Abstract
Fluoride is a colourless micro-nutrient which is highly required for the strong teeth and bones. The above and below the prescribed range (0.6–1.5 mg/l) of fluoride in drinking water is harmful or hazardous for human health. Granite gneiss and pegmatite are the natural sources of fluoride minerals in this North Singbhum Craton. Purulia district which is the extended part of Chhota Nagpur Gneissic complex hosts such fluoride bearing rocks and minerals. About 619 water samples were collected from different parts of the district. Different rock samples have been collected from exposed litho-strata with prominent geological structures through Garmin GPS Etrex 30x. Sample sites have been geocoded on SRTM DEM and rocks are tested in the laboratory to examine the concentration of fluoride ions. The study was conducted to identify the natural and anthropogenic sources of fluoride and find out the relationship among the fluoride, geology with structures, hydro-geomorphology, soil and aquifer. Lineament features have been extracted using different bands of two specific images, namely ETM and ASTER. Digital mapping techniques including spatial analysis are used to detect the geomorphological attributes using SRTM and ASTER DEM data with adequate ground verification. Finally, Fluoride Contamination Index (FCI) map has been prepared by Thomas L. Saaty (1984) Analytical Hierarchy Process (AHP) using weighted sum method (WSM) in the range between 1 and 10 on the basis of their percentage of contamination. The study shows that high and very high fluoride content (3.52–5.50 mg/l and more than 5.50 mg/l) is found in the undulating plateau with dissected valley while granite gneiss and pegmatite are the dominant fluoride bearing rocks. Fluoride minerals are being released from structural weak zones through various mobile agents and ultimately mixed into the soils and groundwater. The high and very high contaminated zones (37.79%) reveal moderate to good groundwater yield pockets of unconfined and semi-confined aquifers and larger population of these regions are exposed to fluoride vulnerability.
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References
Apambire WB, Boyle DR, Michel FA (1997) Geochemistry, genesis, and health implications of fluoriferous groundwaters in the upper regions of Ghana. Environ Geol 33(1):13–24. https://doi.org/10.1007/s002540050
Ayoob S, Gupta AK (2006) Fluoride in drinking water: a review on the status and stress effects. Crit Rev Environ Sci Technol 36(6):433–487. https://doi.org/10.1080/10643380600678112
Bera, B. (2018a) Jelajure Fluoride Samosa Asustho Gramer Par Gramer Manush, Dainik Statesman, A daily newspaper
Bera B (2018b) Fluoride Samoshyai Jerbar Purulia, Uttar Banga Sambad, A daily Regional Bengali Newspaper
Bera B, Bhattacharjee S, Ghosh A, Ghosh S, Chamling M (2019) Dynamic of channel potholes on Precambrian geological sites of Chhota Nagpur plateau, Indian peninsula: applying fluvio-hydrological and geospatial techniques. SN Applied Sciences 1(5):494–414. https://doi.org/10.1007/s42452-019-0516-2
Bhattachrya P, Jacks G, Gustafsson JP, Sracck A, Olofsson B, Aaltonen J, Khan AA, Akhtcr SH, & Ahmed KM (1999) High-arsenic groundwater in the alluvial aquifers of Bcngal Delta Plains in Bangladesh: genesis and low-cost remediation. KTH - Dhaka University Seminar on Groundwater Arsenic Contamination in the Bengal Delta Plains of Bangladesh, February 7-8, 1999. pp.6-9
Bishop M, & Shroder JF (2004) Geographic information science and mountain geomorphology. Springer Science & Business Media. https://books.google.co.in/books?hl=en&lr=&id=6TGu7-mwSNYC&oi=
Blaszczynski JS (1997) Landform characterization with geographic information systems. Photogramm Eng Remote Sens 63(2):183–191
