Skip to main content
Log in

Corrosion and Wear Characteristics of Electroless Ni–P, Ni–P–W and Composite Ni–P–W/Al2O3 Coatings on AZ91 Sheet

  • Published:
Metals and Materials International Aims and scope Submit manuscript

Abstract

Electroless Ni–P–W was coated on AZ91 sheets with various W contents and both the corrosion and wear resistance characteristics of these coatings were observed. The increase in W content resulted in a decrease in P content and an increase in the crystallinity of the electroless coatings. The corrosion resistance of the electroless coatings increased upon increase in W content of the electroless coatings up to approximately 5%. Above this content, however, the corrosion resistance tended to decrease due to the disturbed grain structure of the electroless coating. But both the surface hardness and wear resistance increased concurrently due to the positive contribution of W solid solution hardening. The applied heat treatment resulted in a decrease in the corrosion resistance due to the disappearance of the amorphous structure and increase in both the surface hardness and wear resistance due to the precipitation hardening. Al2O3 dispersion was better with the nonionic surfactant, as compared to the anionic and cationic surfactants. Composite coating reduced the corrosion resistance and increased the wear resistance of the electroless Ni–P–W coatings. The applied heat treatment was observed to have positive contribution to Ni–P–W coatings in getting the optimum corrosion and wear resistance combination.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14

Similar content being viewed by others

References

  1. N. Tsyntsaru, H. Cesiulis, M. Donten, J. Sorte, E. Pellicer, E.J. Podlaha-Murphy, Modern trends in tungsten alloys electrodeposition with iron group metals. Surf. Eng. Appl. Electrochem. 48(6), 491–520 (2012)

    Article  Google Scholar 

  2. E.J. Podlaha, D. Landolt, Induced codeposition: I. An experimental investigation of Ni-Mo alloys. J. Electrochem. Soc. 143(3), 885–892 (1996)

    Article  Google Scholar 

  3. E.J. Podlaha, D. Landolt, Induced codeposition: III. Molybdenum alloys with nickel, cobalt, and iron. J. Electrochem. Soc. 144(5), 1672–1680 (1997)

    Article  Google Scholar 

  4. O. Younes, E. Gileadi, Electroplating of high tungsten content Ni/W alloys. Electrochem. Solid State Lett. 3(12), 543–545 (2000)

    Article  Google Scholar 

  5. O. Younes, E. Gileadi, Electroplating of Ni/W alloys: I. Ammoniacal citrate baths. J. Electrochem. Soc. 149(2), C100–C111 (2002)

    Article  Google Scholar 

  6. O. Younes, L. Zhu, E. Gileadi, The anomalous codeposition of tungsten in the presence of nickel. Electrochim. Acta 48(18), 2551–2562 (2003)

    Article  Google Scholar 

  7. M.D. Obradovic, R.M. Stevanovic, A.R. Despic, Electrochemical deposition of Ni–W alloys from ammonia-citrate electrolyte. J. Electroanal. Chem. 552, 185–196 (2003)

    Article  Google Scholar 

  8. K.R. Sriraman, S.G.S. Raman, S.K. Seshadri, Synthesis and evaluation of hardness and sliding wear resistance of electrodeposited nanocrystalline Ni–W alloys. Mater. Sci. Eng. A 418(1–2), 303–311 (2006)

    Article  Google Scholar 

  9. A. Krolikowski, E. Plonska, A. Ostrowski, M. Donten, Z. Stojek, The electrochemistry of nanostructured Ni–W alloys. J. Solid State Electrochem. 13(2), 263–275 (2009)

    Article  Google Scholar 

  10. K.A. Kumar, G.P. Kalaignan, V.S. Muralidharan, Pulse electrodeposition and characterization of nano Ni–W alloy deposits. Appl. Surf. Sci. 259, 231–237 (2012)

    Article  Google Scholar 

  11. N. Du, M. Pritzker, Investigation of electroless plating of Ni–W–P alloy films. J. Appl. Electrochem. 33(11), 1001–1009 (2003)

    Article  Google Scholar 

  12. X.Y. Yuan, T. Xie, G.S. Wu, Y. Lin, G.W. Meng, L.D. Zhang, Fabrication of Ni–W–P nanowire arrays by electroless deposition and magnetic studies. Physica E 23(1), 75–80 (2004)

    Article  Google Scholar 

  13. J.N. Balaraju, S. Millath Jahan, C. Anandan, K.S. Rajam, Studies on electroless Ni–W–P and Ni–W–Cu–P alloy coatings using chloride based bath. Surf. Coat. Technol. 200(16), 4885–4890 (2006)

