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Rare earth element distribution in tropical coastal wetland sediments: a case study from Vembanad estuary, southwest India

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Abstract

Rare earth element (REE) geochemistry of sediments from Vembanad Coastal Wetland, southwest India, shows that light rare earth elements (LREEs) are the more abundant compared to middle rare earth element (MREE) and heavy rare earth element (HREE). We suggest that the textural parameters and the biochemical processes lead to the REE variation in this coastal wetland environment. Variations in the REE abundance are mainly controlled by the source materials deposited by riverine input. REE records in sediments showed spatial heterogeneity due to the influence of the physico-chemical conditions like, sedimentological conditions, salinity and depositional flux of the sediments along the wetland. Enriched values observed along the northern and southern stations are due to the increased riverine input. The REE ratios and enrichment factor values suggest that the abundance is in the order of LREE > MREE > HREE. Positive Eu anomaly is linked to the source sediments brought down from the catchment areas of the Periyar River and Muvattupuzha River. However, Ce anomaly suggests no significant variation in the oxidation condition at the sites of deposition.

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References

  • Abdulla Bava K (1996) Geochemistry of interstitial waters and sediments of Vembanad estuary, Kerala, India. Ph.D Thesis. Cochin University of Science and Technology, Cochin

    Google Scholar 

  • Allen P, Condie KC, Narayana BL (1985) The geochemistry of prograde and retrograde charnockite-gneiss reactions in southern India. Geochim Cosmochim Acta 49:323–336

    Article  Google Scholar 

  • Babu KN, Ouseph PP, Padmalal D (2000) Interstitial water sediment geochemistry of N, P and Fe and its response to overlying waters of tropical estuaries: a case from the southwest coast of India, Cases and solutions. Environ Geol 39:633–640

    Article  Google Scholar 

  • Balachandran KK, Laluraj CM, Nair M, Joseph T, Sheeba P, Venugopal P (2005) Heavy metal accumulation in a flow restricted, tropical estuary. Estuar Coast Shelf Sci 65:361–370

  • Bau M (1991) Rare-earth element mobility during hydrothermal and metamorphic fluid-rock interaction and the significance of the oxidation state of europium. Chem Geol 93:219–230

    Article  Google Scholar 

  • Bau M, Dulski P (1996) Distribution of yttrium and rare-earth elements in the Penge and Kuruman iron-formations, Transvaal Supergroup, South Africa. Precambrian Res 79(1–2):37–55

    Article  Google Scholar 

  • Bock B, McLennan SM, Hanson GN (1994) Rare earth element redistribution and its effects on the neodymium isotope system in the Austin Glen Member of the Normanskill Formation, New York, USA. Geochim Cosmochim Acta 58(23):5245–5253

    Article  Google Scholar 

  • Bowen H (1979) Environmental geochemistry of the elements. Academic Press, New York, p 333

    Google Scholar 

  • Braun JJ, Pagel M, Muller JP, Bilong P, Michard A, Guillet B (1990) Cerium anomalies in lateritic profiles. Geochim Cosmochim Acta 54:781–795

    Article  Google Scholar 

  • Brookins DG, (1989) Aqueous geochemistry of rare earth elements. In: Lipin, B.R., McKay, G.A. (Eds.), Geochemistry and Mineralogy of Rare Earth Elements. Reviews in Mineralogy. Mineral Soc America: 201–225

  • Censi P (2007) The behavior of REEs in Thailand’s Mae Kong estuary: suggestions from the Y/Ho ratios and lanthanide tetrad effects. Estuar Coast Shelf Sci 71:569–579

    Article  Google Scholar 

  • Chaillou G, Anschitz P, Lavaux G, Blanc G (2006) Rare earth elements in the modern sediments of the Bay of Biscay (France). Mar Chem 100:39–52

    Article  Google Scholar 

  • Coppin F, Berger G, Bauer A, Caslet S, Loubet M (2002) Sorption of lanthanides on smectite and kaolinite. Chem Geol 182:57–68

    Article  Google Scholar 

  • Cullers RL, Barett T, Carlson R, Robinson B (1987) Rare earth element and mineralogical changes in Holocene soil and stream sediments: a case study in the Wet Mountains, Colorado, USA. Chem Geol 63:275–297

