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Factors controlling fluoride contents of groundwater in north-central and northwestern Sri Lanka

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Abstract

Chemical characterization has been made of groundwater bodies at 294 locations in four village districts in north-central and northwestern Sri Lanka, with special focus on fluorine contamination. High fluoride contents in groundwater are becoming a major problem in the dry zone of Sri Lanka, and dental fluorosis and renal failures are widespread. Field measurements of temperature, pH, and electrical conductivity were made during sampling. Chemical analyses of the water samples were later made using atomic absorption spectroscopy, spectrophotometry, and titration. Fluoride concentrations in the study area vary from 0.01 to 4.34 mg/l, and depend on pH and the concentrations of Na, Ca, and HCO3 −. Basement rocks including hornblende biotite gneiss, biotite gneiss, and granitic gneiss seem to have contributed to the anomalous concentrations of fluoride in the groundwater. Longer residence time in aquifers within fractured crystalline bedrocks may enhance fluoride levels in the groundwater in these areas. In addition, elevated fluoride concentrations in shallow groundwater in intensive agricultural areas appear to be related to the leaching of fluoride from soils due to successive irrigation.

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References

  • Apambire WM, Boyle DR, Michel FA (1997) Geochemistry genesis and health implications of fluoriferous groundwaters in the upper regions of Ghana. Environ Geol 35(1):13–24

    Article  Google Scholar 

  • Arnesen AKM (1997) Fluoride solubility in dust emission from an aluminum smelter. J Environ Qual 26(6):1564–1570

    Article  Google Scholar 

  • Cooray PG (1994) The Precambrian of Sri Lanka: a historical review. Precambrian Res 66:3–18

    Article  Google Scholar 

  • Dahanayake K (1995) Geological and geochemical aspects of Eppawala and Ridigama phosphate deposits of Sri Lanka. In: Dahanayaka K, Van Kauwenbergh SJ, Hellums DT (eds) Proceedings of international workshop on direct application of phosphate rock and appropriate technology fertilizers in Asia—what hinders acceptance and growth. Institute of Fundamental Studies, Sri Lanka, pp 143–151

  • Dahanayke K, Senaratne A, Subasinghe SMND, Liyanaarachchi A (1991) Potential use of naturally occurring sulphuric acid to beneficiate poorly soluble phosphate from Eppawala Sri Lanka. Fert Res 29:197–201

    Article  Google Scholar 

  • Datta PS, Deb DL, Tyagi SK (1996) Stable isotope (18O) investigations on the processes controlling fluoride contamination of groundwater. J Contam Hydrol 24:85–96

    Article  Google Scholar 

  • Dharmagunawardhana HA (2004) Fluoride in groundwater surface water rocks and soils of an area of endemic fluorosis: in the dry zone of Sri Lanka. In: 4th international workshop on fluorosis prevention and defluoridation of water. Intercountry Center for Oral Health, Colombo, Sri Lanka

  • Dharmagunawardhane HA, Disanayake CB (1993) Fluoride problems in Sri Lanka. Environ Manage Health 4(2):9–16. doi:10.1108/09566169310033422

    Article  Google Scholar 

  • Dharmagunawardhane HA, Dissanayake CB (1991) Hydrogeochemistry of deep tube wells in the dry zone of Sri Lanka. In: The 2nd international symposium on the geology of Sri Lanka, Abstract 37

  • Dissanayake CB (1991) The fluoride problem in the groundwater in Sri Lanka—environmental management and health. Int J Environ Stud 38:137–156

    Article  Google Scholar 

  • Dissanayake CB, Weerasooriya SVR (1986) The hydrogeochemical atlas of Sri Lanka. Natural Resources Energy and Science Authority of Sri Lanka, pp 103

  • Edmunds WM, Smedley PL (2005) Fluoride in natural waters. In: Selinus O (ed) Essentials of medical geology. Elsevier, Burlington, pp 301–329

    Google Scholar 

  • Ekanayake L, Hoek WVD (2002) Dental caries and developmental defects of enamel in relation to fluoride levels in drinking water in an arid area of Sri Lanka. Caries Res 36:398–404

    Article  Google Scholar 

  • Falvey DA (1999) Groundwater geochemistry. Earthwise. British Geological Survey Magazine No. 13

  • Final Report for Groundwater Resource Assessment in the KOB (2004) Foundation and Water Well Engineering Private Limited

  • Gaus I, Shand P, Gale IN, Williams AT, Eastwood JC (2002) Geochemical modeling of fluoride concentration changes during aquifer storage and recovery (ASR) in the Chalk aquifer, Wessex, England. Q J Eng Geol Hydrogeol 35(2):203–208

    Article  Google Scholar 

  • Guo Q, Wang Y, Ma T, Ma R (2007) Geochemical processes controlling the elevated fluoride concentrations in groundwaters of the Taiyuan Basin, Northern China. J Geochem Explor 93:1–12

    Article  Google Scholar 

  • Herath KRPK, Ileperuma1 OA, Dharmagunawardhane HA, Haller KJ (2005) Environmental health risk for the chronic renal failure in Sri Lanka. In: 31st congress on science and technology of Thailand, Suranaree University of Technology

  • Jacks G, Bhattacharya P, Chaudhary V, Singh KP (2005) Controls on the genesis of some high-fluoride groundwater in India. Appl Geochem 20:221–228

    Article  Google Scholar 

  • Junco LI (1972) Renal failure and fluorosis. Fluorine and dental health. JAMA 222:783–785

    Google Scholar 

  • Kim K, Jeong GY (2005) Factors influencing natural occurrence of fluoride rich groundwaters: a case study in the southeastern part of the Korean Peninsula. Chemosphere 58(10):1399–1408