    Article  Google Scholar 

  14. X. Shu, Y. Wang, X. Lu, C. Liu, W. Gao, Parameter optimization for electroless Ni–W–P coating. Surf. Coat. Technol. 276, 195–201 (2015)

    Article  Google Scholar 

  15. J.E. Gray, B. Luan, Protective coatings on magnesium and its alloys—a critical review. J. Alloys Compd. 336(1–2), 88–113 (2002)

    Article  Google Scholar 

  16. G.L. Makar, J. Kruger, Stress corrosion cracking of rapidly solidified magnesium-aluminum alloys. Int. Mater. Rev. 38(8), 138–153 (1993)

    Article  Google Scholar 

  17. G. Song, A. Atrens, Corrosion mechanisms of magnesium alloys. Adv. Eng. Mater. 1(1), 11–33 (1999)

    Article  Google Scholar 

  18. M. Anik, P. Avci, A. Tanverdi, I. Celikyurek, B. Baksan, R. Gurler, Effect of the eutectic phase on the anodic behavior of alloy AZ91. Mater. Des. 27(5), 347–355 (2006)

    Article  Google Scholar 

  19. M. Anik, G. Çelikten, Analysis of the electrochemical reaction behavior of alloy AZ91 by EIS technique in H3PO4/KOH buffered K2SO4 solutions. Corros. Sci. 19(4), 1878–1894 (2007)

    Article  Google Scholar 

  20. M. Anik, E. Körpe, Effect of alloy microstructure on electroless NiP deposition behavior on alloy AZ91. Surf. Coat. Technol. 201(8), 4702–4710 (2007)

    Article  Google Scholar 

  21. M. Anik, E. Körpe, E. Şen, Effect of coating bath composition on the properties of electroless nickel–boron films. Surf. Coat. Technol. 202(9), 1718–1727 (2008)

    Article  Google Scholar 

  22. W.X. Zhang, N. Huang, J.G. He, Z.H. Jiang, Q. Jiang, J.S. Lian, Electroless deposition of Ni–W–P coating on AZ91D magnesium alloy. Appl. Surf. Sci. 253(11), 5116–5121 (2007)

    Article  Google Scholar 

  23. X.M. Chen, G.Y. Li, J.S. Lian, Deposition of electroless Ni–P/Ni–W–P duplex coatings on AZ91D magnesium alloy. Trans. Nonferrous Met. Soc. China 18(Supp. 1), 323–328 (2008)

    Article  Google Scholar 

  24. V.E. Selvi, P. Chatterji, S. Subramanian, J.N. Balaraju, Autocatalytic duplex Ni–P/Ni–W–P coatings on AZ31B magnesium alloy. Surf. Coat. Technol. 240, 103–109 (2014)

    Article  Google Scholar 

  25. S. Armyanov, E. Valova, D. Tatchev, J. Georgieva, Electroless deposited ternary alloys: third element chemical state, localization and influence on the properties. A short review. Trans. Inst. Met. Finish 96(1), 12–19 (2018)

    Article  Google Scholar 

  26. Z. Adigüzel, M. Anik, Dissolution behavior of electrodeposited Ni–W alloys. Prot. Met. Phys. Chem. 54(2), 316–324 (2018)

    Article  Google Scholar 

  27. R.B. Diegle, N.R. Sorensen, C.R. Clayton, M.A. Helfand, Y.C. Yu, An XPS investigation into the passivity of an amorphous Ni-20P alloy. J. Electrochem. Soc. 135(5), 1085–1092 (1988)

    Article  Google Scholar 

  28. J. Sudagar, J. Lian, W. Sha, Electroless nickel, alloy, composite and nano coatings—a critical review. J. Alloys Compd. 571, 183–204 (2013)

    Article  Google Scholar 

  29. A. Amell, C. Muller, M. Sarret, Influence of fluorosurfactants on the codeposition of ceramic nanocomposites and the morphology of electroless NiP coatings. Surf. Coat. Technol. 205(2), 356–362 (2010)

    Article  Google Scholar 

  30. A.S. Hamdy, M.A. Shoeib, H. Hady, O.F.A. Salam, Corrosion behavior of electroless Ni–P alloy coatings containing tungsten or nano-scattered alumina composite in 3.5% NaCl solution. Surf. Coat. Technol. 202(1), 162–171 (2007)