    Article  Google Scholar 

  • Cullers RL, Basu A, Suttner LJ (1988) Geochemical signature of provenance in sand size materials in soils and stream sediments near the Tobacco Root Batholith, Montana, U.S.A. Chem Geol 70:335–348

    Article  Google Scholar 

  • Deepulal PM, Gireesh Kumar TR, Sujatha CH (2012) Behaviour of REEs in a tropical estuary and adjacent continental shelf of southwest coast of India: evidence from anomalies. J Earth Syst Sci 121:1215–1227

    Article  Google Scholar 

  • Deepulal PM, Sujatha CH, Gireesh Kumar TR (2014) Distribution of REEs along continental shelf of south west India. Indian J Mar Sci 43(1):96–105

    Google Scholar 

  • DeGroot AJ, DeGoeij JJM, Zegers C (1971) Contents and behaviour of mercury as compared with other heavy metals in sediments from the rivers Rhine and Ems. Geol Mijnbouw 50:393–398

    Google Scholar 

  • Dinesh Kumar PK, Sankaranarayanan VN, Saraladevi K (1994) Cochin backwaters: an introduction to the system, prior studies, historical trends and future implications. Indian J Environ Prot 14:98–102

  • Dipu S, Kumar AA (2013) Distribution of mercury and other trace metals in the sediments of Cochin estuary (a Ramsar site), Kerala, India. Environ Monit Assess 185(8):33–41. doi:10.1007/s10661-012-3028-8

    Article  Google Scholar 

  • Douville E, Bienvenu P, Charlou JL, Donval JP, Fouquet Y, Appriou P, Gamo T (1999) Yttrium and rare earth elements in fluids from various deep-sea hydrothermal systems. Geochim Cosmochim Acta 63:627–643

    Article  Google Scholar 

  • Dubinin AV (2004) Geochemistry of rare earth elements in the ocean. Lithol Miner Resour 39:289–307

    Article  Google Scholar 

  • Elderfield H, Greaves MJ (1982) The rare earth elements in seawater. Nature 296(5854):214–219

    Article  Google Scholar 

  • Elderfield H, Upstill-Goddard R, Sholkovitz ER (1990) The rare earth elements in rivers, estuaries, and coastal seas and their significance to the composition of the ocean waters. Geochim Cosmochim Acta 54:971–991

    Article  Google Scholar 

  • Fleet AJ (1984) Aqueous and sedimentary geochemistry of the rare earth elements. In: Henderson P (ed) Rare earth element geochemistry. Developments in geochemistry. Elsevier, Amsterdam, pp 343–373

    Chapter  Google Scholar 

  • Gallello G, Pastor A. Diez A, Bernabeu J (2014) Lanthanides revealing anthropogenic impact within a stratigraphic sequence. Journal of Archaeology, 767085: http://dx.doi.org/10.1155/2014/767085.

  • German CR, Elderfield H (1990) Application of the Ce anomaly as a paleoredox indicator: the ground rules. Paleoceanography 5(5):823–833

    Article  Google Scholar 

  • Gromet LP, Dymek RF, Haskin LA, Korotev RL (1984) The North American shale composite: its compilation, major and trace element characteristics. Geochim Cosmochim Acta 48:2469–3482

    Article  Google Scholar 

  • Hannigan R, Dorval E, Jones C (2010) The rare earth element chemistry of estuarine surface sediments in the Chesapeake Bay. Chem Geol 272:20–30

    Article  Google Scholar 

  • Henderson P (1984) Rare earth element geochemistry. Elsevier, Amsterdam, Oxford, 510

    Google Scholar 

  • Jung HS, Lim D, Choi JY, Yoo HS, Rho KC, Lee HB (2012) REE compositions of core sediments from the shelf of the South sea, Korea; their controls and origins. Cont Shelf Res 48:75–86

    Article  Google Scholar 

  • Kennish MJ (1986) Ecology of estuaries: physical and chemical aspects, volume 1. CRC Press, Inc., Boca Raton

    Google Scholar 

  • Kennish MJ (2002) Environmental threats and environmental future of estuaries. Environ Conserv 29:78–107

