Skip to main content

Advertisement

Log in

Soil and groundwater quality with reference to nitrate in a semiarid agricultural region

  • Original Paper
  • Published:
Arabian Journal of Geosciences Aims and scope Submit manuscript

Abstract

Nitrate is a common pollutant in surface water and groundwater of agricultural areas. It is essential to monitor this pollutant in groundwater, especially when it is used for drinking purposes without treatment. The present study was carried out in an intensively irrigated area which forms a part of Nalgonda district, Andhra Pradesh, India where groundwater meets all the water needs of the rural population living in this area. The objective was to assess the spatiotemporal variation in the concentration of nitrate in groundwater and soil. Based on the analysis of 496 groundwater samples collected from 45 wells over a period of 2 years from March 2008 to January 2010 by sampling every 2 months, it was observed that groundwater in 242 km2 of the total 724 km2 area had nitrate above the maximum permissible limit of 45 mg/l for drinking purposes. Nitrate concentration in groundwater showed a positive relation with potassium, chloride, and sulfate, indicating their source from fertilizers. Reasons for the high concentration of nitrate in domestic areas were the dumping of animal wastes and leakage from septic tanks. The pH of the soil samples showed that most of the area had basic soil. Apart from pH, organic carbon, available phosphorous, available potassium, ammoniacal nitrogen, and nitrate nitrogen were also analyzed in the 97 soil samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14

Similar content being viewed by others

References

  • Almasri MN, Kaluarachchi JJ (2007) Modeling nitrate contamination of groundwater in agricultural watersheds. J Hydrol 343:211–229

    Article  Google Scholar 

  • Avtar R, Kumar P, Surjan A, Gupta LN, Roychowdhury K (2013) Geochemical processes regulating groundwater chemistry with special reference to nitrate and fluoride enrichment in Chhatarpur area, Madhya Pradesh, India. Environ Earth Sci. doi:10.1007/s12665-013-2257-7

    Google Scholar 

  • Baily A, Rock L, Watson CJ, Fenton O (2011) Spatial and temporal variations in groundwater nitrate at an intensive dairy farm in south-east Ireland: insights from stable isotope data. Agric Ecosyst Environ 144:308–318

    Article  Google Scholar 

  • BIS (Bureau of Indian Standards) (2003) Specification for drinking water, IS:10500:91. Revised 2003, Bureau of Indian Standards, New Delhi

  • Bouwer H (1990) Agricultural chemicals and groundwater quality. J Soil Water Conserv 45:184–189

    Google Scholar 

  • Brindha K, Rajesh R, Murugan R, Elango L (2010) Natural and anthropogenic influence on the fluoride and nitrate concentration of groundwater in parts of Nalgonda district, Andhra Pradesh, India. J Appl Geochem 12(2):231–241

    Google Scholar 

  • Canter LW (1997) Nitrate in groundwater. Lewis, New York, p 263

    Google Scholar 

  • CGWB (Central Ground Water Board) (2007) Ground water information Nalgonda district Andhra Pradesh. Available at http://cgwb.gov.in/District_Profile/AP/Nalgonda.pdf. Accessed 10 July 2011

  • Chen X, Wu H, Wo F (2007) Nitrate vertical transport in the main paddy soils of Tai Lake region. China Geoderma 142:136–141

    Article  Google Scholar 

  • Dan-Hassan MA, Olasehinde PI, Amadi AN, Yisa J, Jacob JO (2012) Spatial and temporal distribution of nitrate pollution in groundwater of Abuja, Nigeria. Int J Chem 4(3):104–112

    Article  Google Scholar 

  • Dar IA, Dar MA, Sankar K (2010) Nitrate contamination in groundwater of Sopore town and its environs, Kashmir, India. Arab J Geosci 3(3):267–272

    Article  Google Scholar 

  • Dar IA, Sankar K, Shah TS, Dar MA (2012) Assessment of nitrate contamination of Lidder catchment Kashmir, India. Arab J Geosci 5(2):233–243

    Article  Google Scholar 

  • Darwish T, Atallah T, Francis R, Saab C, Jomaa I, Shaaban A, Sakka H, Zdruli P (2011) Observations on soil and groundwater contamination with nitrate: a case study from Lebanon–East Mediterranean. Agricultural Water Management 99:74–84

