Abstract
Oxide nanofibers synthesized by the electrospinning method have received considerable attention owing to their potential applications in various fields. This paper provides an overview of the growth behavior and the importance of the presence of nanograins in oxide nanofibers synthesized by the electrospinning method. The growth behavior of nanograins in various oxide nanofibers is described in terms of its effect on activation energy and growth exponent, which are then compared with the bulk counterparts. The lower activation energy of nanograins in nanofibers by an order of magnitude revealed that the active participation of nanograins during grain growth is due to higher chemical potential of atoms presented in nanosized grains. In addition, the influences of nanograins on the electrical, gas-sensing, magnetic, optical, and photocatalytic properties of nanofibers are discussed. It is shown that optimization of the nanograin size is essential to ensure that the advantages of oxide nanofibers are utilized in different applications.
Similar content being viewed by others
References
G. Yu, A. Cao, and C. M. Lieber, Nat. Nanotechnol. 2, 372 (2007).
B. Tian, X. Zheng, T. J. Kempa, Y. Fang, N. Yu, G. Yu, J. Huang, and C. M. Lieber, Nature, 449, 885 (2007).
W. Lu and C. M. Lieber, Nat. Mater. 6, 841 (2007).
F. Kleitz, F. Marlow, G. D. Stucky, and F. Schuth, Chem. Mater. 13, 3587 (2001).
X. P. Shen, H. J. Liu, X. Fan, Y. Jiang, J. M. Hong, and Z. Xu, J. Cryst. Growth, 276, 471 (2005).
Y. Ding, P. Zhang, Z. Long, Y. Jiang, J. Huang, W. Yan, and G. Liu, Mater. Lett. 62, 3410 (2008).
Y.-T. Hsieh, M.-W. Huang, C.-C. Chang, U.-S. Chen, and H.-C. Shih, Thin Solid Films, 519, 1668 (2010).
M. Chen, Z. Wang, D. Han, F. Gu, and G. Guo, Sens. Actuators B: Chem. 157, 565 (2011).
J. Y. Park, K. Asokan, S.-W. Choi, and S. S. Kim, Sens. Actuators B: Chem. 152, 254 (2011).
K. Yoon, B. S. Hsiao, and B. Chu, J. Mater. Chem. 18, 5326 (2008).
L. M. Bellan and H. G. Craighead, J. Manuf. Sci. Eng. 131, 034001 (2009).
I. S. Chronakis, J. Mater. Process. Technol. 167, 283 (2005).
Y. Dai, W. Liu, E. Formo, Y. Sun, and Y. Xia, Polym. Adv. Technol. 22, 326 (2011).
M. N. Rahaman, Ceramic Processing and Sintering, pp. 447–492, Marcel Dekkar Inc., New York (1995).
C. H. Shek, G. M. Lin, and J. K. L. Lai, Nanostruct. Mater. 11, 831 (1999).
Q. Pan, J. Xu, X. Dong, and J. Zhang, Sens. Actuators B: Chem. 66, 237 (2000).
C. Drake, A. Amalu, J. Bernard, and S. Seal, J. Appl. Phys. 101, 104307 (2007).
J. K. L. Lai, C. H. Shek, and G. M. Lin, Scripta Mater. 49, 441 (2003).
R. Joesten, J. Am. Ceram. Soc. 68, C–62 (1985).
J. Y. Park and S. S. Kim, J. Am. Ceram. Soc. 92, 1691 (2009).
J. E. Burke and D. Turnbull, Progr. Met. Phys. 3, 220 (1952).
A. J. Ardell, Acta Metall. 20, 601 (1972).
J. Y. Park, S.-W. Choi, K. Asokan, and S. S. Kim, Met. Mater. Int. 16, 785 (2010).
J. Y. Park, S.-W. Choi, K. Asokan, and S. S. Kim, J. Nanosci. Nanotechnol. 10, 3604 (2010).
S.-W. Choi, J. Y. Park, and S. S. Kim, Mater. Chem. Phys. 127, 16 (2011).
S.-W. Choi, J. Y. Park, and S. S. Kim, Chem. Eng. J. 172, 550 (2011).
S.-W. Choi, J. Y. Park, and S. S. Kim, Ceram. Int. 37, 427 (2011).
J. Han, P. Q. Mantas, and A. M. R. Senos, J. Eur. Ceram. Soc. 20, 2753 (2000).
G. Li, L. Li, J. B.-Goates, and B. F. Woodfield, J. Mater. Res. 18, 2664 (2003).
R. W. Jackson, J. P. Leonard, F. S. Pittit, and G. H. Meier, Solid State Ionics. 179, 2111 (2008).
J.-P. Ahn, J.-H. Kim, J.-K. Park, and M.-Y. Huh, Sens. Actuators, B: Chem., 99, 18 (2004).
S.-J. L. Kang, Sintering: Densification, Grain Growth, and Microstructure, pp.9–12, Elsevier Butterworth-Heinemann, Amsterdam (2005).
J. Y. Kim, J. A. Rodriguez, J. C. Hanson, A. I. Frenkel, and P. L. Lee, J. Am. Chem. Soc., 125, 10684 (2003).
R.-J. Yang, F.-S. Yen, S.-M. Lin, and C.-C. Chen, J. Cryst. Growth, 299, 429 (2007).
I.-L. Liu and P. Shen, J. Eur. Ceram. Soc. 29, 2235 (2009).
