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Electrical property improvement of phenolic formaldehyde resin with graphene and ionic liquid

  • Materials (Organic, Inorganic, Electronic, Thin Films)
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Abstract

The ionic liquid 3-decyl-bis(1-vinyl-1H-imidazole-3-ium-bromide) (C10[VImBr]2) was synthesized and its chemical structure characterized by Fourier-transform infrared spectroscopy and 1H nuclear magnetic resonance spectroscopy. To improve the electrical conductivity of the phenolic formaldehyde (PF) resin, PF/graphene and PF/graphene/C10[VImBr]2 composites were prepared via a melt blending and compression-curing process. The impact strength of the composites was shown to increase with the addition of increasing proportion of graphene, and with increasing proportion of C10[VImBr]2, of up to 5 wt%. In detail, the electrical conductivity of the PF/graphene composites increased significantly from 2.3×10−12 to 4×10−4S/cm as the graphene content increased from 0 to 20 wt%. Moreover, the electrical conductivity of the PF/graphene/C10[VImBr]2 composites containing 15 wt% graphene was shown to increase from 5.6×10−5 to 9.2×10−4 S/cm as the content of C10[VImBr]2 increased from 0 to 5 wt%.

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References

  1. M. Wang, X. H. Tanga, J. H. Cai, H. Wu, J. B. Shen and S. Y. Guo, Carbon, 177, 377 (20221).

  2. C. Lin, S. Nie, G. He, L. Ding, Y. Wen, J. Zhang, Z. Yang, J. Liu, S. Liu, J. Li and S. Guo, Compos. Part B-Eng., 203, 108447 (2020).

    Article  CAS  Google Scholar 

  3. T. Sano, H. Ebihara, S. Sano, T. Okabe and H. Itagaki, Eur. Polym. J., 138, 109975 (2020)

    Article  CAS  Google Scholar 

  4. Y. Liu, E. Asare, H. Porwal, E. Barbieri, S. Goutianos, J. Evans, M. Newton, J. J. C. Busfield, T. Peijs, H. Zhang and E. Bilotti, Compos. Part A-Appl. S., 139, 106074 (2020).

    Article  CAS  Google Scholar 

  5. H. J. Park, J. S. Woo and S. Y. Park, Korean J. Chem. Eng., 36, 2133 (2019).

    Article  CAS  Google Scholar 

  6. G. Li, H. Xia, Y. Lei, W. Yang, T. Liu and J. P. He, J. Appl. Polym. Sci., 137, 48820 (2020).

    Article  CAS  Google Scholar 

  7. I. Jodan, K. Wantala, N. Amini, B. Shahmoradi, M. Ghaslani, S. M. Lee, J. Yang and S. H. Puttaiah, Korean J. Chem. Eng., 37, 1609 (2020).

    Article  CAS  Google Scholar 

  8. K. Zhu, H. Jia, Y. Sun, Y. Dai, C. Zhang, X. Guo, T. Wang and L. Zhu, Environ. Int., 145, 106137 (2020).

    Article  CAS  PubMed  Google Scholar 

  9. B. Massoumi, M. Abbasian, R. Mohammad-Rezaei, A. Farnudiyan-Habibi and M. Jaymand, Polym. Adv. Technol., 30, 1484 (2019).

    Article  CAS  Google Scholar 

  10. N. Kamarudin, D. R. A. Biak, Z. Z. Abidin, F. Cardona and S. M. Sapuan, Materials, 13, 2578 (2020).

    Article  CAS  PubMed Central  Google Scholar 

  11. K. Naito, M. Yoshida, Y. Adachi, K. Kawai, O. Sakurada and K. Yashiro, J. Appl. Polym. Sci., 138, 50410 (2021).

    Article  CAS  Google Scholar 

  12. M. Holtzer, R. Dańko, A. Kmita, D. Drożyński, M. Kubecki, M. Skrzyński and A. Roczniak, Materials, 13, 4395 (2020).

    Article  CAS  PubMed Central  Google Scholar 

  13. Y. Huang, Q. Lin, C. Yang, G. Bian, Y. Zhang and W. Yu, J. R. Soc. Interface, 17, 20190755 (2020).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  14. B. Song, X. Wang, S. Patel, F. Wu, K. Moon and C. Wong, Soft Matter, 16, 6765 (2020).

    Article  CAS  PubMed  Google Scholar 

  15. M. Yazdi, B. Noorbakhsh, B. Nazari and Z. Ranjbar, Prog. Org. Coat., 145, 105674 (2020).

    Article  CAS  Google Scholar 

  16. K. Logesh, P. Hariharasakthisudhan, B. S. Rajan, A. A. M. Moshi and V. Khalkar, Polym. Composite., 41, 4849 (2020).

    Article  CAS  Google Scholar 

  17. C. Wang, Y. Gong, B. V. Cunning, S. Lee, Q. Le, S. R. Joshi, O. Buyukcakir, H. Zhang, W. K. Seong, M. Huang, M. Wang, J. Lee, G. H. Kim and R. S. Ruoff, Sci. Adv., 7, 3767 (2021).