    Article  Google Scholar 

  • Elango L, Brindha K, Kalpana L, Sunny F, Nair RN, Murugan R (2012) Groundwater flow and radionuclide decay-chain transport modelling around a proposed uranium tailings pond in India. Hydrogeol J 20(4):797–812

    Article  Google Scholar 

  • Enwright N, Hudak PF (2009) Spatial distribution of nitrate and related factors in the High Plains Aquifer. Texas Environmental Geology 58:1541–1548

    Article  Google Scholar 

  • ESRI (Environmental Systems Research Institute) (2007) ArcGIS 9.3 Software and user manual. Environmental Systems Research Institute, Redlands

  • Flipo N, Jeannée N, Poulin M, Even S, Ledoux E (2007) Assessment of nitrate pollution in the Grand Morin aquifers (France): combined use of geostatistics and physically based modeling. Environ Pollut 146:241–256

    Article  Google Scholar 

  • Gemitzi A, Petalas C, Pisinaras V, Tsihrintzis VA (2009) Spatial prediction of nitrate pollution in groundwaters using neural networks and GIS: an application to South Rhodope aquifer (Thrace, Greece). Hydrol Processes 23:372–383

    Article  Google Scholar 

  • GSI (Geological Survey of India) (1995) Geology and minerals map of Nalgonda district. Andhra Pradesh, India

  • Gupta SK, Gupta RC, Chhabra SK, Eskiocak S, Gupta AB, Gupta R (2008) Health issues related to N pollution in water and air. Curr Sci 94(11):1469–1477

    Google Scholar 

  • Hu K, Huang Y, Li H, Li B, Chen D, White RE (2005) Spatial variability of shallow groundwater level, electrical conductivity and nitrate concentration, and risk assessment of nitrate contamination in North China Plain. Environ Int 31:896–903

    Article  Google Scholar 

  • Huang J, Xu J, Liu X, Liu J, Wang L (2011) Spatial distribution pattern analysis of groundwater nitrate nitrogen pollution in Shandong intensive farming regions of China using neural network method. Math Comput Model 54(3–4):995–1004

    Article  Google Scholar 

  • Jalali M (2005) Nitrates leaching from agricultural land in Hamadan, western Iran. Agric Ecosyst Environ 110:210–218

    Article  Google Scholar 

  • Journel AG (1983) Non-parametric estimation of spatial distribution. Math Geol 15:445–468

    Article  Google Scholar 

  • Kuhr P, Haider J, Kreins P, Kunkel R, Tetzlaff B, Vereecken H, Wendland F (2013) Model based assessment of nitrate pollution of water resources on a federal state level for the dimensioning of agro-environmental reduction strategies: the North Rhine-Westphalia (Germany) case study. Water Resources Management 27:885–909

    Article  Google Scholar 

  • Kurunc A, Ersahin S, Uz BY, Sonmez NK, Uz I, Kaman H, Bacalan GE, Emekli Y (2011) Identification of nitrate leaching hot spots in a large area with contrasting soil texture and management. Agricul Water Manag 98:1013–1019

    Article  Google Scholar 

  • Lake IR, Lovett AA, Hiscock KM, Betson M, Foley A, Sünnenberg G, Evers S, Fletcher S (2003) Evaluating factors influencing groundwater vulnerability to nitrate pollution: developing the potential of GIS. J Environ Manage 68:315–328

    Article  Google Scholar 

  • Lasserre F, Razack M, Banton O (1999) A GIS-linked model for the assessment of nitrate contamination in groundwater. J Hydrol 224:81–90

    Article  Google Scholar 

  • Ledoux E, Gomez E, Monget JM, Viavattene C, Viennot P, Ducharne A, Benoit M, Mignolet C, Schott C, Mary B (2007) Agriculture and groundwater nitrate contamination in the Seine basin. The STICS–MODCOU modelling chain. Sci Total Environ 375:33–47

    Article  Google Scholar 

  • Lee SM, Min KD, Woo NC, Kim YJ, Ahn CH (2003) Statistical models for the assessment of nitrate contamination in urban groundwater using GIS. Environ Geol 44:210–221

    Google Scholar 

  • Leeper GW, Uren NC (1993) Soil science, an introduction, 5th edn. Melbourne University Press, Melbourne, ISBN 0-522-84464-2

