Skip to main content
Log in

Unprecedented exploration of ionic liquids as additives which astonishes the thermal stability of PVC formulations

  • Published:
Bulletin of Materials Science Aims and scope Submit manuscript

Abstract

The use of ionic liquids as additives and an economic and environmentally benign alternative to conventional inorganic and organic additives in poly(vinyl chloride) (PVC) formulation is investigated by using thermogravimetric analysis. The present study deals with an elegant exploration of the resulting thermal profiles to disclose the pattern of thermal degradation for N-butylpyridinium hexafluorophosphate and PVC formulation as well. Furthermore, non-isothermal kinetic investigations providing sound information about kinetic parameters, such as activation energy and frequency factor by using the Coats–Redfern equation in the temperature range of 593–663 K for N-butylpyridinium hexafluorophosphate and 423–473 K for the resulting PVC formulation were performed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Scheme 1
Scheme 2
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Scheme 3
Scheme 4

Similar content being viewed by others

References

  1. Ana M A D, Sofia M, Mara E M B, Jorge F J C, Abel G M F, Pedro N S et al 2012 Acta Biomater. 8 1366

    Article  Google Scholar 

  2. Jun L, Guangming C and Jiping Y 2008 Polymer 49 3923

    Article  Google Scholar 

  3. Mikael R and Thomas H 1992 Macromolecules 25 6332

    Article  Google Scholar 

  4. Nadia E A E, Riham R M and Zayed M A 2012 Dalton Trans. 41 1824

    Article  Google Scholar 

  5. Abdul A, Chetan P, Vikas G and Dilip H 2012 J. Thermoplast. Compos. Mater., https://doi.org/10.1177/0892705712446716

    Article  Google Scholar 

  6. Gupta G R, Chaudhari G R, Tomar P A, Waghulde G P and Patil K J 2012 Asian J. Chem. 24 4675

    CAS  Google Scholar 

  7. Gupta G R, Chaudhari G R, Tomar P A, Gaikwad Y, Pameez A, Pandya G H et al 2012 Eur. J. Chem. 3 475

    Article  CAS  Google Scholar 

  8. Sarode C H, Gupta G R, Chaudhari G R and Waghulde G P 2018 Curr. Green Chem. 5 191

    Article  CAS  Google Scholar 

  9. Gupta G R, Chaudhari G R, Tomar P A, Gaikwad Y, Pameez A, Pandya G H et al 2013 Asian J. Chem. 25 8261

    Article  CAS  Google Scholar 

  10. Shaikh V R, Terdale S S, Gupta G R, Hundiwale D G and Patil K J 2013 J. Mol. Liq. 186 14

    Article  CAS  Google Scholar 

  11. Dong K, Liu X, Dong H, Zhang X and Zhang S 2017 Chem. Rev. 117 6636

    Article  CAS  Google Scholar 

  12. Mustafizur R and Christopher S B 2006 Polym. Degrad. Stab. 91 3371

    Article  Google Scholar 

  13. Sui W and Lin X H 2011 Iran. Polym. J. 20 989

    Google Scholar 

  14. Lin X H and Sui W 2011 Polym. Bull. 67 1273

    Article  Google Scholar 

  15. Shirsath N B, Gupta G R, Gite V V and Meshram J S 2018 Bull. Mater. Sci. 41 63

    Article  Google Scholar 

  16. Gupta G R, Shaikh V R and Patil K J 2018 Curr. Phys. Chem. 8 175

    Article  CAS  Google Scholar 

  17. Patil K S, Zope P H, Patil U T, Patil P D, Dubey R S and Gupta G R 2019 Bull. Mater. Sci. 42 24

    Article  Google Scholar 

  18. Gupta G R, Patil P D, Shaikh V R, Kolhapurkar R R, Dagade D H and Patil K J 2018 Curr. Sci. 114 2525

    Article  CAS  Google Scholar 

  19. Ammar K and Douglas R F 2005 J. Pharm. Sci. 95 472

    Google Scholar 

  20. Ammar K and Douglas R F 2006 J. Phys. Chem. B 110 17315

    Article  Google Scholar 

  21. Tomar P A, Yadav S M and Gupta G R 2014 Polym. Bull. 71 1349

    Article  CAS  Google Scholar 

  22. Bamford C H and Tipper C F H 1980 Comprehensive chemical kinetics (UK: Elsevier Scientific Publishing Company B. V.) vol. 22

  23. Coats A W and Redfern J P 1968 Nature 201 68

    Article  Google Scholar 

  24. Wasserscheid P and Welton T 2002 Ionic liquids in synthesis (Weinheim: Wiley-VCH Verlag)

    Book  Google Scholar 

  25. Alpert N L, William E K and Szymanski H A 1970 IR, theory and practice of infrared spectroscopy (US: Plenum Press, Springer)

    Google Scholar 

  26. Fred W B 2007 Textbook of polymer science, 3rd edn (New York: Wiley Asia)

    Google Scholar 

  27. Simon P 1990 Polym. Degrad. Stab. 29 155

    Article  CAS  Google Scholar 

  28. Bacaloglu R and Fisch M H 1994 Polym. Degrad. Stab. 45 325

    Article  CAS  Google Scholar 

  29. Fisch M H and Bacaloglu R 1995 J. Vinyl Addit. Techn. 1 233

    Article  CAS  Google Scholar 

  30. Fisch M H and Bacaloglu R 1999 Plast. Rubber Compos. 28 119

    Article  CAS  Google Scholar 

  31. Baltacioglu H and Balkose D 1999 J. Appl. Polym. Sci. 74 2488

    Article  CAS  Google Scholar 

  32. Okieimen F E and Sogbaike C E 1995 J. Appl. Polym. Sci. 57 513

    Article  CAS  Google Scholar 

  33. Balkose D, Gokcel H I and Goktepe S E 2000 Eur. Polym. J. 37 1191

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Gaurav R Gupta.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gupta, G.R., Nevare, M.R., Patil, A.M. et al. Unprecedented exploration of ionic liquids as additives which astonishes the thermal stability of PVC formulations. Bull Mater Sci 42, 203 (2019). https://doi.org/10.1007/s12034-019-1866-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12034-019-1866-5

Keywords

Navigation