Abstract
We studied the structure and phase transformations of nanocrystalline alloys prepared with mechanical alloying (MA) and annealing by milling copper and iron powders with graphite and xylene. At an early stage of MA, a supersaturated solid solution of iron is formed in copper, regardless of the carbon-precursor type used. In the case of graphite, the formation of iron carbides occurs at a later stage of milling. MA in xylene results in an insignificant amount of carbon phases. Heat treatment leads to the formation of nanocrystalline copper composites with 30 vol.% Fe3C in the two cases of using graphite and xylene. The grain size (30 nm) of the annealed (800 °C) Cu + Fe3C composite produced by MA with xylene is five times less than that of the annealed sample produced with graphite.
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J. Y. Huang, Y. K. Wu, and H. Q. Ye, Acta Mater. 44, 1211 (1996).
D. Setman, M. Kerber, H. Bahmanpour, J. Horky, R. O. Scattergood, C. C. Koch, and M. J. Zehetbauer, Mech. Mater. 67, 59 (2013).
J. Schiøtz, F. D. Di Tolla, and K. W. Jacobsen, Nature. 391, 561 (1998).
K. S. Kumar, S. Suresh, M. F. Chisholm, J. A. Horton, and P. Wang, Acta Mater. 51, 387 (2003).
X. Z. Liao, Y. H. Zhao, S. G. Srinivasan, and Y. T. Zhu, Appl. Phys. Lett. 84, 592 (2004).
J. M. Tao, X. K. Zhu, R. O. Scattergood, and C. C. Koch, Mater. Design. 50, 22 (2013).
M. A. Eremina, S. F. Lomayeva, and E. P. Elsukov, Phys. Met. Metallogr. 114, 928 (2013).
Yu. N. Raikov, G. V. Ashihmin, A. K. Nikolaev, N. I. Revina, and S. A. Kostin, Metallurgist. 8, 40 (2007).
K. Ichikawa and M. Achikita, Mater. Trans. JIM 34, 718 (1993).
B. D. Long, M. Umemoto, Y. Todaka, R. Othman, and H. Zuhailawati, Mater. Sci. Eng. A 528, 1750 (2011).
R. H. Palma, A. H. Sepúlveda, R. A. Espinoza, and R. C. Montiglio, J. Mater. Proc. Technol. 169, 62 (2005).
B. D. Long, R. Othman, M. Umemoto, and H. Zuhailawati, J. Alloys Compd. 505, 510 (2010).
P. A. Caravalho, I. Fonesca, M. T. Marques, J. B. Correia, A. Almeida, and R. Vilar, Acta Mater. 53, 967 (2005).
J. B. Correia and M. T. Marques, Mater. Sci. Forum. 455–456, 501 (2004).
T. J. Goodwin, S. H. Yoo, P. Matteazzi, and J. R. Groza, NanoStruct. Mater. 8, 559 (1997).
M. Umemoto, Z. G. Liu, H. Takaoka, M. Sawakami, K. Tsuchiya, and K. Masuyama, Metall. Mater. Trans. A 32, 2127 (2001).
D. Chaira, B. K. Mishra, and S. Sangal, Powder Technol. 191, 149 (2009).
J. Zhang and O. Ostrovski, ISIJ Intern. 41, 333 (2001).
S. F. Lomaeva, V. A. Volkov, A. N. Maratkanova, D. V. Surnin, E. P. Elsukov, S. F. Zayats, A. S. Kaigorodov, V. V. Ivanov, and S. N. Paranin, Materialovedenie (Materials Science), 6, 58 (2010).
V. A. Barinov, E. P. Yelsukov, and L. V. Ovetchkin, A Method for Producing of Cementite Powder, SU Patent No. 1678525 A1. Bull. No. 35 (1991).
E. P. Yelsukov, V. A. Barinov, and L. V. Ovetchkin, J. Mater. Sci. Lett. 11, 662 (1992).
S. F. Lomaeva, Phys. Met. Metallogr. 104, 388 (2007).
G. A. Dorofeev, A. N. Streletskii, I. V. Povstugar, A. V. Protasov, and E. P. Elsukov, Colloid J. 74, 675 (2012).
E. V. Voronina, N. V. Ershov, A. L. Ageev, and Y. A. Babanov, Phys. Stat. Sol. B 160, 625 (1990).
A. M. Harris, G. B. Schaffer, and N. W. Page, J. Mater. Sci. Lett. 12, 1103 (1993).
J.-C. Crivello, T. Nobuki, and T. Kuji, Mater. Trans. 49, 527 (2008).