R. W. Jackson, J. P. Leonard, F. S. Pittit, and G. H. Meier, Solid State Ion. 179, 2111 (2008).
Y. Yeh, I.-H. Liu, and P. Shen, J. Eur. Ceram. Soc. 30, 677 (2010).
J. Y. Park, J. J. Kim, and S. S. Kim, Microelectron. Eng. 101, 8 (2013).
K. Kim, H. Kang, H. Kim, J. S. Lee, S. Kim, W. Kang, and G.T. Kim, Appl. Phys. A, 94, 253 (2009).
W. Park, W. K. Hong, G. Jo, G. Wang, M. Choe, J. Maeng, Y. H. Kahng, and T. Lee, Nanotechnology, 20, 475702 (2009).
Y. I. Lee, K. J. Lee, K. D. Kim, H. T. Kim, Y. W. Chang, S. C. Kang, and Y. H. Choa, J. Nanosci. Nanotechnol. 7, 3910 (2007).
W. Sukbua, J. Muangban, N. Triroj, and P. Jaroenapibal, Procedia Engineering, 47, 370 (2012).
S. K. Lim, S.-Ho. Hwang, D. Chang, and S. Kim, Sens. Actuators B: Chem. 149, 28 (2010).
J. Y. Leng, X.-J. Xu, N. Lv, H.-T. Fan, and T. Zhang, J. Colloid Interf. Sci. 356, 54 (2011).
S.-W. Choi, J. Y. Park, and S. S. Kim, J. Mater. Res. 26, 1662 (2011).
A. Katoch, G.-J. Sun, S.-W. Choi, J.-H. Byun, and S. S. Kim, Sens. Actuators B: Chem. 185, 411 (2013).
X. L. Zhang, Z. Zhang, D. Chen, P. Bäuerle, U. Bache, and Y.-B. Cheng, Chem. Commun. 48, 9885 (2012).
J. H. Song, J. H. Nam, J. H. Cho, B. I. Kim, and M. P. Chun, J. Korean Phys. Soc. 59, 2308 (2011).
W. Pan, R. Han, X. Chi, Q. Liu, and J. Wang, J. Alloys Comp., 577, 192 (2013).
J. Zhang, J. Fu, F. Li, E. Xie, D. Xue, N. J. Mellors, and Y. Peng, Acs Nano, 6, 2273 (2012).
X. Yang, Y. Liu, J. Li, and X. Zhang, Micro Nano Lett. 6, 967 (2011).
M. Liu, F. Song, X. Shen, and Y. Zhu, J. Sol-Gel Sci. Technol. 56, 39 (2010).
M. Liu, X. Shen, F. Song, J. Xiang, and X. Meng, Mater. Chem. Phys. 124, 970 (2010).
Q. Liang, X. Sheny, F. Song, and M. Liu, J. Mater. Sci. Technol. 27, 996 (2011).
X. Shen, J. Zheng, X. Meng, and Q. Liang, J. Wuhan Univ. Technol. 26, 384 (2011).
P. Viswanathamurthi, N. Bhattarai, H. Y. Kim, and D. R. Lee, Nanotechnology, 15, 320 (2004).
A. Kumar, R. Jose, K. Fujihara, J. Wang, and S. Ramakrishna, Chem. Mater. 19, 6536 (2006).
M. M. Munir, F. Iskandar, K. M. Yun, K. Okuyama, and M. Abdullah, Nanotechnology, 19, 145603 (2008).
G. Dong, Y. Chi, X. Xiao, X. Liu, B. Qian, Z. Ma, E. Wu, H. Zeng, D. Chen, and J. Qiu, Opt. Express, 17, 22514 (2009).
Y. Wang, I. Ramos, and J. J. Santiago-Avilés, J. Appl. Phys. 102, 093517 (2007).
N. A. M. Barakat, M. S. Khil, F. A. Sheikh, and H. Y. Kim, J. Phys. Chem. C, 112, 12225 (2008).
S. Qi, R. Zuo, Y. Liu, and Y. Wang, Mater. Res. Bull. 48, 1213 (2013).
R. Viter, A. Katoch, and S. S. Kim, Met. Mater. Int. 20, 163 (2013).
B. Dong, Z. Li, Z. Li, X. Xu, M. Song, W. Zheng, C. Wang, S. S. Al-Deyab, and M. El-Newehy, J. Am. Ceram. Soc. 93, 3587 (2010).
X. Zhang, H. Liu, B. Zheng, Y. Lin, D. Liu, and C.-W. Nan, J. Nanomater. 2013, 1 (2013).
P. Singh, K. Mondal, and A. Sharma, J. Colloid Interf. Sci. 394, 208 (2013).
M. S. Hassan, T. Amna, and M.-S. Khil, Ceram. Inter. 40, 423 (2013).
D. Hou, W. Luo, Y. Huang, J. C. Yu, and X. Hu, Nanoscale, 5, 2028 (2013).
S. S. Lee, H. Bai, Z. Liu, and D. D. Sun, Water Res. 47, 4059 (2013).
C. C. Pei and W. W.-F. Leung, Catal. Commun. 37, 100 (2013).
D. K. Sarkar, D. Brassard, M. A. E. Khakani, and L. Ouellet, Appl. Phys. Lett. 87, 253108 (2005).
A. S. Ahmed, A. Azam, M. M. Shafeeq M. Chaman, and S. Tabassum, J. Phys. Chem. Solids. 73, 943 (2012).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Katoch, A., Choi, SW. & Kim, S.S. Nanograins in electrospun oxide nanofibers. Met. Mater. Int. 21, 213–221 (2015). https://doi.org/10.1007/s12540-015-4319-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12540-015-4319-8