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The new synthesis and characterization of SBA-15-Pr–NMe3OH: a tailored and reusable Bronsted base nanoreactor for the conversion of nitriles into amides using H2O2

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Abstract

A novel method for the synthesis of SBA-15-Pr–NMe3OH as a nanoreactor heterogenous Brønsted base catalyst has been developed. Quaternary organic tetraalkylammonium hydroxide grafted on SBA-15 is a strong Brønsted base catalyst, and represents a useful alternative to soluble bases in the selective conversion of nitriles to amides with aqueous 30 % H2O2, presenting high efficiency, convenient recovery and steady reuse.

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Acknowledgments

We are thankful to the Razi University Research Council for partial support of this work.

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Authors and Affiliations

  1. Department of Organic Chemistry, Faculty of Chemistry, Razi University, 67149-67346, Kermanshah, Iran

    Peyman Fattahpour, Mehdi Sheikh Arabi, Mohammad M. Khodaei & Kiumars Bahrami

  2. Nanoscience and Nanotechnology Research Center (NNRC), Razi University, 67149-67346, Kermanshah, Iran

    Kiumars Bahrami

Authors
  1. Peyman Fattahpour
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  2. Mehdi Sheikh Arabi
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  3. Mohammad M. Khodaei
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  4. Kiumars Bahrami
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Correspondence to Mohammad M. Khodaei or Kiumars Bahrami.

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Fattahpour, P., Arabi, M.S., Khodaei, M.M. et al. The new synthesis and characterization of SBA-15-Pr–NMe3OH: a tailored and reusable Bronsted base nanoreactor for the conversion of nitriles into amides using H2O2 . J Porous Mater 22, 211–218 (2015). https://doi.org/10.1007/s10934-014-9887-3

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