.H., and Kim S.J., Synthesis and characterization of carbon-doped titania as an artificial solar lightsensitive photocatalyst, Chem. Phys. Lett., 2005, 404(1–3): 25.
Zhao W., Ma W., Chen C., Zhao J., and Shuai Z., Efficient degradation of toxic organic pollutants with Ni2O3/TiO2−x Bx under visible irradiation, J. Am. Chem. Soc., 2004, 126(15): 4782.
Li Y.Z., Zhang H., Guo Z.M., Han J.J., Zhao X.J., Zhao Q.N., and Kim S.J., Highly efficient visible-light-induced photocatalytic activity of nanostructured AgI/TiO2 photocatalyst, Langmuir, 2008, 24(15): 8351.
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He, K., Zhu, K. & Chen, W. Photocatalytic behavior of PdCl2-modified nanostructured AgI/TiO2 photocatalyst. Rare Metals 30 (Suppl 1), 131–134 (2011). https://doi.org/10.1007/s12598-011-0254-0
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DOI: https://doi.org/10.1007/s12598-011-0254-0