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A novel hydroxyl polyacrylate latex modified by OvPOSS and its application in two-component waterborne polyurethane coatings

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Abstract

Octavinyl polyhedral oligomeric sisesquioxane (OvPOSS) was synthesized via hydrolysis and condensation of vinyltriethoxysilane. The structure of OvPOSS was determined by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), 1H nuclear magnetic resonance and 29Si nuclear magnetic resonance. A novel hydroxyl functional polyacrylate latex (HPA) with core–shell structure modified by OvPOSS (OvPOSS/HPA) was successfully prepared via emulsion copolymerization. Consequently two-component waterborne polyurethane (2K-WPU) coatings were prepared by using the as-prepared latex as hydroxyl components and hydrophilic polyisocyanates as curing agents. The structure and properties of OvPOSS/HPA were marked by FTIR, XRD, differential scanning calorimetry and thermogravimetric analysis. The results of FTIR and XRD show that OvPOSS has been successfully embedded into HPA, and OvPOSS occupies a homogeneous distribution in the HPA matrix. The effect of OvPOSS on the properties of OvPOSS/HPA as well as the application performance of 2K-WPU coatings film were also investigated. The results show that OvPOSS/HPA possesses core–shell structure with the OvPOSS core and enhanced thermal stability. The glass transition temperature (Tg) of OvPOSS/HPA with 2.0% OvPOSS content is 22.3°C, which is 8.4°C higher than that of pure HPA. The performance properties of the 2K-WPU coating films such as pencil hardness were also improved by incorporation of OvPOSS.

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References

  1. Deng, YJ, Zhou, C, Zhang, MY, Zhang, HX, “Effects of the Reagent Ratio on the Properties of Waterborne Polyurethanes-Acrylate for Application in Damping Coating.” Prog. Org. Coat., 122 239–247 (2018)

    CAS  Google Scholar 

  2. Yousefi, E, Ghadimi, MR, Amirpoor, S, Dolad, A, “Preparation of New Superhydrophobic and Highly Oleophobic Polyurethane Coating with Enhanced Mechanical Durability.” Appl. Surf. Sci., 454 201–209 (2018)

    CAS  Google Scholar 

  3. Hu, T, Xuan, SH, Ding, L, Gong, XL, “Stretchable and Magneto-Sensitive Strain Sensor Based on Silver Nanowire-Polyurethane Sponge Enhanced Magnetorheological Elastomer.” Mater. Design, 156 528–537 (2018)

    CAS  Google Scholar 

  4. Prociak, A, Kuranska, M, Cabulis, U, Ryszkowska, J, Leszczynska, M, Uram, K, Kirpluks, M, “Effect of Bio-polyols with Different Chemical Structures on Foaming of Polyurethane Systems and Foam Properties.” Ind. Crops Prod., 120 262–270 (2018)

    CAS  Google Scholar 

  5. Hausberger, A, Major, Z, Theiler, G, Gradt, T, “Observation of the Adhesive- and Deformation-Contribution to the Friction and Wear Behaviour of Thermoplastic Polyurethanes.” Wear, 412 14–22 (2018)

    Google Scholar 

  6. Akram, N, Zia, KM, Saeed, M, Mansha, A, Khan, WG, “Morphological Studies of Polyurethane Based Pressure Sensitive Adhesives by Tapping Mode Atomic Force Microscopy.” J. Polym. Res., 25 (9) 193–203 (2018)

    Google Scholar 

  7. Hsiao, SH, Hsu, SH, “Synthesis and Characterization of Dual Stimuli-Sensitive Biodegradable Polyurethane Soft Hydrogels for 3D Cell-Laden Bioprinting.” ACS Appl. Mater. Inter., (2018). https://doi.org/10.1021/acsami.8b08362

    Article  Google Scholar 

  8. Guo, L, Huang, S, Qu, JQ, “Synthesis and Properties of High-Functionality Hydroxyl-Terminated Polyurethane Dispersions.” Prog. Org. Coat., 119 214–220 (2018)

    CAS  Google Scholar 

  9. Xu, W, Zhao, WJ, Hao, LF, Wang, S, Pei, M, Wang, XC, “Synthesis and Characterization of Novel Fluoroalkyl-Terminated Hyperbranched Polyurethane Latex.” Appl. Surf. Sci., 436 1104–1112 (2018)

