Abstract
We report here on the development and spectral analysis of Cu2+ (0.5 mol%) and Mn2+ (0.5 mol%) ions doped in two new series of glasses. The visible absorption spectra of Cu2+ and Mn2+ glasses have shown broad absorption bands at 820 nm and 495 nm, respectively. For Cu2+ BFP glasses, excitation at 380 nm, a blue emission at 441 nm and also a weak emission at 418 nm ions have been observed. For Mn2+ ions doped BFP glasses, excitation at 410 nm and a red shift at 605 nm emission have been observed.
Similar content being viewed by others
References
Ainslie B J, Craig S P, Davey S T and Wakefield B 1988 Mater. Lett. 6 139
Asahara Y 1997 Ceram. Int. 23 375
Bamford C R 1962 Phys. Chem. Glasses 3 189
Belliveau T F and Simkin D J 1989 J. Non-Cryst. Solids 110 127
Binnemans K, Van Deun R, Gorller-Walrand C and Adam J L 1998 J. Alloys Compd. 275–277 455
Dexpert-Ghys J, Piriou B, Fracillon N J and Sombret C 1990 J. Non-Cryst. Solids 125 117
Duran A and Fernandez Navarro J M 1985 Phys. Chem. Glasses 26 126
Duran A, Fernandez Navarro J M, Garcia Sol J and Agullo Lopez F 1984 J. Mater. Sci. 19 1468
Durga D K and Veeraiah N 2003 J. Phys. Chem. Solids 64 133
Elbatal Fatma H A, Khalil M M I, Nada N and Desouky S A 2003 Mater. Chem. Phys. 82 375
Fernandez J, Balda R and Ariandiaga M A 1994 Opt. Mater. 4 91
Figgis B N 1966 Introduction to ligand field theory (New York: Wiley)
Garcia-Hipolito M, Alvarez Fregoso O, Martinez E, Falcony C and Aguilar-Frutis M A 2002 J. Opt. Mater. 20 113
Hernandez J A et al 2001 Opt. Mater. 17 491
Konda Y, Kuroiwa Y, Sugimoto N, Manbe T, Tokizaki T and Nakamura A 1996 J. Non-Cryst. Solids 196 90
Lei B, Liu Y, Ye Z and Shi C 2004 J. Lumin. 109 215
Li C, Yu Y, Wang S and Su Q 2003 J. Non-Cryst. Solids 321 191
Machado I E C, Prado L, Gomes L, Prison J M and Martinelli J R 2004 J. Non-Cryst. Solids 348 113
Nistor S V, Stefan M, Goovaerts E, Nikl M and Bohaeck P 2004 Radiat. Meas. 38 655
Patra A, Baker G A and Baker S N 2005 J. Lumin. 111 105
Penz B and Zhou Z J 2002 Mater. Sci. Lett. 21 1863
Rao A S, Ahammed Y N, Reddy R R and Rao T V R 1998 Opt. Mater. 10 245
Ravikumar R V S S N, Komatsu R, Ikeda K, Chandrasekhar A V, Ramamoorthy L, Reddy B J, Reddy Y P and Rao P S 2003 Physica B334 398
Saltberg M A and Haw Hu Y 1990 J. Am. Ceram. Soc. 73 2970
Selomulya R, Ski S, Pita K, Kam C H, Zhang Q Y and Buddhudu S 2003 Mater. Sci. Eng. B100 136
Shelby J E and Downie L K 1989 Phys. Chem. Glasses 30 151
Sreekanth Chakradhar R P, Ramesh K P, Rao J L and Ramakrishna J 2003 J. Phys. Chem. Solids 64 641
Staske R, Frobel P, Dirke M V, Mullor S and Barner K 1991 Solid State Commun. 78 647
Thulasiramudu A and Buddhudu S 2006 JQSRT 181–191 97
Tomita A, Sato T, Tanaka K, Kawabe Y, Shirai M, Tanaka K and Hanamura E 2004 J. Lumin. 109 19
Vaidhyanathan B, Prem Kumar C, Rao J L and Rao K J 1998 J. Phys. Chem. Solids 59 121
Wang J, Wang S and Su Q 2004 J. Solid State Chem. 177 895
Wang S F, Gu F, Meng K L, Guang J Z, Ping A, Zi, Xu D and Yuan D R 2003 J. Cryst. Growth 84–88 257
Yi S S, Bae J S, Shim K S, Jeong J H, Park H L and Holloway P H 2003 J. Cryst. Growth 259 95
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sudhakar Reddy, B., Buddhudu, S. Spectral analysis of Cu2+ and Mn2+ ions doped borofluorophosphate glasses. Bull Mater Sci 30, 481–486 (2007). https://doi.org/10.1007/s12034-007-0076-8
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12034-007-0076-8