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Study on oil adsorption/desorption kinetics and polymer network parameters of poly(lauryl methacrylate-co-hydroxyethyl methacrylate)

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Abstract

In the present work, oil adsorption, desorption, and resorption of poly(lauryl methacrylate-co-hydroxyethyl methacrylate) P(LMA-co-HEMA) were evaluated with different oils by a gravimetric method. Adsorption kinetics were modeled using pseudo-first-order and pseudo-second-order equations. Polymer network parameters of P(LMA-co-HEMA) regarding average molecular weight (Mc) between two crosslink piontss can be calculated by oil absorbency at equilibrium (Q e ), the solubility parameter (δ) and polymer-solvent interaction parameter (χ) with Flory-Huggins relation. The results showed pseudo-second-order model has a better fit to the oil adsorption kinetic data The desorption can be analyzed by fitting a prediction of exponential-like decay to the deswelling curves. A typical oil desorption exhibited two stages: a burst release driven by concentration gradient, and a slow release controlled by diffusion and the elastic recovery of polymer networks. For reusability, the resorption behavior of P(LMA-co-HEMA) was also investigated. It was worth noting that oil resorption was faster than the first adsorption due to potential passages. Moreover, the adsorption capacity was not significantly changed after regeneration.

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Authors and Affiliations

  1. State Key Laboratory of Separation Membranes and Membrane Processes, School of Textiles, Tianjin Polytechnic University, Tianjin, 300387, China

    Jian Zhao, Shengnan Tian & Changfa Xiao

  2. Australian Future Fibres Research and Innovation Centre, Institute for Frontier Materials, Deakin University, VIC, 3220, Australia

    Jian Zhao & Linpeng Fan

  3. School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin, 300387, China

    Yanru Shan

Authors
  1. Jian Zhao
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  2. Shengnan Tian
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  3. Linpeng Fan
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  4. Yanru Shan
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  5. Changfa Xiao
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Correspondence to Jian Zhao or Changfa Xiao.

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Zhao, J., Tian, S., Fan, L. et al. Study on oil adsorption/desorption kinetics and polymer network parameters of poly(lauryl methacrylate-co-hydroxyethyl methacrylate). Fibers Polym 18, 1858–1864 (2017). https://doi.org/10.1007/s12221-017-5556-x

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  • DOI: https://doi.org/10.1007/s12221-017-5556-x

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