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Structural and phase transformations during copper and iron mechanical alloying in liquid medium studied by Mössbauer spectroscopy

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Abstract

Mössbauer spectroscopy and X-ray diffraction have been used to study the kinetics of structural and phase transformations in Cu + 2 at% 57Fe during mechanical activation in liquid media (heptane, distilled water) and subsequent heat treatment (600 and 700 °С). The initial stages of mechanical alloying are associated with the transition of components to the nanostructural state. Iron atom groups form near the grain boundaries, and isolated iron atoms penetrate from the boundaries into the grains. Oxidation of groups of iron atoms that form highly dispersed phases of ternary oxide and magnetite occur in the initial stages of mechanical alloying of Cu + 2 at% 57Fe in water. The formation of the solid solution in the form of isolated iron atoms in the lattice of copper proceeds, regardless of the milling media used. Samples prepared in heptane contain carbon and oxygen, and upon heat treatment, carbide and oxide phases are formed.

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Authors and Affiliations

  1. Russian Academy of Sciences, Ural Branch, Physical-Technical Institute, Izhevsk, 426000, Russia

    Marina Anatol’evna Eryomina, Svetlana Fedorovna Lomayeva, Alexandr Leonidovich Ul’yanov & Evgeny Petrovich Yelsukov

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  1. Marina Anatol’evna Eryomina
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  2. Svetlana Fedorovna Lomayeva
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  3. Alexandr Leonidovich Ul’yanov
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Correspondence to Marina Anatol’evna Eryomina.

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Eryomina, M.A., Lomayeva, S.F., Ul’yanov, A.L. et al. Structural and phase transformations during copper and iron mechanical alloying in liquid medium studied by Mössbauer spectroscopy. Met. Mater. Int. 22, 163–170 (2016). https://doi.org/10.1007/s12540-016-5459-1

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