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Influence of sodium dodecyl sulfate and cetyl trimethylammonium bromide upon calcium carbonate precipitation on bacterial cellulose

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Abstract

Calcium carbonate was deposed on bacterial cellulose (BC) never-dried membranes in the presence of different concentrations of sodium dodecyl sulfate (SDS) and cetyl trimethylammonium bromide (CTAB) by a precipitation reaction between aqueous solutions of calcium chloride (CaCl2) and sodium carbonate (Na2CO3) containing, or not, surfactant in their composition. Different shapes of crystals were obtained from rhombohedral ones to flowerlike, depending on surfactant type and concentration. From the two surfactants tested, SDS has a greater influence on calcium carbonate morphology than CTAB. The only polymorph obtained in all studied cases was calcite. The composite films BC-calcite were characterized by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and color measurements. The obtained BC-calcium carbonate composites could be used in paper manufacturing.

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Authors and Affiliations

  1. Faculty of Applied Chemistry and Materials Science, Politehnica University of Bucharest, Polizu 1-3, Bucharest, 011061, Romania

    Marta Stroescu, Anicuta Stoica-Guzun, Sorin Ion Jinga, Tanase Dobre, Iuliana Mihaela Jipa & Loredana Mihaela Dobre

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  1. Marta Stroescu
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  2. Anicuta Stoica-Guzun
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  3. Sorin Ion Jinga
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  4. Tanase Dobre
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  5. Iuliana Mihaela Jipa
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  6. Loredana Mihaela Dobre
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Correspondence to Anicuta Stoica-Guzun.

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Stroescu, M., Stoica-Guzun, A., Jinga, S.I. et al. Influence of sodium dodecyl sulfate and cetyl trimethylammonium bromide upon calcium carbonate precipitation on bacterial cellulose. Korean J. Chem. Eng. 29, 1216–1223 (2012). https://doi.org/10.1007/s11814-011-0290-3

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  • DOI: https://doi.org/10.1007/s11814-011-0290-3

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