    Article  Google Scholar 

  • Kuss J, Garbe-Schönberg D, Kremling K (2001) Rare earth elements in suspended particulate material of North Atlantic surface waters. Geochim Cosmochim Acta 65(2):187–199

    Article  Google Scholar 

  • Laluraj CM (2009) Geochemistry of transition non-transition and rare-earth elements in the surficial sediments of continental shelf of Kerala and an annex to the Cochin estuarine system. Ph.D. Thesis. Cochin University of Science and Technology, Cochin

    Google Scholar 

  • Lamb AL, Vane CH, Wilson GP, Rees JG, Moss-Hayes VL (2007) Assessing δ13C and C/N ratios from organic material in archived cores as Holocene sea level and palaeoenvironmental indicators in the Humber estuary, UK. Mar Geol 244:109–128

    Article  Google Scholar 

  • Lawrence MG, Kamber BS (2006) The behaviour of the rare earth elements during estuarine mixing—revisited. Mar Chem 100:147–161

    Article  Google Scholar 

  • Mallik TK, Vasudevan P, Varghesse B, Terry M (1987) The black sand placer deposits of Kerala beach, southwest India. Mar Geol 77:129–150

    Article  Google Scholar 

  • Martin JM, Hogdahl O, Phillippot JC (1976) Rare earth element supply to the oceans. J Geophys Res 81:3119–3124

    Article  Google Scholar 

  • Martin, GD, Rejomon George, Shaiju P, Muraleedharan, KR, Nair, SM, Chandramohanakumar, N (2012) Toxic metals enrichment in the surficial sediments of a eutrophic tropical estuary (Cochin Backwaters, Southwest Coast of India), Scientific World Journal. doi: 10.1100/2012/972839

  • Mascarenhas-Pereira MBL, Nath BN (2010) Selective leaching studies of sediments from a seamount flank in the central Indian basin: resolving hydrothermal, volcanogenic and terrigenous sources using major, trace and rare-earth elements. Mar Chem 121(1–4):49–66

    Article  Google Scholar 

  • McLennan SM (1989) Rare earth elements in sedimentary rocks: influence of provenance and sedimentary processes. In: Lipin BR, McKay GA (eds) Geochemistry and mineralogy of rare earth elements, vol 21, Mineralogical Society of America, Rev Mineral., pp 169–200

    Google Scholar 

  • Munksgaard NC, Lim K, Parry DL (2003) Rare earth elements as provenance indicators in North Australian estuarine and coastal marine sediments. Estuar CoastShelf S 57:399–409

    Article  Google Scholar 

  • Nair SM, Balchand AN, Nambisan PNK (1993) Phosphate fractionation in mud bank sediments from the southwest coast of India. Hydrobiologia 252:61–69

    Article  Google Scholar 

  • Nath BN, Kunzendorf H, Pluger WL (2000) Influence of provenance, weathering and sedimentary processes on the elemental ratios of the fine-grained fraction of the bedload sediments from the Vembanad Lake and the adjoining continental shelf, southwest coast of India. J Sediment Res 70(5):1081–1094

    Article  Google Scholar 

  • Nesbitt HW (1979) Mobility and fractionation of rare earth elements during weathering of a granodiorite. Nature 279(5710):206–210

    Article  Google Scholar 

  • Nozaki Y, Lerche D, Alibo DS, Snidvongs A (2000) The estuarine geochemistry of rare earth elements and indium in the Chao Phraya River, Thailand. Geochim Cosmochim Acta 64:3983–3991

    Article  Google Scholar 

  • Padmalal P, Seralathan P (1994) Textural studies of the surficial sediments of Muvattupuzha River and central Vembanad estuary, Kerala. J Geol Soc India 43:179–190

    Google Scholar 

  • Padmalal D, Maya K, Seralathan P (1997) Geochemistry of Cu, Co, Ni, Zn, Cd and Cr in the surficial sediments of a tropical river and estuary, south west coast of India. A granulometric approach. Environment Geol 31:85–93

