Abstract
The current study aims to explore the use of a low cost technique to develop biodegradable composite films of poly(vinyl alcohol) (PVA) reinforced with silk fibre. The composite films were fabricated by varying the weight percentage of silk fibres and PVA, using the solution casting technique and evaluated for their mechanical and bio-degradable properties. The films were further subjected to characterization by X-ray diffraction (XRD), differential scanning calorimetry (DSC), scanning electron microscopy (SEM), and atomic force microscopy techniques (AFM). The prepared film composites showed enhanced mechanical properties as compared to the pure PVA film. From the XRD studies, the composite films exhibited improved crystallinity, when compared to the pristine sample. The dispersion of fibres in the matrix was revealed by SEM. The thermal properties of the film composites increased with the increasing concentration of silk fibre. Moreover, the soil burial experiments revealed that the degradation rate improved with the addition of silk fibre, thus making it suitable in the packaging sector, without causing any ecological damage owing to its disposable property.
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References
Shalwan A, Yousif BF (2013) In state of art: mechanical and tribological behaviour of polymeric composites based on natural fibres. Mater Des 48:14–24. doi:10.1016/j.matdes.2012.07.014
Shinoj S, Visvanathan R, Panigrahi S, Kochubabu M (2011) Oil palm fiber (OPF) and its composites: a review. Ind Crops Prod 33:7–22. doi:10.1016/j.indcrop.2010.09.009
Liu W, Mohanty AK, Drzal LT, Misra M (2005) Novel biocomposites from native grass and soy based bioplastic: processing and properties evaluation. Ind Eng Chem Res 44:7105–7112. doi:10.1021/ie050257b
Cheung HY, Lau AKT (2006) Mechanical performance of silk-based structural composites. Key Eng Mater 326–328:457–460. doi:10.4028/www.scientific.net/KEM.326-328.457
Hatch KL (1993) Textile science. West Group Publishing, New York
Rockwood DN, Preda RC, Yücel T, Wang X, Lovett ML, Kaplan DL (2011) Materials fabrication from Bombyx mori silk fibroin. Nat Protoc 6:1612–1631. doi:10.1038/nprot.2011.379
Ahmed M, Islam MS, Ahsan Q, Islam MM (2012) Silk fibres and their unidirectional polymer composites. In: Thomas A, Ninan N, Mohan S, Francis E (eds) Natural polymers, biopolymers, biomaterials and their composites, blends and IPN’s. Apple Academic Press Inc, New York, pp 79–90
Tripathi S, Mehrotra GK, Dutta PK (2009) Physicochemical and bioactivity of cross-linked chitosan-PVA film for food packaging applications. Int J Biol Macromol 45:372–376. doi:10.1016/j.ijbiomac.2009.07.006
Tripathi S, Mehrotra GK, Dutta PK (2010) Preparation and physicochemical evaluation of chitosan/poly(vinyl alcohol)/pectin ternary film for food-packaging applications. Carbohydr Polym 79:711–716. doi:10.1016/j.carbpol.2009.09.029
Yoon SD, Park MH, Byun HS (2012) Mechanical and water barrier properties of starch/PVA composite films by adding nano-sized poly(methyl methacrylate-co-acrylamide) particles. Carbohydr Polym 87:676–686. doi:10.1016/j.carbpol.2011.08.046
Cheung HY, Lau KT, Tao XM, Hui D (2008) A potential material for tissue engineering: Silkworm silk/PLA biocomposite. Compos Part B Eng 39:1026–1033. doi:10.1016/j.compositesb.2007.11.009
Prachayawarakorn J, Hwansanoet W (2012) Effect of silk protein fibers on properties of thermoplastic rice starch. Fibers Polym 13:606–612. doi:10.1007/s12221-012-0606-x
Kuchaiyaphum P, Punyodom W, Watanesk S, Watanesk R (2013) Composition optimization of polyvinyl alcohol/rice starch/silk fibroin-blended films for improving its eco-friendly packaging properties. J Appl Polym Sci 129:2614–2620. doi:10.1002/app.38977
Rahman MM, Afrin S, Haque P (2014) Characterization of crystalline cellulose of jute reinforced poly(vinyl alcohol) (PVA) biocomposite film for potential biomedical applications. Prog Biomater 3:23. doi:10.1007/s40204-014-0023-x
Laxmeshwar SS, Madhu Kumar DJ, Viveka S, Nagaraja GK (2012) Preparation and properties of biodegradable film composites using modified cellulose fibre-reinforced with PVA. ISRN Polym Sci 2012:1–8. doi:10.5402/2012/154314
Sanchez-Garcia MD, Gimenez E, Lagaron JM (2008) Morphology and barrier properties of solvent cast composites of thermoplastic biopolymers and purified cellulose fibers. Carbohydr Polym 71:235–244. doi:10.1016/j.carbpol.2007.05.041
Kirby AR, Ng A, Waldron KW, Morris VJ (2006) AFM investigations of cellulose fibers in Bintje potato (solanum tuberosum L.) cell wall fragments. Food Biophys 1:163–167. doi:10.1007/s11483-006-9013-4
Sriupayo J, Supaphol P, Blackwell J, Rujiravanit R (2005) Preparation and characterization of α-chitin whisker-reinforced poly (vinyl alcohol) nanocomposite films with or without heat treatment. Polymer (Guildf) 46:5637–5644. doi:10.1016/j.carbpol.2005.07.013
Morton WE, Hearle JWS (2008) Physical properties of textile fibres. Woodhead Publishing Limited, Sawston
Ho MP, Lau KT, Wang H, Bhattacharyya D (2011) Characteristics of a silk fibre reinforced biodegradable plastic. Compos Part B Eng 42:117–122. doi:10.1016/j.compositesb.2010.10.007
Shubhra QT, Saha M, Alam A, Beg M, Khan MA (2010) Effect of matrix modification by natural rubber on the performance of silk-reinforced polypropylene composites. J Reinf Plast Compos 29:3338–3344. doi:10.1177/0731684410375640
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The authors express their sincere appreciation to DST- PURSE, Mangalore University for providing the facilities to carry out the characterizations of the samples.
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Sheik, S., Nagaraja, G.K., Naik, J. et al. Development and characterization study of silk fibre reinforced poly(vinyl alcohol) composites. Int J Plast Technol 21, 108–122 (2017). https://doi.org/10.1007/s12588-017-9174-7
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DOI: https://doi.org/10.1007/s12588-017-9174-7