Abstract
One of the objectives of this work is to characterize marl samples collected from the bedrock aquifer (at 30 m depth) of Wadi Al Ghoula located in Draria southwest of Algiers. The other objective is to make a kinetics study, linear and non-linear isotherm study, and mass transfer study of the adsorption of copper onto marl in aqueous solution. The fitness of kinetics and isotherm models was evaluated by using some error analysis function. One of the major results using an XRF technique is an evidence of the presence of calcite in the weight of 13.82%. The XRD patterns of these samples confirmed the presence of montmorillonite, kaolinite, illite, calcite, and quartz. On the other hand, the FTIR analysis clarified the presence of calcite. The specific surface area of 20,999 m2/g was obtained using the BET, which indicates that the material has a predominance for the mesoporous character. The instrumental neutron activation analysis (INAA), a nondestructive method, gives the elemental composition of the adsorbent. Based on the value of the coefficient of determination, the adsorption kinetics of copper in aqueous solution using marl as adsorbent follows the pseudo-second-order model. And according to the value of the coefficient of determination obtained for the two models, the intraparticle diffusion and liquid film diffusion control the process of adsorption of copper onto marl with low predominance for the second model of diffusion in the first stage of adsorption. The linear and the non-linear treatments of the two-parameter isotherm models (Langmuir, Freundlish, Temkin) show that the fitting best model of isotherm is the empirical Freundlish isotherm. For the three-parameter isotherm models (Toth, Sips, and Redlish-Peterson), the Sips model is the more accurate fitting model than the two other isotherms in the non-linear approach. Some error analysis functions are used to choose the best results.
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References
Atanassova I, Okazaki M (1997) Adsorption-desorption characteristics of high levels of copper in soil clay fractions. Water, air and soil pollution. 98 213-228, © 1997 Kluwer Academic Publishers. Printed in the Netherlands.
Atia AA (2008) Adsorption of chromate and molybdate by cetypyridinium bentonite. Appl Clay Sci 41:73-84. https://doi.org/10.1016/j.clay.2007.09.011
Aytas S, Yurtlu M, Donat R (2009) Adsorption characteristic of U(VI) ion onto thermally active bentonite. J Hazard Mater 172:667-674. https://doi.org/10.1016/j.jhazmat.2009.07.049
Barakat MA (2011) New trends in removing heavy metals from industrial wastewater. Arab J Chem 4:361-377
Beltran JL, Pignatello JJ, Teixido M (2016) ISOT-Calc: a versatile tool for parameter estimation in sorption isotherms. Comput Geosci 94:11-17. https://doi.org/10.1016/j.cageo.2016.04.008
Bosch RF, Gimeno AJV, Moya MMCM (2002) FTIR quantitative analysis of calcium carbonate (calcite) and silica (quartz) mixtures using the constant ratio method. Appl Geol Samples Talanta 58:811-821
Bouhila Z, Mouzai M, Azeli T, Nedjar A, Mazouzi C, Zergoug Z, Boukhadra D, Chegrouche S, Lounici H (2015) Investigation of aerosol trace element concentrations nearby Algiers for environmental monitoring using instrumental neutron activation analysis. Atmos Res 166:49-59
