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Fe3O4@SiO2@BHA-Cu(II) as a new, effective, and magnetically recoverable catalyst for the synthesis of polyhydroquinoline and tetrazole derivatives

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Abstract

A magnetically recoverable heterogeneous Fe3O4@SiO2@BHA-Cu(II) nanocomposite was prepared by immobilizing a novel Cu(II) complex on the nanoparticles. The catalyst was characterized by FT-IR, TGA, VSM, TEM, FESEM, XRD, ICP, and EDX techniques. The catalytic activity of nanocatalysts in the synthesis of tetrazoles and polyhydroquinoline derivatives was investigated. This new and recyclable magnetic nanocatalyst has outstanding features such as short reaction time, high atom economy, easy work-up, mild reaction conditions, and excellent yields of the products.

Graphical abstract

A non-toxic and practical Fe3O4@SiO2@BHA-Cu(II) nanocatalyst was prepared using accessible and simple starting material. The structure, morphology and properties of nanocatalyst were fully characterized using different techniques. In this method, the catalyst is capable of synthesizing a set of NH-containing heterocycles through multicomponent reactions and also shows good reusability.

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Acknowledgements

The authors acknowledge Ilam University, Ilam, Iran for financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ilam University, P.O. Box 69315516, Ilam, Iran

    Masoomeh Norouzi & Shima Beiranvand

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  1. Masoomeh Norouzi
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  2. Shima Beiranvand
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Correspondence to Masoomeh Norouzi.

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Norouzi, M., Beiranvand, S. Fe3O4@SiO2@BHA-Cu(II) as a new, effective, and magnetically recoverable catalyst for the synthesis of polyhydroquinoline and tetrazole derivatives. J Chem Sci 135, 86 (2023). https://doi.org/10.1007/s12039-023-02206-w

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  • DOI: https://doi.org/10.1007/s12039-023-02206-w

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