    CAS  Google Scholar 

  10. Zhu, ZW, Li, RQ, Zhang, CY, Gong, XL, “Preparation and Properties of High Solid Content and Low Viscosity Waterborne Polyurethane-Acrylate Emulsion with a Reactive Emulsifier.” Polymers, 10 (2) 154 (2018)

    Google Scholar 

  11. Chai, CP, Hou, JH, Yang, XH, Ge, Z, Huang, MH, Li, GP, “Two-Component Waterborne Polyurethane: Curing Process Study Using Dynamic In Situ IR Spectroscopy.” Polym. Test, 69 259–265 (2018)

    CAS  Google Scholar 

  12. Wu, GM, Liu, GG, Chen, J, Kong, ZW, “Preparation and Properties of Thermoset Composite Films from Two-Component Waterborne Polyurethane with Low Loading Level Nanofibrillated Cellulose.” Prog. Org. Coat., 106 170–176 (2017)

    CAS  Google Scholar 

  13. Nabuurs, T, Pears, D, Overbeek, A, “Defect-Free Coatings from Two-Pack Isocyanate Curable Acrylic Dispersions.” Prog. Org. Coat., 35 129–140 (1999)

    CAS  Google Scholar 

  14. Geurink, PJA, Scherer, T, Buter, R, Steenbergen, A, Henderiks, H, “A Complete New Design for Waterborne 2-Pack PUR Coatings with Robust Application Properties.” Prog. Org. Coat., 55 119–127 (2006)

    CAS  Google Scholar 

  15. Wang, L, Xu, F, Li, H, Liu, Y, Liu, Y, “Preparation and Stability of Aqueous Acrylic Polyol Dispersions for Two-Component Waterborne Polyurethane.” J. Coat. Technol. Res., 14 1–9 (2017)

    Google Scholar 

  16. Suen, MC, Gu, JH, Hwang, JJ, Wu, CL, Lee, HT, “In-Situ Polymerization and Characteristic Properties of the Waterborne Poly(siloxanes-urethane)s Nanocomposites Containing Graphene.” J. Polym. Res., 25 (1) 32–46 (2018)

    Google Scholar 

  17. Oguz, O, Simsek, E, Soz, CK, Heinz, OK, Yilgor, E, Yilgor, I, Menceloglu, YZ, “Effect of Filler Content on the Structure-Property Behavior of Poly(ethylene oxide) Based Polyurethaneurea-Silica Nanocomposites.” Polym. Eng. Sci., 58 (7) 1097–1107 (2018)

    CAS  Google Scholar 

  18. Li, Q, Guo, LH, Qiu, T, Ye, J, He, LF, Li, XY, Tuo, XL, “Polyurethane/Polyphenylsilsequiloxane Nanocomposite: from Waterborne Dispersions to Coating Films.” Prog. Org. Coat., 122 19–29 (2018)

    CAS  Google Scholar 

  19. Zhang, FA, Yu, CL, “Application of a Silicone-Modified Acrylic Emulsion in Two-Component Waterborne Polyurethane Coatings.” J. Coat. Technol. Res., 4 289–294 (2007)

    CAS  Google Scholar 

  20. Ge, Z, Luo, Y, “Synthesis and Characterization of Siloxane-Modified Two-Component Waterborne Polyurethane.” Prog. Org. Coat., 76 1522–1526 (2013)

    CAS  Google Scholar 

  21. Majumdar, P, Webster, DC, “Influence of Solvent Composition and Degree of Reaction on the Formation of Surface Microtopography in a Thermoset Siloxane–Urethane System.” Polymer, 47 4172–4181 (2006)

    CAS  Google Scholar 

  22. Majumdar, P, Webster, DC, “Surface Microtopography in Siloxane–Polyurethane Thermosets: the Influence of Siloxane and Extent of Reaction.” Polymer, 48 7499–7509 (2007)

    CAS  Google Scholar 

  23. Li, YC, Luo, CH, Li, XH, Zhang, KQ, Zhao, YH, Zhu, KY, Yuan, XY, “Submicron/Nano-Structured Icephobic Surfaces Made from Fluorinated Polymethylsiloxane and Octavinyl-POSS.” Appl. Surf. Sci., 360 113–120 (2016)