    Article  CAS  Google Scholar 

  18. X. You, J. Yang, M. Wang, H. Wang, L. Gao and S. Dong, J. Mater. Sci. Technol., 58, 16 (2020).

    Article  Google Scholar 

  19. Y. Jun, S. Habibpour, M. Hamidinejad, M. Park, W. Ahn, A. Yu and C. Park, Carbon, 174, 305 (2021).

    Article  CAS  Google Scholar 

  20. B. G. Soares, J. Mol. Liq., 262, 8 (2018).

    Article  CAS  Google Scholar 

  21. N. Redki, F. F. Al-blewi, S. A. Al-Sodies, A. K. Alnuzha, M. Messali, I. Ali and M. R. Aouad, ACS Omega, 5, 4807 (2020).

    Article  CAS  Google Scholar 

  22. S. Krishnan, N. A. Ghani, N. F. Aminuddin, K. S. Quraishi, B. L. Razafindramangarafara, S. Baup and J. M. Leveque, Ultrason. Sonochem., 74, 105576 (2021).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  23. J. Texter, R. Crombez, R. Maniglia, X. Ma, V. A. Vasantha, M. Manuelian, R. Campbell, L. Slater and T. Mourey, J. Surfactants Deterg., 22, 1059 (2019).

    CAS  Google Scholar 

  24. J. Atoyo, M. R. Burton, J. McGettrick and M. J. Carnie, Polymers, 12, 559 (2020).

    Article  CAS  PubMed Central  Google Scholar 

  25. R. Pamies, M. D. Avilés, I. Arias-Pardilla, F. I. Carriön, I. Sanes and M. D. Bermúdez, J. Mol. Liq., 278, 368 (2019).

    Article  CAS  Google Scholar 

  26. Y. Wu, L. Han, X. Zhang, J. Mao, L. Gong, W. Guo, K. Gu and S. Li, Polym. Chem., 6, 2560 (2015).

    Article  CAS  Google Scholar 

  27. J. Narongthong, A. Das, H. H. Le, S. Wießner and C. Sirisinha, Compos. Part A-Appl. S., 113, 330 (2018).

    Article  CAS  Google Scholar 

  28. Q. Wu, Q. Shi, J. Shang, M. Wang, H. Li, D. Shi, Y. Zhao and Q. Jiao, ACS Omega, 5, 31171 (2020).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  29. Y. Luo, X. Huang, S. Yao, L. Peng, F. Li and H. Song, Polymers, 12, 2171 (2020).

    Article  CAS  PubMed Central  Google Scholar 

  30. M. Dang, Q. L. Deng, Y. Y. Tian, C. Liu, H. P. Shi, G. Z. Fang and S. Wang, RSC Adv., 10, 5443 (2020).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  31. T. Zaoui, M. Debdab, B. Haddad, E. H. Belarbi, Y. Chaker, M. Rahmouni, S. Bresson and V. Baeten, J. Mol. Struct., 1236, 130264 (2021).

    Article  CAS  Google Scholar 

  32. D. Yokota, A. Kanazawa and S. Aoshima, RSC Adv., 10, 42378 (2020).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  33. A. Karadağ, H. Akbaş, A. Destegül, Ç. Çakirlar, Y. Yerli, Z. Kılıç and F. Sen, Sci. Rep., 10, 11705 (2020).

    Article  PubMed  PubMed Central  CAS  Google Scholar 

  34. J. Chen, R. R. Hu, F. L. Jin and S. J. Park, J. Appl. Polym. Sci., 138, 50250 (2021).

    Article  CAS  Google Scholar 

  35. F. L. Jin, R. R. Hu and S. J. Park, Korean J. Chem. Eng., 37, 905 (2020).

    Article  CAS  Google Scholar 

  36. L. Zhao, Y. Li, X. Cao, J. You and W. Dong, Nanotechnology, 23, 255702 (2012).

    Article  PubMed  CAS  Google Scholar 

  37. J. B. Zhang, H. Zhang, F. L. Jin and S. J. Park, Bull. Mater. Sci., 43, 6 (2020).

    Article  CAS  Google Scholar 

  38. A. K. Singh, Siddhartha and S. Yadav, Polym. Adv. Technol., 28, 1764 (2017).

    Article  CAS  Google Scholar 

  39. R. Xia, X. X. Gao, Y. Zhang, N. Drigo, V. I. E. Queloz, F. F. Tirani, R. Scopelliti, Z. Huang, X. Fang, S. Kinge, Z. Fei, C. Roldán-Carmona, M. K. Nazeeruddin and P. J. Dyson, Adv. Mater., 32, 2003801 (2020).