F. M. Lucas, B. Trindade, B. F. O. Costa, and G. L. Caër, Key Eng. Mater. 230–232, 631 (2002).
V. G. Harris, K. M. Kemner, B. N. Das, N. C. Koon, and A. E. Ehrlich, Phys. Rev. B 54, 6929 (1996).
S. B. Ogale, P. G. Bilurkar, S. Joshi, and G. Marest, Phys. Rev. B 50, 9743 (1994).
S. J. Stewart, G. F. Goya, G. Punte, and R. C. Mercader, J. Phys. Chem. Sol. 58, 73 (1997).
D. P. Joseph, T. P. David, S. P. Raja, and C. Venkateswaran, Mater. Charact. 59, 1137 (2008).
R. A. Dunlap, D. A. Eelman, and G. R. Mackay, J. Mater. Sci. Lett. 17, 437 (1998).
I. P. Suzdalev, Yu. V. Maksimov, V. K. Imshennik, S. V. Novichikhin, V. V. Matveev, E. A. Gulilin, A. E. Chekanova, O. S. Petrova, and Y. D. Tretyakov, Nanotechnologies in Russia. 2, 73 (2007).
S. J. Campbell, P. E. Clark, and P. R. Liddell, J. Phys. F.: Metal. Phys. 2, L114 (1972).
G. Le Caër, J. M. Dubois, and J. P. Senateur, J. Solid State Chem. 19, 19 (1976).
K. Tokumitsu and M. Umemoto, Mater. Sci. Forum. 360–362, 183 (2001).
S. J. Campbell, G. M. Wang, A. Calka, and W. A. Kaczmarek, Mater. Sci. Eng. A 226–228, 75 (1997).
T. Matsue, Y. Yamada, and Y. Kobayashi, Hyperfine Interact. 205, 31 (2011).
E. Bauer-Grosse and G. Le Caër, Phil. Mag. B 56, 485 (1987).
F. Miani, P. Matteazzi, D. Basset, and G. Le Caër, Hyperfine Inter. 94, 2219 (1994).
P. Matteazzi, F. Miani, and G. L. Caër, Hyperfine Inter. 68, 173 (1991).
K. Uenishi, K. F. Kobayashi, S. Nasu, H. Hatano, K. N. Ishihara, and P. H. Shingu, Z. Metallkd. 83, 132 (1992).
J. Z. Jiang, Q. A. Pankhurst, C. E. Johnson, C. Gente, and R. Bormann, J. Phys.: Cond. Matter. 6, L227 (1994).
J. Eckert, J. C. Holzer, and W. L. Johnson, J. Appl. Phys. 73, 131 (1993).
P. P. Macri, S. Enzo, N. Cowlam, R. Frattini, G. Principi, and W. X. Hu, Phil. Mag. B 71, 249 (1995).
M. Eilon, J. Ding, and R. Street, J. Phys. Cond. Matter. 7, 4921 (1995).
W. Keune, J. Lauer, and D. L. Williamson, J. de Physique. 35, C6-473 (1974).
W. B. Pearson, A Handbook of Lattice Spacings and Structures of Metals and Alloys, pp.571–572, Pergamon Press, London, New York, Paris, Los Angeles (1958).
M. T. Marques, J. B. Correia, and O. Conde, Scr. Mater. 50, 963 (2004).
Y. Jin and M. Hu, Adv. Mater. Res. 306–307, 1747 (2011).
R. J. Longbottom, O. Ostrovski, J. Zhang, and D. Young, Met. Mater. Trans. B 38, 175 (2007).
L. S. Vasil’ev and S. F. Lomayeva, J. Mater. Sci. 3, 5411 (2004).
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Eryomina, M.A., Lomayeva, S.F., Yelsukov, E.P. et al. Cementite formation in copper matrix under mechanical activation using carbon media. Met. Mater. Int. 20, 1123–1130 (2014). https://doi.org/10.1007/s12540-014-6016-4
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DOI: https://doi.org/10.1007/s12540-014-6016-4