    Article  Google Scholar 

  • Pattan JN, Masuzawa T, Borole DV, Parthiban G, Jauhari P, Yamamoto M (2005) Biological productivity, terrigenous influence and noncrustal elements supply to the central Indian Ocean Basin; Paleoceanography during the past 1 Ma. J Earth Syst Sci 114:63–74

    Article  Google Scholar 

  • Paul SK (2001) Geochemistry of bottom sediments from a river-estuary-shelf mixing zone on the tropical southwest coast of India. B Geol Surv Japan 52(8):371–382

    Article  Google Scholar 

  • Pereira AA, van Hattum B, Brouwer A, van Bodegom PM, Rezende CE, Salomons W (2008) Effects of iron-ore mining and processing on metal bioavailability in a tropical coastal lagoon. J Soils Sediments 8:239–252

    Article  Google Scholar 

  • Piper DZ (1974) Rare earth elements in the sedimentary cycle: a summary. Chem Geol 14:285–304

    Article  Google Scholar 

  • Piper DZ, Bau M (2013) Normalized rare earth elements in water, sediments, and wine: identifying sources and environmental redox conditions. Am J Analytic Chem 4:69–83

    Article  Google Scholar 

  • Prasad MBK, Ramanathan A (2008) Distribution of rare earth elements in the Pichavaram mangrove sediments of the southeast coast of India. J Coast Res 24(1A):126–134

    Article  Google Scholar 

  • Priju CP, Narayana AC (2006) Spatial and temporal variability of trace element concentrations in a tropical Lagoon, Southwest Coast of India: environmental implications. J Coast Res 39:1053–1057

  • Priju CP, Narayana AC (2007) Particle size characterization and Late Holocene depositional processes in Vembanad lagoon, Kerala: inferences from suite statistics. J Geol Soc India 69:311–318

    Google Scholar 

  • Ramesh R, Ramanathan AL, James RA, Subramanian V, Jacobsen S, Holland H (1999) Rare earth elements and heavy metal distribution in estuarine sediments of east coast of India. Hydrobiologia 397:89–99

    Article  Google Scholar 

  • Riedel GF, Sanders JG, Osman RW (1999) Biogeochemical control on the flux of trace elements from estuarine sediments: effects of seasonal and short-term hypoxia. Mar Environ Res 47:349–372

    Article  Google Scholar 

  • Rodriguez CA, Flessa KW, Dettman DL (2001) Effects of upstream diversion of Colorado River water on the Estuarine Bivalve Mollusc Mulinia coloradoensis. Conserv Biol 15:249–258

    Article  Google Scholar 

  • Rollinson H (1993) Using geochemical data: evaluation, presentation, interpretation. Longman Scientific & Technical, Essex, 352

    Google Scholar 

  • Sappal SM, Ramanathan AL, Ranjan RK, Singh G, Kumar A (2014) Rare earth elements as biogeochemical indicators in mangrove ecosystems (Pichavaram, Tamil Nadu, India). J Sediment Res 84:781–791

    Article  Google Scholar 

  • Selvam, AP, Priya, SL, Banerjee, K, Hariharan, G, Purvaja, R, Ramesh, R (2011) Heavy metal assessment using geochemical and statistical tools in the surface sediments of Vembanad Lake, Southwest Coast of India. EnvironMonit Assess 184(10)5: 899–915. doi: 10.1007/s10661-011-2389-8

  • Sholkovitz ER (1990) Rare earth elements in marine sediments and geochemical standards. Chem Geol 88:333–347

    Article  Google Scholar 

  • Sholkovitz ER (1993) The geochemistry of rare earth elements in the Amazon River estuary. Geochim Cosmochim Acta 57:2181–2190

  • Sholkovitz ER (1995) The aquatic chemistry of rare earth elements in rivers and estuaries. Aquat Geochem 1:1–34

    Article  Google Scholar 

  • Sholkovitz ER, Elderfield H (1988) Cycling of dissolved rare earth elements in Chesapeake Bay. Global Biogeochem Cy 2:157–176

    Article  Google Scholar 

  • Sholkovitz E, Elderfield H, Szymczak R, Casey K (1999) Island weathering: river sources of rare earth elements to the Western Pacific Ocean. Mar Chem 68:39–57