    CAS  Google Scholar 

  24. Tao, C, Li, XH, Liu, B, Zhang, KQ, Zhao, YH, Zhu, KY, Yuan, XY, “Highly Icephobic Properties on Slippery Surfaces Formed from Polysiloxane and Fluorinated POSS.” Prog. Org. Coat., 103 48–59 (2017)

    CAS  Google Scholar 

  25. Liu, N, Yu, JY, Meng, YY, Liu, YZ, “Hyperbranched Polysiloxanes Based on Polyhedral Oligomeric Silsesquioxane Cages with Ultra-High Molecular Weight and Structural Tuneability.” Polymers, 10 (5) 495–508 (2018)

    Google Scholar 

  26. Ke, F, Zhang, C, Guang, S, Xu, H, “POSS Core Star-Shape Molecular Hybrid Materials: Effect of the Chain Length and POSS Content on Dielectric Properties.” J. Appl. Polym. Sci., 127 2628–2634 (2012)

    Google Scholar 

  27. Du, BX, Su, JG, Tian, M, Han, T, Li, J, “Understanding Trap Effects on Electrical Treeing Phenomena in EPDM/POSS Composites.” Sci. Rep., 8 1 (2018). https://doi.org/10.1038/s41598-018-26773-y

    Article  CAS  Google Scholar 

  28. Hou, GX, Li, N, Han, HZ, Huo, L, Gao, JG, “Hybrid Cationic Ring-Opening Polymerization of Epoxy Resin/Glycidyloxypropyl-Polyhedral Oligomeric Silsesquioxane Nanocomposites and Dynamic Mechanical Properties.” Iran. Polym. J., 24 (4) 299–307 (2015)

    CAS  Google Scholar 

  29. Zhuo, YZ, Hakonsen, V, He, ZW, Xiao, SB, He, JY, Zhang, ZL, “Enhancing the Mechanical Durability of Icephobic Surfaces by Introducing Autonomous Self-Healing Function.” ACS Appl. Mater. Inter., 10 (14) 11972–11978 (2018)

    CAS  Google Scholar 

  30. Liao, WB, Huang, XX, Ye, LY, Lan, SH, Fan, HB, “Synthesis of Composite Latexes of Polyhedral Oligomeric Silsesquioxane and Fluorine Containing Poly(styrene-acrylate) by Emulsion Copolymerization.” J. Appl. Polym. Sci., 133 (21) 43455–43460 (2016)

    Google Scholar 

  31. Chen, SH, Gao, JG, Han, HZ, Wang, C, “Mechanical and Thermal Properties of Epoxy-POSS Reinforced(biphenyl Diol Formaldehyde/Epoxy Hybrid Resin) Composites.” Iran. Polym. J., 23 (8) 609–617 (2014)

    CAS  Google Scholar 

  32. Yu, CY, Wan, HQ, Chen, L, Li, HX, Cui, HX, Ju, PF, Zhou, HD, Chen, JM, “Marvelous Abilities for Polyhedral Oligomeric Silsesquioxane to Improve Tribological Properties of Polyamide-Imide/Polytetrafluoroethylene Coatings.” J. Mater. Sci., 53 (17) 12616–12627 (2018)

    CAS  Google Scholar 

  33. Wang, X, Hu, Y, Song, L, Xing, W, Lu, H, Lv, P, Jie, GX, “UV-Curable Waterborne Polyurethane Acrylate Modified with Octavinyl POSS for Weatherable Coating Applications.” J. Polym. Res., 18 721–729 (2011)

    CAS  Google Scholar 

  34. Godnjavec, J, Znoj, B, Veronovski, N, Venturini, P, “Polyhedral Oligomeric Silsesquioxanes as Titanium Dioxide Surface Modifiers for Transparent Acrylic UV Blocking Hybrid Coating.” Prog. Org. Coat., 74 654–659 (2012)

    CAS  Google Scholar 

  35. Li, H, Zhao, X, Chu, G, Zhang, S, Yuan, X, “One Step Fabrication of Superhydrophobic Polymer Surface from an Acrylic Copolymer Containing POSS by Spraying.” RSC Adv., 4 62694–62697 (2014)

