Abstract
Four different membrane-electrode-assemblies (MEAs) with single and dual-layer gas diffusion layers (GDLs) at the anode and the cathode were prepared to examine polarization characteristics that rely on MEA configuration. Porous structure of single and dual-layer GDLs was investigated using a mercury porosimeter. An MEA with dual-layer GDLs at each electrode demonstrated higher performance with an air feed. To comprehend the improvement, the impedance behavior at various current densities and polarization behavior under back pressure were analyzed in terms of oxygen diffusion processes that control catalyst utilization in the gas diffusion electrode.
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M. Mathias, J. Roth, J. Fleming and W. Lehnert, in Handbook of fuel cells, W. Vielstich, A. Lamm and H. A. Gasteiger Eds., John Wiley & Sons, New York (2003).
F. Barbir, PEM fuel cells, Elsevier Academic Press, Burlington (2005).
M.V. Williams, E. Begg, L. Bonville, H. R. Kunz and J. M. Fenton, J. Electrochem. Soc., 151, A1173 (2004).
S. Park, J.W. Lee and B. N. Popov, Int. J. Hydrog. Energy, 37, 5850 (2012).
V. A. Paganin, E.A. Ticianelli and E. R. Gonzalez, J. Appl. Electrochem., 26, 297 (1996).
F. Lufrano, E. Passalacqua, G. Squadrito, A. Patti and L. Giorgi, J. Appl. Electrochem., 29, 445 (1999).
E. Passalacqua, G. Squadrito, F. Lufrano, A. Patti and L. Giorgi, J. Appl. Electrochem., 31, 449 (2001).
Z. Qi and A. Kaufman, J. Power Sources, 109, 38 (2002).
E. Antolini, R.R. Passos and E. A. Ticianelli, J. Power Sources, 109, 477 (2002).
J. H. Nam and M. Kaviany, Int. J. Heat Mass Transfer, 46, 4595 (2003).
U. Pasaogullari and C.Y. Wang, Electrochim. Acta, 49, 4359 (2004).
G.G. Park, Y. J. Sohn, T. H. Yang, Y.G. Yoon, W.Y. Lee and C. S. Kim, J. Power Sources, 131, 182 (2004).
A. Z. Weber and J. Newman, J. Electrochem. Soc., 152, A677 (2005).
S. Park, J.W. Lee and B. N. Popov, J. Power Sources, 177, 457 (2008).
A. Z. Weber and J. Newman, J. Electrochem. Soc., 153, A2205 (2006).
S. Kim and M. M. Mench, J. Electrochem. Soc., 156, B353 (2009).
L. Cindrella, A. M. Kannan, R. Ahmad and M. Thommes, Int. J. Hydrog. Energy, 34, 6377 (2009).
Y. X. Wang, S. Al Shakhshir and X.G. Li, Appl. Energy, 88, 2168 (2011).
R. Schweiss, M. Steeb and P. M. Wilde, Fuel Cells, 10, 1176 (2010).
M. Ahn, Y. H. Cho, J. Kim, N. Jung and Y. E. Sung, Electrochim. Acta, 56, 2450 (2011).
M. Kaviany, Principles of heat transfer in porous media, Springer-Verlag, New York (1991).
S. Park and B. N. Popov, Electrochim. Acta, 54, 3473 (2009).
C. S. Kong, D.Y. Kim, H. K. Lee, Y.G. Shul and T.H. Lee, J. Power Sources, 108, 185 (2002).
G. Lin and T.V. Nguyen, J. Electrochem. Soc., 152, A1942 (2005).
T. E. Springer and I.D. Raistrick, J. Electrochem. Soc., 136, 1594 (1989).
I. D. Raistrick, Electrochim. Acta, 35, 1579 (1990).
M. Ciureanu and R. Roberge, J. Phys. Chem. B, 105, 3531 (2001).
Y. Bultel, K. Wiezell, F. Jaouen, P. Ozil and G. Lindbergh, Electrochim. Acta, 51, 474 (2005).
T. E. Springer, M. S. Wilson and S. Gottesfeld, J. Electrochem. Soc., 135, 1594 (1989).
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Park, S., Popov, B.N. Effect of membrane-electrode-assembly configuration on proton exchange membrane fuel cell performance. Korean J. Chem. Eng. 31, 1384–1388 (2014). https://doi.org/10.1007/s11814-014-0037-z
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DOI: https://doi.org/10.1007/s11814-014-0037-z