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A smart anticorrosion coating based on hollow silica nanocapsules with inorganic salt in shells

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Abstract

This work presents the synthesis of corrosion inhibitor [1H-benzotriazole (BTA)]-loaded hollow silica nanocapsules with magnesium hydroxide precipitate in the shells (HSNs-M/BTA) through inverse microemulsion (W/O) polymerization. TEM and Brunauer–Emmett–Teller (BET) measurements indicate that the silica nanocapsules possess voids in the inner part and mesoporous on the surface. The actual loading capacity of BTA is 287.17 mg (BTA)/1 g (HSNs-M/BTA). The results of UV absorption spectra show that the release of BTA can be triggered by the changing of pH in the corrosion solution. The anticorrosive SiO x /ZrO x coatings embedded with hydrophobically modified HSNs-M have a better waterproof performance since the water contact angle can reach 140°. In comparison to the passive SiO x /ZrO x coatings with or without BTA, the enhanced corrosion protection performance of this developed anticorrosive system was observed by both electrochemical impedance spectroscopy and Tafel analysis. The fabrication of nanocapsules with corrosion inhibitors is promising as an intelligent element in protective coatings in the future.

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References

  1. Presuel-Moreno, F, Jakab, MA, Tailleart, N, Goldman, M, Scully, JR, “Corrosion-Resistant Metallic Coatings.” Mater. Today, 11 (10) 14–23 (2008)

    Article  Google Scholar 

  2. Andreeva, DV, Shchukin, DG, “Smart Self-Repairing Protective Coatings.” Mater. Today, 11 (10) 24–30 (2008)

    Article  Google Scholar 

  3. Wang, HM, Akid, R, Gobara, M, “Scratch-Resistant Anticorrosion Sol–Gel Coating for the Protection of AZ31 Magnesium Alloy via a Low Temperature Sol–Gel Route.” Corros. Sci., 52 (8) 2565–2570 (2010)

    Article  Google Scholar 

  4. Park, JH, Yun, TH, Kim, KY, Song, YK, Park, JM, “The Improvement of Anticorrosion Properties of Zinc-Rich Organic Coating by Incorporating Surface-Modified Zinc Particle.” Prog. Org. Coat., 74 (1) 25–35 (2012)

    Article  Google Scholar 

  5. Twite, RL, Bierwagen, GP, “Review of Alternatives to Chromate for Corrosion Protection of Aluminum Aerospace Alloys.” Prog. Org. Coat., 33 (2) 91–100 (1998)

    Article  Google Scholar 

  6. Conradi, M, Kocijan, A, Kek-Merl, D, Zorko, M, Verpoest, I, “Mechanical and Anticorrosion Properties of Nanosilica-Filled Epoxy-Resin Composite Coatings.” Appl. Surf. Sci., 292 432–437 (2014)

    Article  Google Scholar 

  7. Rahimi, A, Amiri, S, “Anticorrosion Hybrid Nanocomposite Coatings with Encapsulated Organic Corrosion Inhibitors.” J. Coat. Technol. Res., 12 (3) 587–593 (2015)

    Article  Google Scholar 

  8. Ferreira, JM, Rossi, JL, Baker, MA, Hinder, SJ, Costa, I, “Deposition and Characterization of a New Mixed Organic/Inorganic Cerium Containing Coating for the Corrosion Protection of Electrogalvanized Steel.” Int. J. Electrochem. Sci., 9 (4) 1827–1839 (2014)

    Google Scholar 

  9. Santana, I, Pepe, A, Jimenez-Pique, E, Pellice, S, Cere, S, “Silica-based Hybrid Coatings for Corrosion Protection of Carbon Steel. Part I: Effect of Pretreatment with Phosphoric Acid.” Surf. Coat. Technol., 236 476–484 (2013)

    Article  Google Scholar 

  10. Lei, YH, Sheng, N, Hyono, A, Ueda, M, Ohtsuka, T, “Effect of Benzotriazole (BTA) Addition on Polypyrrole Film Formation on Copper and Its Corrosion Protection.” Prog. Org. Coat., 77 (2) 339–346 (2014)

    Article  Google Scholar 

  11. Seifzadeh, D, Golmoghani-Ebrahimi, E, “Formation of Novel and Crack Free Nanocomposites Based on Sol Gel Process for Corrosion Protection of Copper.” Surf. Coat. Technol., 210 103–112 (2012)

    Article  Google Scholar 

  12. Skorb, EV, Skirtach, AG, Sviridov, DV, Shchukin, DG, Möhwald, H, “Laser-Controllable Coatings for Corrosion Protection.” ACS Nano, 3 (7) 1753–1760 (2009)

    Article  Google Scholar 

  13. Li, GL, Zheng, ZL, Möhwald, H, Shchukin, DG, “Silica/Polymer Double-Walled Hybrid Nanotubes: Synthesis and Application as Stimuli-Responsive Nanocontainers in Self-Healing Coatings.” ACS Nano, 7 (3) 2470–2478 (2013)

