Skip to main content
Log in

Evaluation of the physico-mechanical properties of activated-carbon enhanced recycled polyethylene/polypropylene 3D printing filament

  • Published:
Sādhanā Aims and scope Submit manuscript

Abstract

In this study, recycled polymer feedstocks (high-density polyethylene, HDPE and polypropylene, PP) were added with different percentages of activated carbon (AC) made from coconut fiber waste – 0, 2, 4, 6, and 8%. The melting temperatures of the recycled HDPE and HDPE/PP filaments were 113 and 170°C, respectively. The addition of AC improved the thermal stability of the recycled filaments up to 28% while decreased the crystallinity of the filament produced, resulting in a more uniform surface with less crazing. Incompatibility of the recycled HDPE and AC was observed. However, the presence of PP greatly enhanced the compatibility of AC with the HDPE polymer. With the addition of 8% AC to the recycled HDPE/PP, the elongation at break of the recycled HDPE/PP filament reached 54.2%, about 10 times higher than that without AC, which could be due to the passive local interfacial bonding of AC with the methyl group of the PP matrix. The improved elongation at break would in turn aid in 3D printing of products with better elasticity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6

Similar content being viewed by others

References

  1. Chong S, Chiu H-L, Liao Y-C, Hung S-T and Pan G-T 2015 Cradle to Cradle® Design for 3D Printing. Chem. Eng. Trans. 45: 1669–1674

    Google Scholar 

  2. Kreiger M A, Mulder M L, Glover A G and Pearce J M 2014 Life cycle analysis of distributed recycling of post-consumer high density polyethylene for 3-D printing filament. J. Clean. Prod. 70: 90–96

    Article  Google Scholar 

  3. Chong S, Pan G-T, Khalid M, Yang T C-K, Hung S-T and Huang C-M 2017 Physical characterization and pre-assessment of recycled high-density polyethylene as 3D printing material. J. Polym. Environ. 25(2): 136–145

    Article  Google Scholar 

  4. Tokoro R, Vu D M, Okubo K, Tanaka T, Fujii T and Fujiura T 2008 How to improve mechanical properties of polylactic acid with bamboo fibers. J. Mater. Sci. 43(2): 775–787

    Article  Google Scholar 

  5. Murphy C A and Collins M N 2018 Microcrystalline cellulose reinforced polylactic acid biocomposite filaments for 3D printing. Polym. Compos. 39(4): 1311–1320

    Article  Google Scholar 

  6. ders 2013 Wood filament LAYWOO-D3 suppliers and price compare. [2016/10/24]; Available from: http://www.3ders.org/articles/20130204-wood-filament-laywoo-d3-suppliers-and-price-compare.html

  7. Okada A and Usuki A 2006 Twenty years of polymer-clay nanocomposites. Macromol. Mater. Eng. 291(12): 1449–1476

    Article  Google Scholar 

  8. Coleman J N, Khan U, Blau W J and Gun’ko Y K 2006 Small but strong: a review of the mechanical properties of carbon nanotube–polymer composites. Carbon. 44(9): 1624–1652

    Article  Google Scholar 

  9. Fasolino A, Los J and Katsnelson M I 2007 Intrinsic ripples in graphene. Nat. Mater. 6(11): 858

    Article  Google Scholar 

  10. Refil 2020 [2017/04/10]. Available from: http://www.re-filament.com/

  11. MakerGeeks 2019 [2015/03/05]. Available from: http://www.makergeeks.com/

  12. Fim F C, Guterres J M, Basso N R and Galland G B 2010 Polyethylene/graphite nanocomposites obtained by in situ polymerization. J. Polym. Sci. A Polym. Chem. 48(3): 692–698

    Article  Google Scholar 

  13. Dalton E and Collins M N 2014 Lamella alignment ratio: a SAXS analysis technique for macromolecules. J. Appl. Crystallogr. 47(3): 847–851

    Article  Google Scholar 

  14. Pan G T, Chong S, Tsai H J, Lu W H and Yang T C K 2018 The effects of iron, silicon, chromium, and aluminum additions on the physical and mechanical properties of recycled 3D printing filaments. Adv. Polym. Technol. 37(4): 1176–1184

    Article  Google Scholar 

  15. Launer P J 2013 Infrared analysis of organosilicon compounds: spectra-structure correlations. Reprinted from Silicone Compounds: Silanes & Silicones. [2016/10/30]. Available from: https://www.gelest.com/wp-content/uploads/5000A_Section1_InfraredAnalysis.pdf

  16. Ultimaker 2016 Ultimaker Materials. [2016/10/30]. Available from: https://ultimaker.com/en/products/materials

  17. Iqbal J, Pandey K, Verma V, Singh P and Mishra R 2015 Physico-mechanical and thermal behaviour of binary blends of EPDM and LLDPE. European J. Adv. Eng. Technol. 2(10): 43–48

    Google Scholar 

  18. Bagheri S and Julkapli N M 2016 Effect of hybridization on the value-added activated carbon materials. Int. J. Ind. Chem. 7(3): 249–264

    Article  Google Scholar 

  19. Xiao Q and Zhou X 2003 The study of multiwalled carbon nanotube deposited with conducting polymer for supercapacitor. Electrochim. Acta. 48(5): 575–580

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Guan-Ting Pan.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chong, S., Yang, T.CK., Lee, KC. et al. Evaluation of the physico-mechanical properties of activated-carbon enhanced recycled polyethylene/polypropylene 3D printing filament. Sādhanā 45, 57 (2020). https://doi.org/10.1007/s12046-020-1294-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12046-020-1294-7

Keywords

Navigation