Abstract
We prepared solid polymer electrolytes (SPEs) composed of poly(ethylene glycol) monomethyl ether acrylate (1A9OMe) and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([EMIm][OTF]) and 1-ethyl-3-methylimidazolium bis(trifluoromethane sulfonyl) imide ([EMIm][TFSI]) as the ionic liquid. The SPEs formed by appropriately adding ionic liquids in the 1A9OMe prior to thermal cure. The ratio of 1A9OMe and ionic liquid was 1:9, 3:7, and 5:5, respectively. The characterization of solid polymer electrolytes were investigated using Fourier transform infrared spectroscopy in the attenuated total reflectance mode (FTIR-ATR), Electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), and glavanostatic charge-discharge test. The highest ionic conductivity of SPEs was found to be 4.90×10−4 S/cm in a 1A9OMe/[EMIm][OTF] of 3:7. As IL contents were increased, the specific capacitance of supercapacitor was increased. The specific capacitance of supercapacitor for ionic liquid with large ion size was lower than that for ionic liquid with smaller ion size.
Similar content being viewed by others
References
B. E. Conway, “Electrochemical Supercapicitors: Scientific Fundamentals and Technological Application”, Plenum publishers, New York, 1999.
M. Winter and R. J. Brodd, Chem. Rev., 104, 4245 (2004).
L. L. Zhang, R. Zhou, and X. S. Zhao, J. Mater. Chem., 20, 5983 (2011).
R. Kotz and M. Carlen, Electrochim. Acta, 45, 2483 (2000).
A. Burke, J. Power Sources, 91, 37 (2000).
M. Mastragostino, C. Arbizzani, and F. Soavi, “Advances in Lithium-ion Batteries”, Kluwer Academic Publishers/ Plenum Press, New York, 2002.
R. J. Brodd, K. R. Bullock, R. A. Leising, R. L. Middaugh, J. R. Miller, and E. Takeuchi, J. Electrochem. Soc., 151, K1 (2004).
A. Rufer, D. Hotellier, and P. Barrade, IEEE Trans. Power Deliv., 19, 629 (2004).
P. Rodatz, G. Paganelli, A. Sciarretta, and L. Guzzella, Control. Eng. Pract., 13, 41 (2005).
J. Chmiola, G. Yushin, Y. Gogotsi, C. Portet, P. Simon, and P. L. Taberna, Science, 313, 1760 (2006).
D. D. L. Chung and S. Wang, Smart Mater. Struct., 8, 161 (1999).
M. H. Kjell, E. Jacques, D. Zenkert, M. Behm, and G. Lindbergh, J. Electrochem Soc., 158, A1455 (2011).
Y. Lin and H. A. Sodano, J. Appl. Phys., 106, 114108 (2009).
D. J. O’Brien, D. M. Baechle, and E. D. Wetzel, J. Comp. Mat., 45, 2797 (2011).
D. Peairs, C. Hilton, S. Case, J. Lesko, D. Sitton, and R. Moffitt, Compos. Res. J., 2, 30 (2008).
X. Luo and D. D. L. Chung, Compos. Sci. Technol., 61, 885 (2001).
T. Carlson, D. Ordéus, M. Wysocki, and L. E. Asp, Plastics, Rubbers and Compos., 40, 311 (2011).
T. Carlson, D. Ordéus, M. Wysocki, and L. E. Asp, Compos. Sci. Technol., 70, 1135 (2010).
H. Qian, A. R. Kucernak, E. S. Greenhalgh, A. Bismarck, and M. S. P. Shaffer, ACS Appl. Mater. Interfaces, 5, 6113 (2013).
A. Javaid, K. K. C. Ho, A. Bismarck, M. S. P. Shaffer, J. H. G. Steinke, and E. S. Greenhalgh, J. Compos. Mat., 48, 1409 (2013).
T. Carlson and L. E. Asp, Compos. Pt. B-Eng., 49, 16 (2013).
V. Srinivasan and J. W. Weider, J. Power Source, 108, 15 (2002).
H. M. Shiri and M. Aghazadeh, J. Electrochem. Soc., 159, E132 (2012).
Y. Wang, Z. Q. Shi, Y. Huang, Y. F. Ma, C. Y. Wang, M. M. Chen, and Y. Y. Chen, J. Phys. Chem. C, 113, 13103 (2009).
T. L. Greaves, A. Weerawardena, C. Fong, I. Krodkiewska, and C. J. Drummond, J. Phys. Chem. B, 110, 22479 (2006).
K. H. An, W. S. Kim, Y. S. Park, J. M. Moon, D. J. Bae, S. C. Lim, Y. S. Lee, and Y. H. Lee, Adv. Funct. Mater., 11, 387 (2001).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Cho, BS., Choi, J. & Kim, KY. Preparation and properties of solid polymer electrolyte based on imidazolium-based ionic liquids for structural capacitors. Fibers Polym 18, 1452–1458 (2017). https://doi.org/10.1007/s12221-017-7266-9
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12221-017-7266-9