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Purification of niobium by multiple electron beam melting for superconducting RF cavities

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Abstract

In this work, purification of commercial grade (∼99.9 %) niobium by multiple Electron Beam Melting (EBM) is reported. Impurity removal of carbon, oxygen, nitrogen, aluminum, iron, molybdenum, zirconium and tungsten in niobium matrix is presented as a part of the ingot melting stages. The minor material loss of niobium during melting is attributed to the amount of decarburization based on the ratio of initial and critical content of oxygen to carbon. The analysis of nearly 60 impurity elements in niobium was carried out by glow discharge mass spectrometry. In the end, the purity of niobium after multiple electron beam meltings was found to be 4N while the purity enhanced from 99.9 % (3N) to 99.993 % (4N3), including gaseous impurities, and 99.98 % (3N8) to 99.998 % (4N8) without gaseous impurities. The glow discharge mass spectrometry analytical results of purified niobium indicated that the material is suitable as input material for further processing of fabricated superconducting radio-frequency cavities.

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Authors and Affiliations

  1. Minerals Resource Research Division, Korea Institute of Geoscience & Mineral Resources, 92 Gwahangno, Yuseong-gu, Daejeon, 305-350, Korea

    Good-Sun Choi, Jae-Won Lim & N. R. Munirathnam

  2. Department of Materials Science and Engineering/ReSEM, Chungju National University, 72 Daehangno, Chungju-si, Chungbuk, 380-702, Korea

    Il-Ho Kim

  3. Ultrapure Materials Division, Centre for Materials for Electronics Technology (C-MET), IDA, Phase-III, Cherlapally, HCL Post, Hyderabad, 500051, India

    N. R. Munirathnam

Authors
  1. Good-Sun Choi
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  2. Jae-Won Lim
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  3. N. R. Munirathnam
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  4. Il-Ho Kim
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Correspondence to Good-Sun Choi.

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Choi, GS., Lim, JW., Munirathnam, N.R. et al. Purification of niobium by multiple electron beam melting for superconducting RF cavities. Met. Mater. Int. 15, 385–390 (2009). https://doi.org/10.1007/s12540-009-0385-0

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  • DOI: https://doi.org/10.1007/s12540-009-0385-0

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