    Article  Google Scholar 

  • Shynu R, Rao VP, Kessarkar PM, Rao TG (2011) Rare earth elements in suspended and bottom sediments of the Mandovi estuary, central west coast of India: influence of mining. Estuar Coast Shelf Sci 94:355–368

  • Shynu R, Rao VP, Parthiban G, Balakrishnan S, Narvekar T, Kessarkar PM (2013) REE in suspended particulate matter and sediment of the Zuari estuary and adjacent shelf, western India: influence of mining and estuarine turbidity. Mar Geol 346:326–342

    Article  Google Scholar 

  • Singh P, Rajamani V (2001) REE geochemistry of recent clastic sediments from the Kaveri floodplains, Southern India: implication to source area weathering and sedimentary processes. Geochim Cosmochim Acta 65:3093–3108

    Article  Google Scholar 

  • Soman K (2002) Geology of Kerala, textbook series. Geol Soc India, Calcutta, p 270

    Google Scholar 

  • Taylor SR, McLennan SM (1985) The continental crust: its composition and evolution. Blackwell Scientific Publication, Carlton, p 312

    Google Scholar 

  • Taylor SR, McLennan SM (1995) The geochemical evolution of the continental crust. Rev Geophys 33:241–265

    Article  Google Scholar 

  • Toyoda K, Nakamura Y, Masuda A (1990) Rare earth elements of Pacific pelagic sediments. Geochim Cosmochim Acta 54:1093–1103

    Article  Google Scholar 

  • Tyler G (2004) Rare earth elements in soil and plant systems—a review. Plant Soil 267:191–206

    Article  Google Scholar 

  • Verma A, Subramanian V, Ramesh R (2002) Methane emissions from a coastal lagoon: Vembanad Lake, West Coast. India Chemosphere 47:883–889

    Article  Google Scholar 

  • Wasserman JC, Oliveira FBL, Bidarra M (1998) Cu and Fe associated with humic acids in sediments of a tropical coastal lagoon. Organ Geochem 28:813–822

    Article  Google Scholar 

  • Welch SA, Christy AG, Issacson L, Kriste D (2009) Mineralogical control of rare earth elements in acid sulfate soils. Geochim Cosmochim Acta 73(1):44–64

    Article  Google Scholar 

  • Windom HL, Schropp SJ, Calder FD, Ryan JD, Smith RG Jr, Burney LC, Lewis FG, Rawlinson CH (1989) Natural trace metal concentrations in estuarine and coastal marine sediments of the southeastern United States. Environ Sci Technol 23:314–320

    Article  Google Scholar 

  • Yang SY, Jung HS, Choi MS, Li CX (2002) The rare earth element compositions of the Changjiang (Yangtze) and Huanghe (Yellow) river sediments. Earth Planet Sci Lett 201:407–419

    Article  Google Scholar 

  • Zhang H, Zhang WX, Chang FQ, Yang LQ, Lei GL, Yang MS, Pu Y, Lei YB (2009) Geochemical fractionation of rare earth elements in lacustrine deposits from Qaidam basin. Sci China ser D Earth Sci 52(11):1703–1713

    Article  Google Scholar 

  • Zhong LW, Liu CQ (2008) Geochemistry of rare earth elements in the dissolved, acid-soluble and residual phases in surface waters of the Changjiang estuary. J Oceanogr 64:407–416

    Article  Google Scholar 

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Acknowledgments

The authors are grateful to the Director, Birbal Sahni Institute of Palaeobotany (BSIP), India, for providing the funds, support and facilities extended. We are thankful to Dr. Thamban Meloth, B.L. Redkar, and Ashish Painginkar, National Centre for Antarctic and Ocean Research (NCAOR), India, for the timely help in carrying out the geochemical analysis work at their ICP-MS and TOC analyzer facility. This is BSIP contribution No. BSIP/RDCC/69/2014-15.

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Manoj, M.C., Thakur, B. & Prasad, V. Rare earth element distribution in tropical coastal wetland sediments: a case study from Vembanad estuary, southwest India. Arab J Geosci 9, 197 (2016). https://doi.org/10.1007/s12517-015-2246-0

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