    Article  Google Scholar 

  31. A.S. Hamdy, M.A. Shoeib, H. Hady, O.F.A. Salam, Electroless deposition of ternary Ni–P alloy coatings containing tungsten or nano-scattered alumina composite on steel. J. Appl. Electrochem. 3(38), 385–394 (2008)

    Article  Google Scholar 

  32. J.N. Balaraju, K.S. Rajam, Electroless ternary Ni–W–P alloys containing micron size Al2O3 particles. Surf. Coat. Technol. 205(2), 575–581 (2010)

    Article  Google Scholar 

  33. J. Novakovic, P. Vassiliou, K. Samara, T. Argyropoulos, Electroless NiP–TiO2 composite coatings: their production and properties. Surf. Coat. Technol. 201(3–4), 895–901 (2006)

    Article  Google Scholar 

  34. A.A. Zuleta, O.A. Galvis, J.G. Castaño, F. Echeverría, F.J. Pérez-Trujillo, Preparation and characterization of electroless Ni–P–Fe3O4 composite coatings and evaluation of its high temperature oxidation behavior. Surf. Coat. Technol. 203(23), 3569–3578 (2009)

    Article  Google Scholar 

  35. S. Zhang, K. Han, L. Chen, The effect of SiC particles added in electroless Ni–P plating solution on the properties of composite coatings. Surf. Coat. Technol. 202(12), 2807–2812 (2008)

    Article  Google Scholar 

  36. A.A. Kaya, O. Duygulu, S. Ucuncuoglu, G. Oktay, D.S. Temur, O. Yucel, Production of 150 cm wide AZ31 magnesium sheet by twin roll casting. Trans. Nonferrous Met. Soc. China 18(Supp. 1), 185–188 (2008)

    Article  Google Scholar 

  37. J.N. Belaraju, N.T. Manikandanath, V.K. Grips, Phase transformation behavior of nanocrystalline Ni–W–P alloys containing various W and P contents. Surf. Coat. Technol. 206(10), 2682–2689 (2012)

    Article  Google Scholar 

  38. K. Krishnan, S. John, K. Srinivasan, An overall aspect of electroless Ni–P depositions—a review article. Mater. Trans. A 37(6), 1917–1926 (2006)

    Article  Google Scholar 

  39. P.L. Cavallotti, L. Magagnin, C. Cavallotti, Influence of added elements on autocatalytic chemical deposition electroless NiP. Electrochim. Acta 114, 805–812 (2013)

    Article  Google Scholar 

  40. M. Anik, Anodic behavior of tungsten in H3PO4-K2SO4-H2SO4/KOH solutions. Turk. J. Chem. 26, 915–924 (2002)

    Google Scholar 

  41. M. Anik, Effect of concentration gradient on the anodic behavior of tungsten. Corros. Sci. 48(12), 4158–4173 (2006)

    Article  Google Scholar 

  42. M. Anik, pH-dependent anodic reaction behavior of tungsten in acidic phosphate solutions. Electrochim. Acta 54(15), 3943–3951 (2009)

    Article  Google Scholar 

  43. A. AlZahrani, Y. Alhamed, L. Petrov, S. Armyanov, E. Valova, J. Georgieva, J. Dille, Mechanical and corrosion behavior of amorphous and crystalline electroless Ni–W–P coatings. J. Solid State Electrochem. 18(7), 1951–1961 (2014)

    Article  Google Scholar 

  44. M. Palaniappa, S.K. Seshadri, Friction and wear behavior of electroless Ni–P and Ni–W–P alloy coatings. Wear 265(5–6), 735–740 (2008)

    Article  Google Scholar 

  45. Z. Guo, K.G. Keong, W. Sha, Crystallization and phase transformation behavior of electroless nickel phosphorus platings during continuous heating. J. Alloys Compd. 358(1–2), 112–119 (2003)

    Article  Google Scholar 

  46. J.N. Balaraju, T.S.N. Sankara Narayanan, S.K. Seshadri, Structure and phase transformation behavior of electroless Ni–P composite coatings. Mater. Res. Bull. 41(4), 847–860 (2006)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mustafa Anik.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Taşci, S., Özden, R.C. & Anik, M. Corrosion and Wear Characteristics of Electroless Ni–P, Ni–P–W and Composite Ni–P–W/Al2O3 Coatings on AZ91 Sheet. Met. Mater. Int. 25, 313–323 (2019). https://doi.org/10.1007/s12540-018-0199-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12540-018-0199-z

Keywords

Navigation