    Google Scholar 

  • Li SL, Liu CQ, Li J, Xue Z, Guan J, Lang Y, Ding H, Li L (2013) Evaluation of nitrate source in surface water of southwestern China based on stable isotopes. Environ Earth Sci 68:219–228

    Article  Google Scholar 

  • Liao L, Green CT, Bekins BA, Böhlke JK (2012) Factors controlling nitrate fluxes in groundwater in agricultural areas. Water Resour Res 48:W00L09. doi:10.1029/2011WR011008

    Article  Google Scholar 

  • Liu GD, Wu WL, Zhang J (2005) Regional differentiation of non-point source pollution of agriculture-derived nitrate nitrogen in groundwater in northern China. Agric Ecosyst Environ 107:211–220

    Article  Google Scholar 

  • Morari F, Lugato E, Polese R, Berti A, Giardini L (2012) Nitrate concentrations in groundwater under contrasting agricultural management practices in the low plains of Italy. Agric Ecosyst Environ 147:47–56

    Article  Google Scholar 

  • Nas B, Berktay A (2006) Groundwater contamination by nitrates in the city of Konya, (Turkey): a GIS perspective. J Environ Manage 79:30–37

    Article  Google Scholar 

  • Pérez JMS, Antiguedad I, Arrate I, García-Linares C, Morell I (2003) The influence of nitrate leaching through unsaturated soil on groundwater pollution in an agricultural area of the Basque country: a case study. Sci Total Environ 317:173–187

    Article  Google Scholar 

  • Refsgaard JC, Thorsen M, Jensen JB, Kleeschulte S, Hansen S (1999) Large scale modelling of groundwater contamination from nitrate leaching. J Hydrol 221:117–140

    Article  Google Scholar 

  • Rouabhia A, Baali F, Fehdi C (2010) Impact of agricultural activity and lithology on groundwater quality in the Merdja area, Tebessa, Algeria. Arab J Geosci 3(3):307–318

    Article  Google Scholar 

  • Schwiede M, Duijnisveld WHM, Böttcher J (2005) Investigation of processes leading to nitrate enrichment in soils in the Kalahari Region, Botswana. Phys Chem Earth, Parts A/B/C 30(11–16):712–716

    Article  Google Scholar 

  • Singh B, Singh Y, Sekhon GS (1995) Fertilizer-N use efficiency and nitrate pollution of groundwater in developing countries. J Contam Hydrol 20:167–184

    Article  Google Scholar 

  • Somasundaram MV, Ravindran G, Tellam JH (1993) Ground-water pollution of the Madras Urban aquifer. India Ground Water 31:4–11

    Article  Google Scholar 

  • StatSoft, Inc. (2011) Electronic statistics textbook. StatSoft, Tulsa. Available at http://www.statsoft.com/textbook/

  • US Environmental Protection Agency (1994) Nitrogen control. Technomic Publishing Company, Inc., Lancaster, pp 1–22

    Google Scholar 

  • Wakida FT, Lerner DN (2005) Non-agricultural sources of groundwater nitrate: a review and case study. Water Res 39:3–16

    Article  Google Scholar 

  • WHO (2007) Nitrate and nitrite in drinking-water. Background document for development of WHO Guidelines for Drinking-water Quality

  • Yusop MK, Cleemput OV, Baert L (1984) Nitrogen fertilisation and nitrate pollution of groundwater in sandy soils. Environ Pollution (Series B) 7:43–48

    Article  Google Scholar 

Download references

Acknowledgments

The authors would like to acknowledge the Board of Research in Nuclear Sciences, Department of Atomic Energy, Government of India for funding this work (grant no. 2007/36/35). They also thank the Department of Science and Technology's Funds for Improvement in Science and Technology scheme (grant no. SR/FST/ESI-106/2010), University Grants Commission's Special Assistance Programme (grant no. UGC DRS II F.550/10/DRS/2007(SAP-1)), and Centre with Potential for Excellence in Environmental Sciences scheme of the University Grants Commission (grant no. F.No.1-9/2004 (NS/PE)) for their financial support which helped in creating facilities to carry out part of this work.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to L. Elango.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Brindha, K., Elango, L. Soil and groundwater quality with reference to nitrate in a semiarid agricultural region. Arab J Geosci 7, 4683–4695 (2014). https://doi.org/10.1007/s12517-013-1100-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12517-013-1100-5

Keywords

Navigation