    Article  Google Scholar 

  • Kundu N, Panigrahi MK, Tripathy S, Munshi S, Powell MA, Hart BR (2001) Geochemical appraisal of fluoride contamination of groundwater in the Nayagarh District of Orrissa. Indian Environ Geol 41:451–460

    Google Scholar 

  • Maina JW, Gaciri SJ (1984) Contributions to the hydrogeochemistry of the area to the immediate north of Nairobi conservation area, Kenya. J Afr Earth Sci 2(3):227–232

    Google Scholar 

  • Manocha SL (1975) Cytochemical responses of kidney liver and nervous system to fluoride ions in drinking water. Histochem J 7:343–355

    Article  Google Scholar 

  • Murray JJ (1996) Appropriate use of fluorides for human health. World Health Organization, Geneva

    Google Scholar 

  • Nanyaro JT, Aswathanarayana U, Mungure JS (1984) A geochemical model for the abnormal fluoride concentrations in waters in parts of Northern Tanzania. J Afr Earth Sci 2(2):129–140

    Google Scholar 

  • Ozsvath DL (2006) Fluoride concentrations in a crystalline bedrock aquifer Marathon County. Wis Environ Geol 50:132–138

    Article  Google Scholar 

  • Panabokke CR, Perera APGRL (2005) Groundwater resources of Sri Lanka. Water Resources Board, Sri Lanka

    Google Scholar 

  • Parkhurst DL, Scott C, George NB (1996) Groundwater quality assessment of the central Oklahoma aquifer, Oklahoma—geochemical and geologic investigations. United States Geological Survey Water Supply Paper 2357

  • Pitawala A, Schidlowski M, Dahanayake K, Hofmeister W (2003) Geochemical and petrological characteristics of Eppawala phosphate deposits Sri Lanka. Miner Deposita 38:505–515

    Article  Google Scholar 

  • Pohl JR, Emmermann R (1991) Chemical composition of the Sri Lankan Precambrian basement. The crystalline crust of Sri Lanka. Part I. Summary of research of the German-Sri Lankan consortium. Geological Survey Department, Sri Lanka, pp 94–124

    Google Scholar 

  • Rao NS (2003) Groundwater quality: focus on fluoride concentration in rural parts of Guntur district Andhra Pradesh India. Hydrol Sci 48(5):835–847

    Article  Google Scholar 

  • Robertson FN (1986) Occurrence and solubility controls of trace elements in groundwater in the alluvial basins of Arizona. In: Anderson TW. Johnson AI (eds) Regional aquifer systems of the United States. Southwest Alluvial Basins of Arizona. American Water Resources Association Series No. 7

  • Rukah YA, Alsokhny K (2004) Geochemical assessment of groundwater contamination with special emphasis on fluoride concentration, North Jordan. Chem Erde 64:171–181

    Article  Google Scholar 

  • Saxena V, Ahmed S (2003) Inferring chemical parameters for the dissolution of fluoride in groundwater. Environ Geol 43(6):731–736

    Google Scholar 

  • Second Interim Report on Kala Oya Basin Comprehensive Plan (2002) River basin planning and management division, Mahaweli authority of Sri Lanka

  • Suma S, Latha SR, Ambika, Prasad SJ (1998) Fluoride contamination status of groundwater in Karnataka. http://www.ias.ac.in/currsci/mar25/articles13.htm

  • Teotia SPS, Teotia M (1988) Endemic skeletal fluorosis. Clinical and radiological variants. Fluoride 21:39–44

    Google Scholar 

  • Varner JA (1998) Chronic administration of aluminium-fluoride and sodium fluoride to rats in drinking water: alteration in neuronal and cerebrovascular integrity. Brain Res 784:284–298

    Article  Google Scholar 

  • Wang W, Li R, Tan J, Luo K, Yang L, Li H, Li Y (2002) Adsorption and leaching of fluoride in soils of China. Fluoride 35(2):122–129

    Google Scholar 

  • Warnakulasuriya KAAS, Balasuriya S, Pererra PAI (1990) Prevalence of dental fluorosis in four selected schools from different areas in Sri lanka. Ceylon Med J 35:125–128

    Google Scholar 

  • Weaver TR, Bahr JM (1991) Geochemical evolution in the Cambrian Ordovician sandstone aquifer eastern Wisconsin: 2. Correlation between flow paths and groundwater chemistry. Groundwater 29(4):510–515

    Google Scholar 

  • WHO (1984) Guide lines for drinking water quality. Health criteria and other supporting information, vol 12. World Health Organization, Geneva

  • WHO (1994) Fluorides and oral health. Technical report series No. 846. World Health Organization, Geneva

    Google Scholar 

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Acknowledgments

We gratefully acknowledge the National Science Foundation of Sri Lanka for financial assistance through grant NSF/RG/2005/W&E/01. We are also very grateful to Dr. H. A. Dharmagunawardhana for his advice and encouragement throughout this study, and to Mr. Tharanga Jayawardhana for his assistance during the field work. We are very much grateful for Dr. B. P. Roser for the valuable comments and the editorial assistance during the last stage of the manuscript.

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Authors and Affiliations

  1. Department of Geosciences, Shimane University, Matsue, 690-8504, Japan

    Sansfica M. Young & H. Ishiga

  2. Department of Geology, University of Peradeniya, Peradeniya, Sri Lanka

    A. Pitawala

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  1. Sansfica M. Young
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  2. A. Pitawala
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  3. H. Ishiga
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Correspondence to A. Pitawala.

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Young, S.M., Pitawala, A. & Ishiga, H. Factors controlling fluoride contents of groundwater in north-central and northwestern Sri Lanka. Environ Earth Sci 63, 1333–1342 (2011). https://doi.org/10.1007/s12665-010-0804-z

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