    Article  Google Scholar 

  14. Wang, P, Zhang, D, Qiu, R, Wu, JJ, Wan, Y, “Super-Hydrophobic Film Prepared on Zinc and Its Effect on Corrosion in Simulated Marine Atmosphere.” Corros. Sci., 69 23–30 (2013)

    Article  Google Scholar 

  15. Chen, T, Fu, JJ, “An Intelligent Anticorrosion Coating Based on pH-Responsive Supramolecular Nanocontainers.” Nanotechnology, 23 (50) 505705 (2012)

    Article  Google Scholar 

  16. Skorb, EV, Fix, D, Andreeva, DV, Möhwald, H, Shchukin, DG, “Surface-Modified Mesoporous SiO2 Containers for Corrosion Protection.” Adv. Funct. Mater., 19 (15) 2373–2379 (2009)

    Article  Google Scholar 

  17. Fu, JJ, Chen, T, Wang, MD, Yang, NW, Li, SN, Wang, Y, Liu, XD, “Acid and Alkaline Dual Stimuli-Responsive Mechanized Hollow Mesoporous Silica Nanoparticles as Smart Nanocontainers for Intelligent Anticorrosion Coatings.” ACS Nano, 7 (12) 11397–11408 (2013)

    Article  Google Scholar 

  18. Maia, F, Tedim, J, Lisenkov, AN, Zheludkevich, ML, Ferreira, MGS, “Silica Nanocontainers for Active Corrosion Protection.” Nanoscale, 4 1287–1298 (2012)

    Article  Google Scholar 

  19. Zhao, YJ, Shum, HC, Adams, LLA, Sun, BJ, Holtze, C, Gu, ZZ, Weitz, DA, “Enhanced Encapsulation of Actives in Self-Sealing Microcapsules by Precipitation in Capsule Shells.” Langmuir, 27 (23) 13988–13991 (2011)

    Article  Google Scholar 

  20. Zheludkevich, ML, Shchukin, DG, Yasakau, KA, Möhwald, H, Ferreira, MGS, “Anticorrosion Coatings with Self-Healing Effect Based on Nanocontainers Impregnated with Corrosion Inhibitor.” Chem. Mater., 19 (3) 402–411 (2007)

    Article  Google Scholar 

  21. Song, LY, Ge, XW, Wang, MZ, Zhang, ZC, “Direct Preparation of Silica Hollow Spheres in a Water in Oil Emulsion System: The Effect of pH and Viscosity.” J. Non-Cryst. Solids, 352 (21–22) 2230–2235 (2006)

    Article  Google Scholar 

  22. Tsai, HJ, Lee, YL, “Facile Method to Fabricate Raspberry-Like Particulate Films for Superhydrophobic Surfaces.” Langmuir, 23 (25) 12687–12692 (2007)

    Article  Google Scholar 

  23. Gan, Q, Wang, T, “Chitosan Nanoparticle as Protein Delivery Carrier—Systematic Examination of Fabrication Conditions for Efficient Loading and Release.” Colloid. Surface. B., 59 (1) 24–34 (2007)

    Article  Google Scholar 

  24. Zheludkevich, ML, Serra, R, Montemor, MF, Salvado, IMM, Ferreira, MGS, “Corrosion Protective Properties of Nanostructured Sol-Gel Hybrid Coatings to AA2024-T3.” Surf. Coat. Technol., 200 (9) 3084–3094 (2006)

    Article  Google Scholar 

  25. Maksikova, AV, Serebryakova, ES, Tikhonova, LG, Vereshchagin, LI, “Synthesis of 1-Alkyl-4(5)-oxymethyl-1,2,3-triazoles.” Khim. Geterotsikl. Soedin., 12 1688–1689 (1980)

    Google Scholar 

  26. Prasai, D, Tuberquia, JC, Harl, RR, Jennings, GK, Bolotin, KI, “Graphene: Corrosion-Inhibiting Coating.” ACS Nano, 6 (2) 1102–1108 (2012)

    Article  Google Scholar 

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Acknowledgment

This work was supported by the National Natural Science Foundation of China (No: 51302253).

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Authors and Affiliations

  1. Center of Composite Material and Surface Treatment, China Electronic Technology Group Corporation No.38 Research Institute (CETC 38), Hefei, 230031, Anhui, People’s Republic of China

    Dong Zhao & Dongguang Liu

  2. School of Instrument Science and Opto-electronics Engineering, Hefei University of Technology, Hefei, 230009, People’s Republic of China

    Zhijia Hu

Authors
  1. Dong Zhao
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  2. Dongguang Liu
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Correspondence to Dongguang Liu or Zhijia Hu.

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Zhao, D., Liu, D. & Hu, Z. A smart anticorrosion coating based on hollow silica nanocapsules with inorganic salt in shells. J Coat Technol Res 14, 85–94 (2017). https://doi.org/10.1007/s11998-016-9830-4

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  • DOI: https://doi.org/10.1007/s11998-016-9830-4

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