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Hydride Precipitation in the Hydrogenated 0.12 wt.%H Weld Zone of Ti-0.3Mo-0.8Ni Alloy Argon-Arc-Welded Joints

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Abstract

To reveal the influence of hydrogen on the characteristics of defect-free titanium alloy welded joints, the effects of hydrogen addition on the precipitation behavior in the hydrogenated 0.12 wt.%H weld zone of Ti-0.3Mo-0.8Ni alloy argon-arc-welded joints have been investigated. The results showed that lamellar δ-hydride (face-centered cubic) could only precipitate from α-lamellae, but not from the transformed β-phase due to the high hydrogen solubility in β-phase. Formation of δ-hydride was the result of the αH-phase separation reaction: αH → α (H-lean region) + δ (H-rich region). The formation mechanism of the relatively massive δ-hydride in the αH-matrix was mainly based on the combined effects of harsh stress field states and stringent hydrogen content requirements. A sharp drop in elongation and a slight increase in weld zone hardness of the hydrogenated welded joint were associated with δ-hydride precipitation.

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References

  1. C.R. Simcoe, Adv. Mater. Process. 173, 30 (2015).

    Google Scholar 

  2. H.M. Tawancy, J. Mater. Eng. Perform. 26, 504 (2017).

    Article  Google Scholar 

  3. A.S. Oryshchenko, I.V. Gorynin, V.P. Leonov, A.S. Kudryavtsev, V.I. Mikhailov, and E.V. Chudakov, Inorg. Mater.: Appl. Res. 6, 571 (2015).

    Article  Google Scholar 

  4. D. Teker, F. Muhaffel, M. Menekse, N.G. Karagulerbet, M. Baydogn, and H. Cimenoglu, Mater. Sci. Eng., C 48, 579 (2015).

    Article  Google Scholar 

  5. D. Eliezer, E. Tal-Gutelmacher, C.E. Cross, and T. Boellinghaus, Mater. Sci. Eng., A 433, 298 (2006).

    Article  Google Scholar 

  6. F. Hua, P. Pasupathi, K. Mon, G. Gordon, and D. Shoesmith, JOM 57, 20 (2005).

    Article  Google Scholar 

  7. V. Macin and H.J. Christ, Int. J. Hydro. Energy 40, 16878 (2015).

    Article  Google Scholar 

  8. S. Baragetti and F. Villa, JOM 67, 1154 (2015).

    Article  Google Scholar 

  9. E. Tal-Gutelmacher and E. Dan, JOM 57, 46 (2005).

    Article  Google Scholar 

  10. C.Q. Chen, S.X. Li, H. Zheng, L.B. Wanga, and K. Lu, Acta Mater. 52, 3687 (2004).

    Google Scholar 

  11. T.K. Zhu and M.Q. Li, J. Alloys Compd. 481, 480 (2009).

    Article  Google Scholar 

  12. R. Laptev, A. Lider, Y. Bordulev, V. Kudiiarov, and G. Garanin, J. Alloys Compd. 645, S193 (2015).

    Article  Google Scholar 

  13. D.B. Shan, Y.Y. Zong, T.F. Lu, and Y. Lv, J. Alloys Compd. 427, 229 (2007).

    Article  Google Scholar 

  14. G. Singh, G. Bajargan, R. Datta, and U. Ramamurty, Mater. Sci. Eng., A 576, 326 (2013).

    Article  Google Scholar 

  15. C.C. Shen and C.M. Wang, J. Alloys Compd. 601, 274 (2014).

    Article  Google Scholar 

  16. J.W. Zhao, H. Ding, H.L. Hou, and Z.Q. Li, J. Alloys Compd. 491, 673 (2010).

    Article  Google Scholar 

  17. Y.Y. Zong, Y.C. Liang, Z.W. Yin, and D.B. Shan, Int. J. Hydrog. Energy 37, 13631 (2012).

    Article  Google Scholar 

  18. Z.G. Sun, G.Q. Chen, Y.Q. Wang, W.L. Zhou, and H.L. Hou, Mater. Sci. Eng., A 527, 1003 (2010).

    Article  Google Scholar 

  19. S.M. Jagadeesh Babua, B.P. Kashyap, N. Prabhu, R. Kapoor, R.N. Singh, and J.K. Chakravartty, Mater. Sci. Eng., A 679, 75 (2017).

    Article  Google Scholar 

  20. R. Gaddam, M. Hörnqvist, M.L. Antti, and R. Pederson, Mater. Sci. Eng., A 612, 354 (2014).

    Article  Google Scholar 

  21. E. Tal-Gutelmacher and D. Eliezer, J. Alloys Compd. S404–406, 621 (2005).

    Article  Google Scholar 

  22. K. Nakasa and H. Satoh, Corros. Sci. 38, 457 (1996).

    Article  Google Scholar 

  23. A. San-Martin and F.D. Manchester, Bull. Alloy Phase Diagr. 8, 30 (1987).

    Article  Google Scholar 

  24. C.Q. Chen, S.X. Li, and K. Lu, Acta Mater. 51, 931 (2003).

    Article  Google Scholar 

  25. V.I. Trefilov, I.A. Morozov, and R.A. Morozov, Int. J. Hydrog. Energy 24, 157 (1999).

    Article  Google Scholar 

  26. H.I. Aaronson, T. Furuhara, J.M. Rigsbee, W.T. Reynolds, and J.M. Howe, Metall. Mater. Trans. A 21, 2369 (1990).

    Article  Google Scholar 

  27. F.D. Manchester and A. San-Martin, Phase diagrams of binary hydrogen alloys, 1st ed. (Materials Park: ASM International, 2000), p. 238.

    Google Scholar 

  28. K.R. Morasch and D.F. Bahr, Scr. Mater. 45, 839 (2001).

    Article  Google Scholar 

  29. L.S. Luo, Y.Q. Su, J.J. Guo, and H.Z. Fu, J. Alloys Compd. 425, 140 (2006).

    Article  Google Scholar 

  30. O.T. Woo, G.C. Weatherly, C.E. Coleman, and R.W. Gilbert, Acta Metall. 33, 1897 (1985).

    Article  Google Scholar 

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Acknowledgements

The authors would like to gratefully acknowledge support of this work by the National Nature Science Foundation of China under Grant No. 51671152, Northwest Institute for Non-ferrous Metal Research. The authors would also like to acknowledge Y.Q. Wang, a researcher at China Aeronautical Manufacturing Technology Research Institute, for high-temperature hydrogen charging.

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Correspondence to Q. M. Liu or Z. H. Zhang.

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Liu, Q.M., Zhang, Z.H., Yang, H.Y. et al. Hydride Precipitation in the Hydrogenated 0.12 wt.%H Weld Zone of Ti-0.3Mo-0.8Ni Alloy Argon-Arc-Welded Joints. JOM 70, 1902–1907 (2018). https://doi.org/10.1007/s11837-018-2978-x

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