Brown AM (2001) A step-by-step guide to non-linear regression analysis of experimental data using a Microsoft Excel spreadsheet. Comput Methods Prog Biomed 65:191-200
Camuzzi C, Polese P, Melchior A, Portanova R, Talazzi M (2003) SOLVERSTAT: a new utility for multipurpose analysis, an application to the investigation of deoxygenated Co(II) complex formation in dimethylsifxide solution. Talanta 59:67-80
Chen S, Shen W, Yu F, Wang H (2009) Kinetic and thermodynamic studies of adsorption of Cu2+ and Pb2+ onto amidoximated bacterial cellulose. Polym Bull 63:283-297. https://doi.org/10.1007/s00289-009-0088-1
Davidson CM (2013) Methods for the determination of heavy metals and metalloids in soils. In: Alloway BJ (ed) Heavy metals in soils: trace metals and metalloids in soils and their bioavailability, environmental pollution. 22. https://doi.org/10.1007/978-94-007-4470-7_4
Disli E (2010) Batch and column experiments to support heavy metals (Cu, Zn and Mn) in alluvial sediments. Chin J Geochem 29:365-374. https://doi.org/10.1007/s11631-010-0468-0
Encyclopedia of soil science (2008) Part of the series encyclopedia of soil science series, pp 446-446. https://doi.org/10.1007/978-1-4020-3995-9_341 © Springer Science+Business Media B.V. Springer Netherlands
Eren E, Afsin B (2008) An investigation of Cu(II) adsorption by raw and acid-activated bentonite: a combined potentiometric, thermodynamic, XRD, IR, DTA study. J Hazard Mater 151:682-691
Farrah H, Hatton D, Pickering WF (1980) The affinity of metal ions for clay surface. Chem Geol 28:55-68
Foo KY, Hameed BH (2010) Insights into the modeling of adsorption isotherm systems. Chem Eng J 156:2-9. https://doi.org/10.1016/j.cej.2009.09.013
Fredd CN, Fogler HS (1998) The kinetics of calcite dissolution in acetic acid solutions. Chem Eng Sci 53(22):3863-3874
Hamdaoui O (2006) Batch study of liquid-phase adsorption of methylene blue using cedar sawdust and crushed brick. J Hazard Mater B 135:264-373. https://doi.org/10.1016/j.jhazmet.200511.062
Hamidi AA, Adlan MN, Ariffin KS (2008) Heavy metals (Cd, Pb, Zn, Ni, Cu and Cr(III)) removal from water in Malaysia: post treatment by height quality limestone. Bioresour Technol 99:1578-1583
Henderson P, Pankhurst RJ (1984) Analytical chemistry. In: Henderson P (ed) Rare earth element geochemistry, volume 2. Elsevier, pp 467-499
Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34:451-465
Korichi S, Elias A, Mefti A (2009) Characterization of smectite after acid activation with microwave irradiation. Appl Clay Sci 42:432-438. https://doi.org/10.1016/j.clay.2008.04.014
Korkut O, Sayan E, Lacin O, Bayrak B (2010) Investigation of adsorption and ultrasound assisted desorption of lead (II) and copper (II) on local bentonite: a modelling study. Desalination 259:243-248. https://doi.org/10.1016/j.desal.2010.03.045
Kuila U, Prasad M (2013) Specific surface area and pore-size distribution in clays and shales. Geophys Prospect 61:341-362. https://doi.org/10.1111/1365-2478.12028
Lim S-F, Agnes Y, Lee W (2015) Kinetic study on removal of heavy metal ions from aqueous solution by using soil. Environ Sci Pollut Res 22:10144-10158. https://doi.org/10.1007/s11356-015-4203-6
Lopes CB, Lito PF, Cardoso SP, Pereira E, Duarte AC, Silva CM (2012) Metal recovery, separation and/or pre-concentration. In: Inamuddin, Luqman M (ed) Ion exchange technology II: applications. pp 237-322. https://doi.org/10.1007/978-94-007-4026-6_11 © Springer Science+Business Media B. V.
