Skip to main content
SpringerLink
Log in

The nano-magnetite-loaded 2-mercaptobenzoxazole as an adsorbent for the selective removal of the Pb2+, Ni2+ and Cd2+ ions from aqueous solutions

  • Separation Technology, Thermodynamics
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

The present research focuses on the adsorption efficiency of nano-magnetite loaded 2-mercapto-benzoxazole as an adsorbent (Fe3O4@SiO2@CPTMS@MBOL) for Pb+2, Ni+2 and Cd+2 removal from the contaminated water by the technique of adsorption. The influence of pH, contact time, adsorbent dosage and temperature in 50 ppm concentration of each ion solutions on the sensitivity of the removal procedure was examined. By ICP test the adsorption data were fixed to linearize the adsorption isotherms of the Langmuir and Freundlich equations. This efficient adsorbent showed significant results for metal ion removal from water by formation of complex with adsorbent. From the Langmuir isotherm, the maximum adsorption capacities of nano magnetic adsorbent towards Pb2+, Ni2+ and Cd2+ ions were 238.4, 203.2 and 22.37 mgg−1.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Y. Sun, K. J. Shah, W. Sun and H. Zheng, Sep. Purif. Technol., 215, 208 (2019).

    Article  CAS  Google Scholar 

  2. S. Muthusaravanan, N. Sivarajasekar, J. S. Vivek, T. Paramasivan, M. Naushad, J. Prakashmaran, V. Gayathri and O. K. Al-Duaij, Environ. Chem. Lett., 16, 1339 (2018).

    Article  CAS  Google Scholar 

  3. K. Rambabu, A. Thanigaivelan, G. Bharath, N. Sivarajasekar, F. Banat and P. L. Show, Chemosphere, 268, 128809 (2021).

    Article  CAS  Google Scholar 

  4. K. Janani, N. Sivarajasekar, S. Muthusaravanan, K. Ram, J. Prakashmaran, S. Sivamani, N. Dhakal, T. Shahnaz and N. Selvaraju, Bioresour. Technol., 7, 100265 (2019).

    Article  Google Scholar 

  5. V. J. Sharavanan, M. Sivaramakrishnan, N. Sivarajasekar, N. Senthilrani, R. Kothandan, N. Dhakal, S. Sivamani, P. L. Show, M. R. Awual and M. Naushad. Environ. Chem. Lett., 18, 325 (2020).

    Article  CAS  Google Scholar 

  6. S. Muthusaravanan, N. Sivarajasekar, J. S. Vivek, S. V. Priyadharshini, T. Paramasivan, N. Dhakal and M. Naushad, Green Materials for Wastewater Treatment, 38, 191 (2020).

    Article  Google Scholar 

  7. B. M. Jun, N. Her, C. M. Park and Y. Yoon, Environ. Sci. Water Res. Technol., 6, 173 (2020).

    Article  CAS  Google Scholar 

  8. M. Corral Bobadilla, R. Lostado Lorza, F. Somovilla Gómez and R. Escribano García, Water, 12, 1320 (2020).

    Article  Google Scholar 

  9. C. P. Devatha and S. Shivani, J. Environ. Manage., 258, 110038 (2020).

    Article  CAS  Google Scholar 

  10. A. Azimi, A. Azari, M. Rezakazemi and M. Ansarpour, ChemBioEng Rev., 4, 37 (2017).

    Article  Google Scholar 

  11. M. M Rahman, M. Asaduzzaman and R. Naidu, J. Hazard. Mater., 262, 1056 (2013).

    Article  Google Scholar 

  12. M. Anjum, R. Miandad, M. Waqa, F. Gehany and M. A. Barakat, Arab. J. Chem., 12, 4897 (2019).

    Article  CAS  Google Scholar 

  13. L. C. Lin, J. K. Li and R. S. Juang, Desalination, 225, 249 (2008).

    Article  CAS  Google Scholar 

  14. H. L. Fan, S. F. Zhou, W. Z. Jiao, G. S. Qi and Y. Z. Liu, Carbohydr. Polym., 174, 1192 (2017).

    Article  CAS  Google Scholar 

  15. H. Bessbousse, T. Rhlalou, J. F. Verchère and L. Lebrun, J. Member. Sci., 307, 249 (2008).

    Article  CAS  Google Scholar 

  16. Y Benito and M. L. Ruiz, Desalination, 142, 229 (2002).

    Article  CAS  Google Scholar 

  17. F. Zhao, W. Z. Tang, D. Zhao, Y. Meng, D. Yin and M. Sillanpää, J. Water Process Eng., 4, 47 (2014).

    Article  Google Scholar 

  18. M. Kobya, E. Demirbas, E. Senturk and M. Ince, Bioresour. Technol, 96, 1518 (2005).

    Article  CAS  Google Scholar 

  19. P. Panneerselvam, V. Bala, N. Thinakaran, P. Baskaralingam, M. Palanichamy and S. Sivanesan, E- J. Chem., 6, 729 (2009).

