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SBA-15-Pr–SO3H: An efficient, environment friendly and recyclable heterogeneous nanoreactor catalyst for the one-pot multicomponent synthesis of β-acetamido ketones

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Abstract

SBA-15-Pr–SO3H catalyzes the multi-component condensation of aromatic aldehydes, ketones and acetonitrile in the presence of acetyl chloride at 80°C to afford β-acetamido ketones in excellent yields. The catalyst can be recovered and recycled for subsequent reactions without any appreciable loss of efficiency.

SBA-15-Pr–SO3H as nanoreactor catalyzes the multicomponent condensation of aromatic aldehydes, ketones, and acetonitrile in the presence of acetyl chloride at 80°C to afford β-acetamido ketones in excellent yields.

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Acknowledgments

We are thankful to the Razi University Research Council for partial support of this work.

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Authors and Affiliations

  1. Department of Organic Chemistry, Faculty of Chemistry, Razi University, Kermanshah, 67149-67346, Iran

    KIUMARS BAHRAMI, MOHAMMAD M KHODAEI & PEYMAN FATTAHPOUR

  2. Nanoscience and Nanotechnology Research Center (NNRC), Razi University, Kermanshah, 67149-67346, Iran

    KIUMARS BAHRAMI

Authors
  1. KIUMARS BAHRAMI
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  2. MOHAMMAD M KHODAEI
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  3. PEYMAN FATTAHPOUR
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Corresponding authors

Correspondence to KIUMARS BAHRAMI or MOHAMMAD M KHODAEI.

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Supplementary Information

Complete experimental procedures and relevant spectra (1H NMR and 13C NMR spectra) for some compounds (figure S1–S8) are given in Supplementary Information, which is available free of charge in www.ias.ac.in/chemsci.

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BAHRAMI, K., KHODAEI, M.M. & FATTAHPOUR, P. SBA-15-Pr–SO3H: An efficient, environment friendly and recyclable heterogeneous nanoreactor catalyst for the one-pot multicomponent synthesis of β-acetamido ketones. J Chem Sci 127, 167–172 (2015). https://doi.org/10.1007/s12039-014-0762-1

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