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Large π-conjugated indium-based metal-organic frameworks for high-performance electrochemical conversion of CO2

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Abstract

The active site engineering of electrocatalysts, as one of the most economical and technological approaches, is a promising strategy to enhance the intrinsic activity and selectivity towards electrochemical CO2 reduction reaction. Herein, an indium-based porphyrin framework (In-TCPP) with a well-defined structure, highly dispersed catalytic center, and good stability was constructed for efficient CO2-to-formate conversion. In-TCPP could achieve a high Faraday efficiency for formate (90%) and a cathodic energy efficiency of 63.8% in flow cells. In situ attenuated total reflectance Fourier transform infrared spectroscopy and density functional theory calculation confirm that the crucial intermediate is *COOH species which contributes to the formation of formate. This work is expected to provide novel insights into the precise design of active sites for high-performance electrocatalysts towards electrochemical CO2 reduction reaction.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Nos. 22071172, 52121002, 51733004, 51725304, and 21907043), the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDB12030300), and the Ministry of Science and Technology of China (No. 2018YFA0703200). We also acknowledge the support of the Center for Large-scale instrument management platform of Tianjin University and the Analytical and Testing Center of Tianjin University of Technology for XRD, FTIR, XPS, SEM, and TEM measurements. We thank the Haihe Laboratory of Sustainable Chemical Transformations for financial support.

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Authors and Affiliations

  1. Department of Chemistry, School of Science; Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Tianjin University, Tianjin, 300072, China

    Zengqiang Gao, Yating Zhu, Li Li, Yongxia Shi, Man Hou, Zhicheng Zhang & Wenping Hu

  2. College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang, 330022, China

    Junjie Li & Xuejiao J. Gao

  3. Haihe Laboratory of Sustainable Chemical Transformations, Tianjin, 300192, China

    Wenping Hu

  4. CAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing, 100190, China

    Yue Gong

  5. Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City, Fuzhou, 350207, China

    Wenping Hu

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  1. Zengqiang Gao
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  2. Yue Gong
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  3. Yating Zhu
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  4. Junjie Li
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  5. Li Li
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  6. Yongxia Shi
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  7. Man Hou
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  8. Xuejiao J. Gao
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  9. Zhicheng Zhang
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  10. Wenping Hu
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Correspondence to Xuejiao J. Gao, Zhicheng Zhang or Wenping Hu.

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Gao, Z., Gong, Y., Zhu, Y. et al. Large π-conjugated indium-based metal-organic frameworks for high-performance electrochemical conversion of CO2. Nano Res. 16, 8743–8750 (2023). https://doi.org/10.1007/s12274-023-5685-z

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  • DOI: https://doi.org/10.1007/s12274-023-5685-z

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