    Article  CAS  Google Scholar 

  20. M. Q. Jiang, X. Y. Jin, X. Q. Lu and Z. L. Chen, Desalination, 252, 33 (2010).

    Article  CAS  Google Scholar 

  21. R. D. Ambashta and M. Sillanpää, J. Hazard. Mater., 180, 38 (2010).

    Article  CAS  Google Scholar 

  22. Y. C. Sharma, V. Srivastava, V. K. Singh, S. N. Kaul and C. H. Weng, Environ. Technol., 30, 583 (2009).

    Article  CAS  Google Scholar 

  23. B. R. White, B. T. Stackhouse and J. A. Holcombe, J. Hazard. Mater., 161, 848 (2009).

    Article  CAS  Google Scholar 

  24. Y. C. Sharma and V. Srivastava, J. Chem. Eng. Data, 55, 1441 (2010).

    Article  CAS  Google Scholar 

  25. H. Karami, Chem. Eng. J., 219, 209 (2013).

    Article  CAS  Google Scholar 

  26. A. Z. M. Badruddoza, Z. B. Z. Shawon, W. J. D. Tay, K. Hidajat and M. S. Uddin, Carbohydr. Polym., 91, 322 (2013).

    Article  CAS  Google Scholar 

  27. M. Ariannezhad, D. Habibi and S. Heydari, Russ. J. Org. Chem., 55, 1591 (2019).

    Article  CAS  Google Scholar 

  28. S. J. Hawkes, J. Chem. Educ., 73, 516 (1996).

    Article  CAS  Google Scholar 

  29. H. Watanabe and J. E. Seto, Bull. Chem. Soc. Jpn., 59, 2683 (1986).

    Article  CAS  Google Scholar 

  30. R. Pirarath, P. Shivashanmugam, A. Syed, A. M. Elgorban, S. Anandan and M. Ashokkumar, Front Environ. Sci. Eng., 15, 1 (2021).

    Article  Google Scholar 

  31. H. K. Boparai, M. Joseph and D. M. O’Carroll, J. Hazard. Mater., 186, 458 (2011).

    Article  CAS  Google Scholar 

  32. T. Madrakian, A. Afkhami and M. Ahmadi, Chemosphere, 90, 542 (2013).

    Article  CAS  Google Scholar 

  33. N. Lian, X. Chang, H. Zheng, S. Wang, Y. Cui and Y. Zhai, Microchm. Acta, 151, 81 (2005).

    Article  CAS  Google Scholar 

  34. S. Mohammadi, D. Afzali and D. Pourtalebi, Open Chem., 8, 662 (2010).

    Article  CAS  Google Scholar 

  35. J. Liu, C. Hu and Q. Huang, Bioresour. Technol., 271, 487 (2019).

    Article  CAS  Google Scholar 

  36. Y. Cui, X. Chang, Y. Zhai, Z. H. Zhu and N. Lian, Microchem. J., 83, 35 (2006).

    Article  CAS  Google Scholar 

  37. A. Ozer, J. Hazard. Mater., 141, 753 (2007).

    Article  CAS  Google Scholar 

  38. A. Heidari, H. Younesi and Z. Mehraban, Chem. Eng. J., 153, 70 (2009).

    Article  CAS  Google Scholar 

  39. C. Huang and B. Hu, Spectrochim. Acta Part B., 63, 437 (2008).

    Article  Google Scholar 

Download references

Acknowledgement

Gratefully this project was financially supported by Bu-Ali Sina University.

Author information

Authors and Affiliations

  1. Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, 6517838683, Iran

    Maryam Ariannezhad, Davood Habibi, Somayyeh Heydari & Vahideh Khorramabadi

  2. Department of Research and Development of the Faran Shimi Pharmaceutical Company, Tuyserkan, Iran

    Somayyeh Heydari

Authors
  1. Maryam Ariannezhad
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Davood Habibi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Somayyeh Heydari
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Vahideh Khorramabadi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Maryam Ariannezhad.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ariannezhad, M., Habibi, D., Heydari, S. et al. The nano-magnetite-loaded 2-mercaptobenzoxazole as an adsorbent for the selective removal of the Pb2+, Ni2+ and Cd2+ ions from aqueous solutions. Korean J. Chem. Eng. 38, 1510–1521 (2021). https://doi.org/10.1007/s11814-021-0792-6

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-021-0792-6

Keywords

Search

Navigation