Brindha K, & Elango L (2011) Fluoride in groundwater: causes, implications and mitigation measures. Fluoride properties, applications and environmental management, 1:111–136
Chae GT, Yun ST, Kwon MJ, Kim YS, Mayer B (2006) Batch dissolution of granite and biotite in water: implication for fluorine geochemistry in groundwater. Geochem J 40(1):95–102. https://doi.org/10.2343/geochemj.40.95
Datta PS, Deb DL, Tyagi SK (1996) Stable isotope (18O) investigations on the processes controlling fluoride contamination of groundwater. J Contam Hydrol 24(1):85–96. https://doi.org/10.1016/0169-7722(96)00004-6
Dunn JA (1942) Geology and petrology of eastern Singhbhum and surrounding areas. Mem Geol Surv India 69:261–456 https://ci.nii.ac.jp/naid/20000875781/#cit
Edmunds WM, & Smedley PL (2005) Fluoride in natural waters essentials of medical geology ed BJ Alloway and O Selinus
Farooqi A, Masuda H, Kusakabe M, Naseem M, Firdous N (2007) Distribution of highly arsenic and fluoride contaminated groundwater from East Punjab, Pakistan, and the controlling role of anthropogenic pollutants in the natural hydrological cycle. Geochem J 41(4):213–234. https://doi.org/10.2343/geochemj.41.213
Fawell J, Bailey K, Chilton J, Dahi E, & Magara Y (2006) Fluoride in drinking-water. IWA publishing. https://books.google.co.in/books?hl=en&lr=&id=7xu1yf-OC8oC&oi=
Gaciri SJ, Davies TC (1993) The occurrence and geochemistry of fluoride in some natural waters of Kenya. J Hydrol 143(3–4):395–412. https://doi.org/10.1016/0022-1694(93)90201-J
Gaumat MM, Rastogi R, Misra MM (1992) Fluoride level in shallow groundwater in central part of Uttar Pradesh. Bhu-Jal News 7(2):17–19
CGWB (1984) Report of the groundwater estimation committee. Central Ground Water Board (CGWB), Ministry of Water Resources, Government of India, New Delhi, India
Greenwood NN, Earnshaw A (2012) Chemistry of the elements. Elsevier https://books.google.co.in/books?hl=en&lr=&id=EvTI-ouH3SsC&oi=fnd&pg
Gillespie RJ, Humphries DA, Baird NC, Robinson EA (1989) Chemistry, second edn. Allyn and Bacon, Boston
Ghosh AK, & Talukdar T (1996) Hydrogeology of the hard rock aquifers in Purulia District, West Bengal—scope for sustainable management. Aquifer characteristics and groundwater management in eastern India, Proc. Sem., Department of Geological Sciences, Jadavpur University, Kolkata, March, 61–67
Haidouti C (1991) Fluoride distribution in soils in the vicinity of a point emission source in Greece. Geoderma 49(1–2):129–138. https://doi.org/10.1016/0016-7061(91)90096-C
Handa BK (1975) Geochemistry and genesis of Fluoride‐Containing ground waters in india. Groundwater 13(3):275–281. https://doi.org/10.1111/j.1745-6584.1975.tb03086.x
Handa BK (1988) Fluoride occurrence in natural waters in India and its significance. Bhu-Jal News 3(2):31–37
Hem, J. D., & Geological Survey (US). (1989). Study and interpretation of the chemical characteristics of natural water. https://pubs.usgs.gov/wsp/wsp2254/html/pdf.html
Hung LQ, Batelaan O, & De Smedt F (2005) Lineament extraction and analysis, comparison of LANDSAT ETM and ASTER imagery. Case study: Suoimuoi tropical karst catchment, Vietnam. In Remote Sensing for Environmental Monitoring, GIS Applications, and Geology V (Vol. 5983, p. 59830T). International Society for Optics and Photonics https://doi.org/10.1117/12.627699
Koritnig S (1978) Fluorine. In: Wedepohl KH (ed) Handbook of geochemistry, vol II/1. Sprin er, Berlin, pp 9-C-1 to B-9-O-3
Krauskopf KB, Bird DK (1995) An introduction to geochemistry. McGraw-Hill Int, Singapore, p 647
Kundu N, Panigrahi M, Tripathy S, Munshi S, Powell M, Hart B (2001) Geochemical appraisal of fluoride contamination of groundwater in the Nayagarh District of Orissa, India. Environ Geol 41(3–4):451–460. https://doi.org/10.1007/s002540100414
