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Assembly of organic moiety with metal-oxide cluster to generate a new three dimensional supramolecular/hydrogen bonded network based on isopolymolybdate

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Abstract

A new octa-molybdate formulated as (C2H6N4)2 [β-Mo 8 O 26].4H 2O (1) has been isolated by conventional solution method and structurally characterized by single-crystal X-ray diffraction method, IR spectroscopy, UV-Vis absorption, thermogravimetric analysis and cyclic voltammetry. Compound 1 crystallizes in the Triclinic system, space group P-1 with unit cell dimensions, a = 8.348 (2) Å, b = 10.154 (2) Å, c = 10.823 (3) Å, α=68.35∘ (2), β=71.59∘ (2), ɤ =78.55∘ (2), V = 805.5 (3) Å 3, and Z = 2. The crystal structure of 1 is built up from octa-molybdate [ β-Mo 8 O 26] 4− clusters connected through hydrogen-bonding interactions into a three-dimensional supramolecular network.

A new organic–inorganic hybrid material was prepared from ammonium hepta-molybdate in acidic medium by addition of 1, 2, 4-triazol-3-amine to obtain an octa-molybdate formulated as (C2H6N4)2 [β-Mo8O26].4H2O. The compound was characterized by single crystal X-ray diffraction method, IR spectroscopy, UV-Vis absorption, thermogravimetric analysis and cyclic voltammetry.

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Authors and Affiliations

  1. Laboratoire des Matériaux, Cristallochimie et thermodynamique appliqué, Université Tunis El Manar, Faculté des sciences de Tunis, Tunis, Tunisia

    DONIA ZAMMEL, ICHRAF NAGAZI & AMOR HADDAD

  2. Université Monastir, Faculté des Sciences de Monastir, Monastir, Tunisia

    DONIA ZAMMEL, ICHRAF NAGAZI & AMOR HADDAD

Authors
  1. DONIA ZAMMEL
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  2. ICHRAF NAGAZI
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  3. AMOR HADDAD
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Correspondence to DONIA ZAMMEL.

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Supplementary Information (SI)

Crystallographic data with CCDC Numbers 1056979 for the structure reported in this paper has been deposited in the Cambridge Crystallographic Data Center and can be obtained free of charge via http://www.ccdc.cam.ac.uk/deposit, or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: t(44) 01223 336 033 or e-mail to deposit@ccdc.cam.ac.uk. All additional information pertaining to characterization of the title compound 1 using IR spectroscopy (figure S1), thermogravimetric analysis (figure S2), UV-Vis absorption (figure S3), cyclic voltammetry measurements (figures S4 and S5) are given in the Supporting Information, available at www.ias.ac.in/chemsci.

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ZAMMEL, D., NAGAZI, I. & HADDAD, A. Assembly of organic moiety with metal-oxide cluster to generate a new three dimensional supramolecular/hydrogen bonded network based on isopolymolybdate. J Chem Sci 128, 1141–1148 (2016). https://doi.org/10.1007/s12039-016-1110-4

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  • DOI: https://doi.org/10.1007/s12039-016-1110-4

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