Lyubchik S, Lygina E, Lyubchyk A, Lyubchik S, Loureiro JM, Fonseca IM, Ribeiro A B, Pinto MM, Sa Agnes M (2016) The kinetic parameters evaluation for the adsorption process at liquid-solid interface. In: Ribeiro AB, et al. (ed) Electrokinetic across disciplines and continents. pp 81-109. https://doi.org/10.1007/978-3-319-20179-5_5 © Springer International Publishing Switzerland
Mahtab A, Lee SS, Sang-Eun O, Mohan D, Moon d H, Lee YH, Ok YS (2013) Modeling adsorption kinetics of trichloroethylene onto biochars derived from soybean stover and peanut shell wastes. Environ Sci Pollut Res 20:8364-8373. https://doi.org/10.1007/s11356-013-1676-z
Maramis V, Kurniawan A, Ayucitra A, Sunarso J, Ismadji SS (2012) Removal of copper ion from aqueous solution by adsorption using LABORATORIES-modified bentonite (organo-bentonite). Front Chem Sci Eng 6(1):58-66. https://doi.org/10.1007:s11705-011-1160-6
Mariangela Grassi, Gul Kaykioglu, Vincento Belgiorno, Guisy Lofrano (2012) removal of emerging contaminants from water and wastewater by adsorption process. In: Lofrano G (ed) Emerging compounds removal from wastewater. SpringBriefs in green Chemistery for Sustainability https://doi.org/10.1007/978-94-007-3916-1_2 © Grassi, Kaykioglu, Belgiorno, Lofrano
Menacer S, Lounis A, Guedioura B, Bayou N (2015) Uranium removal from aqueous solution by adsorption on Aleppo pine sawdust: modified by NaOH and irradiation. Desalin Water Treat. https://doi.org/10.1080/19443994.2015.1077475
Mohammed AS, Kapri A, Goe R (2011) Heavy metals pollution: source, impact and remedies. In: Khan MS, et al (ed) Biomanagement of metal-contaminated soils. Environ Pollut 20:1-28. https://doi.org/10.1007/978-94-007-1914-9_1
Mudhoo A, Garg VK, Wang S (2012) Heavy Metals: Toxicity and Removal by Biosorption In: E. Lichtfouse et al. (eds.) Environmental chemistry for a sustainable world : Volume 2: Remediation of Air and Water Pollution, pp 379-442. https://doi.org/10.1007/978-94-007-2439-6_10 © S^ringer Science+Business Media B. V.
Omorogie MO, Babalola JO, Unuabonah EI, Weiguo S, Gong Jian R (2016) Efficient chromium abstraction from aqueous solution using a low-cost biosorbent: Nauclea diderrichii seed biomass waste. J Saudi Chem Soc 20:49-57. https://doi.org/10.1016/j.jscs.2012.09.017
Preeti SN, Singh BK (2007) Instrumental characterization of clay by XRF, XRD and FTIR. Bull Mater Sci 30(3):235-238
Scragg JJ (2011) Electrodeposition of Metallic Precursors in: Copper zinc tin sulfide thin films for photovoltaics. Springer theses. https://doi.org/10.1007/978-3-642-22919-0_2 © Springer-Verlag Berlin Heidelberg
Sdiri AT, Higashi T, Jamoussi F (2014) Adsorption of copper and zinc onto natural clay single and binary systems. Int J Environ Sci Technol 11:1081-1092
Stefanova RY (2001) METAL REMOVAL BY THERMALLY ACTIVATED CLAY MARL. J Environ Sci Health Part A 36(3):293-306
Spiess Andrej-Nikolai, Neumeyer Nathalie (2010) An evaluation of R2 as an inadequate measure for nonlinear models in pharmacological and biochemical research: a Monte Carlo approach. Spiess and Neumeyer BMC Pharmacology 10-6 http://www.biomedcentral.com/1471-2210/10/6
Wang L (2013) Removal of disperse red dye by bomboo-based activated carbon: optimization, kinetic and equilibrium. Environ Sci Pollut Res 20:4635-4646. https://doi.org/10.1007/s11356-012-1421-z
Wu K-T, Wu P-H, Wu F-C, Ru-Ling J, Ruey-Shin J (2013) A novel approach to characterizing liquid-phase adsorption on highly porous activated carbons using the Toth equation. Chem Eng J 221:373-381. https://doi.org/10.1016/j.cej.201302.012
Wu XL, Donglin Z, Yang ST (2011) Impact of solution chemistry conditions on the sorption behavior of Cu(II) on Lin’an montmorillonite. Desalination 269:84-91. https://doi.org/10.1016/j.desal.2010.10.046
Yang X, Al-Duri B (2001) Application of branched pore diffusion model in the adsorption of reactive dyes on activated carbon. Chem Eng J 83:15-23
Zamzow MJ, Murphy JE (1992) Removal of metal cations from water using zeolites. Sep Sci Technol 27:1969-1984. https://doi.org/10.1080/01496399208019459
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Bellaloui, M., Metouchi, A., Foukrache, A. et al. Retention of a heavy metal by marl collected from aquifer substratum. Arab J Geosci 10, 425 (2017). https://doi.org/10.1007/s12517-017-3177-8
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DOI: https://doi.org/10.1007/s12517-017-3177-8