Matthess, G. (1982). The properties of ground-water (no. 551.49 M38)
Pickering WF (1985) The mobility of soluble fluoride in soils. Environmental Pollution Series B, Chemical and Physical, 9(4):281–308. https://doi.org/10.1016/0143-148X(85)90004-7
Mohapatra M, Anand S, Mishra BK, Giles DE, Singh P (2009) Review of fluoride removal from drinking water. J Environ Manag 91(1):67–77. https://doi.org/10.1016/j.jenvman.2009.08.015
Motalane MP, Strydom CA (2004) Potential groundwater contamination by fluoride from two South African phosphogypsums. Water SA 30(4):465–468. https://doi.org/10.4314/wsa.v30i4.5098
Mostafa ME, Zakir FA (1996) New enhancement techniques for azimuthal analysis of lineaments for detecting tectonic trends in and around the Afro-Arabian Shield. Int J Remote Sens 17(15):2923–2943. https://doi.org/10.1080/01431169608949119
Phan K, Sthiannopkao S, Kim KW, Wong MH, Sao V, Hashim JH, Mohamed Yasin MS, Aljunid SM (2010) Health risk assessment of inorganic arsenic intake of Cambodia residents through groundwater drinking pathway. Water Res 44(19):5777–5788. https://doi.org/10.1016/j.watres.2010.06.021
Rao NR, Rao N, Rao KSP, Schuiling RD (1993) Fluorine distribution in waters of Nalgonda district, Andhra Pradesh, India. Environ Geol 21(1–2):84–89. https://doi.org/10.1007/BF00775055
Rao NS (1997) The occurrence and behaviour of fluoride in the groundwater of the Lower Vamsadhara River basin, India. Hydrol Sci J 42(6):877–892. https://doi.org/10.1080/02626669709492085
Saha AK, Chakraborti C, De SAHADEB (1997) Studies of genesis of arsenic in groundwater in parts of West Bengal. Indian Soc Earth Sci 24:1–5
Shaji E, Bindu JV, Thambi DS (2007) High fluoride in groundwater of Palghat District, Kerala. Curr Sci 00113891:92(2)
Saaty TL (1984) The analytic hierarchy process: decision making in complex environments. In Quantitative Assessment in Arms Control (pp. 285–308). Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2805-6_12
Saxena V, Ahmed S (2003) Inferring the chemical parameters for the dissolution of fluoride in groundwater. Environ Geol 43(6):731–736. https://doi.org/10.1007/s00254-002-0672-2
Sikdar PK, Bhattacharya P (2000) Assessment and management of groundwater resources in Puruliya District, West Bengal. Indian J Geol 72(1):31–42
Smedley PL, Nicolli HB, Macdonald DMJ, Barros AJ, Tullio JO (2002) Hydrogeochemistry of arsenic and other inorganic constituents in groundwaters from La Pampa, Argentina. Appl Geochem 17(3):259–284. https://doi.org/10.1016/S0883-2927(01)00082-8
Wedepohl KH (1978) Handbook of geochemistry. Springer, Heidelberg
Who U (2001) UNU. Iron deficiency anaemia: assessment, prevention and control, a guide for programme managers. World Health Organization, Geneva
Young SM, Pitawala A, Ishiga H (2011) Factors controlling fluoride contents of groundwater in north-central and northwestern Sri Lanka. Environ Earth Sci 63(6):1333–1342. https://doi.org/10.1007/s12665-010-0804-z
Zakir FA, Qari MHT, Mostafa ME (1999) Technical note a new optimizing technique for preparing lineament density maps. https://doi.org/10.1080/014311699212858
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This work was funded by Indian Council of Social Science Research (ICSSR) Ministry of Human Resource Development, Government of India (Grant No.:- F. No. 02/299/2016-17/ICSSR).
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Bera, B., Ghosh, A. Fluoride dynamics in hydrogeological diversity and Fluoride Contamination Index mapping: a correlation study of North Singbhum Craton, India. Arab J Geosci 12, 802 (2019). https://doi.org/10.1007/s12517-019-4994-8
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DOI: https://doi.org/10.1007/s12517-019-4994-8