    Article  CAS  Google Scholar 

  40. K. Jiang, X. Liu, F. Huo, K. Dong, X. Zhang and X. Yao, J. Mol. Liq., 271, 550 (2018).

    Article  CAS  Google Scholar 

  41. S. S. Yao, Q. Q. Pang, R. Song, F. L. Jin and S. J. Park, Macromol. Res., 24, 961 (2016).

    Article  CAS  Google Scholar 

  42. J. Wei, C. Wei, L. Su, J. Fu and J. Lv, J. Mater. Sci. Chem. Eng., 3, 56 (2015).

    CAS  Google Scholar 

  43. R. K. Donato, K. Z. Donato, H. S. Schrekker and L. Matěka, J. Mater. Chem., 22, 9939 (2012).

    Article  CAS  Google Scholar 

  44. A. D. Crescenzo, D. Demurtas, A. Renzetti, G. Siani, P. D. Maria, M. Meneghetti, M. Prato and A. Fontana, Soft Matter, 5, 62 (2009).

    Article  Google Scholar 

  45. J. Guan, C. Xing, Y. Wang, Y. Li and J. Li, Compos. Sci. Technol., 138, 98 (2017).

    Article  CAS  Google Scholar 

  46. J. Chen, Q. Z. Zhang, Z. S. Hou, F. L. Jin and S. J. Park, Bull. Mater. Sci., 42, 153 (2019).

    Article  CAS  Google Scholar 

  47. L. Wang, W. Wang, P. Fan, M. Zhou, J. Yang, F. Chen and M. Zhong, J. Appl. Polym. Sci., 134, 45006 (2017).

    Google Scholar 

  48. M. Asim, M. Jawaid, A. Khan, A. M. Asiri and M. A. Malik, J. Mater. Res. Technol., 9, 3614 (2020).

    Article  CAS  Google Scholar 

  49. G. Yang, Y. Wang, H. Xu, S. Zhou, S. Jia and J. Zang, Appl. Surf. Sci., 447, 837 (2018).

    Article  CAS  Google Scholar 

  50. F. L. Jin, C. L. Ma, B. T. Guo and S. J. Park, Bull. Korean Chem. Soc., 40, 991 (2019).

    Article  CAS  Google Scholar 

  51. F. L. Jin, H. Zhang, S. S. Yao and S. J. Park, Macromol. Res., 26, 211 (2018).

    Article  CAS  Google Scholar 

  52. S. S. Yao, C. L. Ma, F. L. Jin and S. J. Park, Korean J. Chem. Eng., 37, 2075 (2020).

    Article  CAS  Google Scholar 

  53. B. Wang, Q. Fu, H. Li, L. Qi and Y. Liu, J. Alloy. Compd., 854, 157176 (2021).

    Article  CAS  Google Scholar 

  54. H. B. Ziarati, M. Fasihi and H. Omranpour, J. Appl. Polym. Sci., 137, 48331 (2020).

    Article  CAS  Google Scholar 

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Acknowledgements

This work was supported by the Technology Innovation Program (or Industrial Strategic Technology Development Program-Development of technology on materials and components) (20010106, Adhesives with low water permeability and low outgassing) funded by the Ministry of Trade, Industry & Energy (MOTIE, Korea).

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Authors and Affiliations

  1. Institute of Petrochemical Technology, Jilin Institute of Chemical Technology, Jilin, 132022, P. R. China

    Hong Wang

  2. Department of Polymer Materials, Jilin Institute of Chemical Technology, Jilin City, 132022, P. R. China

    Shan-Shan Yao & Fan-Long Jin

  3. Department of Chemistry, College of Science, Yanbian University, Yanji, 133002, Jilin, China

    Zhifu Guan

  4. Department of Chemistry, Inha University, Michuhol-gu, Incheon, 22212, Korea

    Soo-Jin Park

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  1. Hong Wang
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  2. Shan-Shan Yao
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  3. Zhifu Guan
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  4. Fan-Long Jin
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  5. Soo-Jin Park
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Correspondence to Fan-Long Jin or Soo-Jin Park.

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Wang, H., Yao, SS., Guan, Z. et al. Electrical property improvement of phenolic formaldehyde resin with graphene and ionic liquid. Korean J. Chem. Eng. 38, 2332–2340 (2021). https://doi.org/10.1007/s11814-021-0860-y

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  • DOI: https://doi.org/10.1007/s11814-021-0860-y

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