    CAS  Google Scholar 

  36. Huang, XX, Liao, WB, Ye, LY, Zhang, N, Lan, SH, Fan, HB, Qu, JQ, “Fabrication of Hydrophobic Composite Films by Sol-Gel Process Between POSS-Containing Fluorinated Polyacrylate Latexes and Colloidal Silica Particles.” Micropor. Mesopor. Mater., 243 311–318 (2017)

    CAS  Google Scholar 

  37. Cordes, DB, Lickiss, PD, Rataboul, F, “Recent Developments in the Chemistry of Cubic Polyhedral Oligosilsesquioxanes.” Chem. Rev., 110 2081–2173 (2010)

    CAS  Google Scholar 

  38. Chen, D, Yi, S, Wu, W, Zhong, Y, Liao, J, Huang, C, Shi, WJ, “Synthesis and Characterization of Novel Room Temperature Vulcanized (RTV) Silicone Rubbers Using Vinyl-POSS Derivatives as Cross Linking Agents.” Polymer, 51 3867–3878 (2010)

    CAS  Google Scholar 

  39. Wang, W, Jie, X, Fei, M, Jiang, H, “Synthesis of Core-Shell Particles by Batch Emulsion Polymerization of Styrene and Octavinyl Polyhedral Oligomeric Silsesquioxane.” J. Polym. Res., 18 13–17 (2011)

    Google Scholar 

  40. Baney, RH, Itoh, M, Sakakibara, A, Suzuki, T, “Silsesquioxanes.” Chem. Rev., 95 1409–1430 (1995)

    CAS  Google Scholar 

  41. Li, G, Wang, L, Ni, H, et al., “Polyhedral Oligomeric Silsesquioxane (POSS) Polymers and Copolymers: A Review.” J. Inorg. Organomet. Polym., 11 (3) 123–154 (2001)

    CAS  Google Scholar 

  42. Ke, F, Zhang, C, Guang, S, Xu, H, Xu, HY, “POSS Core Star-Shape Molecular Hybrid Materials: Effect of the Chain Length and POSS Content on Dielectric Properties.” J. Appl. Polym. Sci., 127 2628–2634 (2013)

    CAS  Google Scholar 

  43. Yang, B, Li, J, Wang, J, Xu, H, Guang, S, Li, C, “Poly(vinyl Pyrrolidone-Co-Octavinyl Polyhedral Oligomeric Silsesquioxane) Hybrid Nanocomposites: Preparation, Thermal Properties, and Tg Improvement Mechanism.” J. Appl. Polym. Sci., 106 (1) 320–326 (2010)

    Google Scholar 

  44. Yang, B, Li, J, Wang, J, et al., “Poly(vinyl Pyrrolidone-Co-Octavinyl Polyhedral Oligomeric Silsesquioxane) Hybrid Nanocomposites: Preparation, Thermal Properties, and Tg Improvement Mechanism.” J. Appl. Polym. Sci., 111 (6) 2963–2969 (2009)

    CAS  Google Scholar 

  45. Xu, H, Yang, B, Wang, J, Guang, S, Li, C, “Preparation, Tg Improvement, and Thermal Stability Enhancement Mechanism of Soluble Poly(methyl Methacrylate) Nanocomposites by Incorporating Octavinyl Polyhedral Oligomeric Silsesquioxanes.” J. Polym. Sci. Polym. Chem., 45 5308–5317 (2010)

    Google Scholar 

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Acknowledgments

The authors gratefully acknowledge the financial support of the Science and Technology Planning Project of Guangzhou Science Technology & Innovation Commission (Grant No. 201607010049) and the Science and Technology Planning Project of Guangdong Province, China (2015A010105008).

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  1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510641, China

    Wu Zeng, Haowei Huang, Liujun Song, Xiang Jiang & Xinya Zhang

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Zeng, W., Huang, H., Song, L. et al. A novel hydroxyl polyacrylate latex modified by OvPOSS and its application in two-component waterborne polyurethane coatings. J Coat Technol Res 17, 181–191 (2020). https://doi.org/10.1007/s11998-019-00256-9

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