Skip to main content
SpringerLink
Log in

Rheological characterization of ferrous sulfate-containing water-in-oil-in-water (W1/O/W2) double emulsions

  • Polymer, Industrial Chemistry, Fluidization, Particle Technology
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

With use of response surface methodology (RSM), the W1/O/W2 emulsions containing ferrous sulfate as the inner phase were optimized in terms of stability (ES) and apparent viscosity (μ app ). Curvature display of the responses around their optimal settings was appropriately described using the quadratic polynomial regression model. The non-Newtonian behavior of the test W1/O/W2 emulsions was characterized using the power-law model and change from non-Newtonian to Newtonian (n≃1) was seen in the case of W1/O:W2 ratio equal 20: 80 when the level of Tween-80 was 1 v%. Results of the size distribution pattern showed 60% of the particles were less than 5 μm. Rheological properties of the test W1/O/W2 emulsions as the viscoelastic liquids were analyzed and the results of oscillatory experiments considering shear stress and frequency dependency of G′ and G″ moduli were discussed in terms of the internal microstructure of the emulsions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. J. McClements, Food emulsions: Principles, practices, and techniques, CRC Press Boca Raton Fl (2005).

    Google Scholar 

  2. F. Nazzaro, P. Orlando and F. Fratianni, Curr. Opin. Biotechnol., 23, 182 (2012).

    Article  CAS  Google Scholar 

  3. F. J. Colmenero, Food Res. Int., 52, 64 (2013).

    Article  Google Scholar 

  4. A. K. Anal and H. Singh, Trends Food Sci. Technol., 18, 240 (2007).

    Article  CAS  Google Scholar 

  5. N. Garti, Lebensm-Wiss Technol., 30, 222 (1997).

    Article  CAS  Google Scholar 

  6. J. L. Salager, R. E. Anton, D.A. Sabatini, J. H. Harwell, E. J. Acosta and L. I. Tolosa, J. Surfactants Deterg., 8, 3 (2005).

    Article  CAS  Google Scholar 

  7. T. Schmidt, D. Dobler, A. Guldan, N. Paulus and F. Runkel, Colloids Surf. A., 372, 48 (2010).

    Article  Google Scholar 

  8. Sh. Magdassi, M. Frenkel, N. Garti and R. Kasan, J. Colloid Interface Sci., 97(2), 374 (1984).

    Article  CAS  Google Scholar 

  9. S. R. Derkatch, S. M. Levachov, A. N. Kuhkushkina, N.V. Novosyolova, A. E. Kharlov and V. N. Matveenko, Colloids Surf. A., 298, 225 (2007).

    Article  CAS  Google Scholar 

  10. E. Dickinson and S. T. Hong, Colloids Surf. A., 127, 1 (1997).

    Article  CAS  Google Scholar 

  11. B. P. Binks and S. O. Lumsdon, Langmuir, 17, 4540 (2001).

    Article  CAS  Google Scholar 

  12. M. Inoue, K. Hashizaki and H. Taguchi, Y. Saito, Chem. Pharm. Bull., 56(5), 668 (2008).

    Article  CAS  Google Scholar 

  13. L. Davarpanah and F. Vahabzadeh, Starch/Starke, 64, 898 (2012).

    CAS  Google Scholar 

  14. L. Davarpanah, F. Vahabzadeh and A. Dermanaki, Oil Gas Sci. Technol., (2013), DOI: 10.2516/ogst/2012066.

    Google Scholar 

  15. I. Terrisse, M. Seiller, A. Rabaron and J. L. Grossiord, Int. J. Cosmetic. Sci., 15, 53 (1993).

    Article  CAS  Google Scholar 

  16. THF. Tadros, Colloids Surf. A., 91, 39 (1994).

    Article  CAS  Google Scholar 

  17. M. M. Murillo-Martinez, R. Pedroza-Islas, C. Lobato-Calleros, A. Martinez-Ferez and E. J. Vernon-Carter, Food Hydrocoll., 25, 577 (2011).

    Article  CAS  Google Scholar 

  18. O. R. Fennema, Food Chemistry, Marcel Dekker NY (1985).

    Google Scholar 

  19. R. H. Myers and D. C. Montgomery, Response surface methodology process and product optimization using designed experiments, Wiley NY (2002).

    Google Scholar 

  20. L. L. Lapin, Modern Engineering Statistics, Wards-worth Publishing Company elmont, CA, USA (1997).

    Google Scholar 

  21. http://www.statease.com/dx8_man.html.

  22. Y. Kim, C. Morr and T. Schenz, J. Agric. Food Chem., 44, 1308 (1996).

    Article  CAS  Google Scholar 

  23. T. Aoki, A. E. Decker and D. J. McClements, Food Hydrocoll., 19, 209 (2005).

    Article  CAS  Google Scholar 

  24. M. P. Yadav, M. Igartuburu, Y. Yan and E. A. Nothnagel, Food Hydrocoll., 21, 297 (2007).

    Article  CAS  Google Scholar 

  25. J. Jiao and D. J. Burgess, AAPS PharmSci., 5(1) Article 7, (2003) (http://www.pharmsci.org).

    Google Scholar 

  26. R. Lutz, A. Aserin, L. Wicker and N. Garti, Colloids Surf. B., 72, 121 (2009).

    Article  CAS  Google Scholar 

  27. L.G. Torres, R. Iturbe, M. J. Snowden, B. Z. Chowdhry and S. A. Leharne, Colloids Surf. A., 302, 439 (2007).

    Article  CAS  Google Scholar 

  28. E. Ibanoglu, J. Food Eng., 52, 273 (2002).

    Article  Google Scholar 

  29. R. Toledo, Fundamentals of food process engineering, van Nostrand Reinhold NY (1991).

    Book  Google Scholar 

  30. P.M. Doran, Bioprocess engineering principles, Academic Press (1995).

    Google Scholar 

  31. X. Huang, Y. Kakuda and W. Cui, Food Hydrocoll., 15, 533 (2001).

    Article  CAS  Google Scholar 

  32. J. Frelichowska, M. A. Bolzinger and Y. Chevalier, J. Colloid Interface Sci., 351, 348 (2010).

    Article  CAS  Google Scholar 

  33. R. P. Gullapalli and B. B. Sheth, Eur. J. Pharm. Biopharm., 48, 233 (1999).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemical Engineering Department, Amirkabir University of Technology (Tehran Polytechnic), 424 Hafez Ave, Tehran, Iran

    Mozhgan Keyvani, Leila Davarpanah & Farzaneh Vahabzadeh

Authors
  1. Mozhgan Keyvani
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Leila Davarpanah
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Farzaneh Vahabzadeh
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Farzaneh Vahabzadeh.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Keyvani, M., Davarpanah, L. & Vahabzadeh, F. Rheological characterization of ferrous sulfate-containing water-in-oil-in-water (W1/O/W2) double emulsions. Korean J. Chem. Eng. 31, 1681–1694 (2014). https://doi.org/10.1007/s11814-014-0102-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-014-0102-7

Keywords

Search

Navigation