Abstract
To compare the adsorption kinetics of Cu, Zn and Cd introduced into red soils simultaneously and sequentially as well as their distribution coefficients, the ability of red soils to retain heavy metals was evaluated by performing batch experiments. The results indicate that Cu is preferentially adsorbed by red soils no matter in simultaneous or in sequential situation. The adsorption amount of Cd is the minimum in simultaneous competitive adsorption experiment. As heavy metals are added into red soils sequentially, the heavy metal adsorptions are relatively hard to reach equilibrium in 2 h. Red soils retain more Cd than Zn, which is opposite to the result in simultaneous adsorption. The addition sequences of heavy metals affect their adsorbed amounts in red soils to a certain extent. The joint distribution coefficients of metals in simultaneous adsorption are slightly higher than those in sequential adsorption.
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ADRIANO D C. Trace elements in terrestrial environments: Biogeochemistry, bioavailability, and risks of metals [M]. New York: Springer, 2001:1–10.
MOLINA M, MANQUIA-CERDA K, ESCUDEY M. Sorption and selectivity sequences of Cd, Cu, Ni, Pb, and Zn in single-and multi-component systems in a cultivated Chilean Mollisol [J]. Soil and Sediment Contamination, 2010, 19(4):405–418.
GUO Xue-yan, ZHANG Shu-zhen, SHAN Xiao-quan, LUO Lei, PEI Zhi-guo, ZHU Yong-guan, LIU Tao, XIE Ya-ning, GAULT A. Characterization of Pb, Cu, and Cd adsorption on particulate organic matter in soil [J]. Environmental Toxicology and Chemistry, 2006, 25(9):2366–2373.
ZHONG Kuang-biao, GUI Ming, ZHU Li-yong, LI Wei, GUAN Cha-xiang, GUO Fang-qiu. Heavy metals accumulation effect in rabbit body fluids after smoking [J]. Journal of Central South University of Technology, 2011, 18(5):1408–1412.
ANTONIADIS V, MCKINLEY J D, ZUHAIRI W Y W. Single-element and competitive metal mobility measured with column infiltration and batch tests [J]. Journal of Environmental Quality, 2007, 36(1):53–60.
MCBRIDE M, SAUVE S, HENDERSHOT W. Solubility control of Cu, Zn, Cd and Pb in contaminated soils [J]. European Journal of Soil Science, 1997, 48(2):337–346.
FLOGEAC K, GUILLON E, APLINCOURT M. Competitive sorption of metal ions onto a north-eastern France soil: Isotherms and XAFS studies [J]. Geoderma, 2007, 139(1):180–189.
AGBENIN J O, OLOJO L A. Competitive adsorption of copper and zinc by a Bt horizon of a savanna Alfisol as affected by pH and selective removal of hydrous oxides and organic matter [J]. Geoderma, 2004, 119(1):85–95.
GUPTA M K, SINGH A K, SRIVASTAVA R K. Kinetic sorption studies of heavy metal contamination on Indian expansive soil [J]. Journal of Chemistry, 2009, 6(4):1125–1132.
SIPOS P, NEMETH T, KIS V K, MOHAI I. Sorption of copper, zinc and lead on soil mineral phases [J]. Chemosphere, 2008, 73(4):461–469.
SERRANO S, O’DAY P A, VLASSOPOULOS D, GARCIA-GONZALEZ M T, GARRIDO F. A surface complexation and ion exchange model of Pb and Cd competitive sorption on natural soils [J]. Geochimica Et Cosmochimica Acta, 2009, 73(3):543–558.
LI Ying, YUE Qin-yan, GAO Bao-yu. Adsorption kinetics and desorption of Cu(II) and Zn(II) from aqueous solution onto humic acid [J]. Journal of Hazardous Materials, 2010, 178(1):455–461.
COVELO E F, ANDRADE M L, VEGA F A. Heavy metal adsorption by humic umbrisols: Selectivity sequences and competitive sorption kinetics [J]. Journal of Colloid and Interface Science, 2004, 280(1):1–8.
SEN G S, BHATTACHARYYA K G. Kinetics of adsorption of metal ions on inorganic materials: A review [J]. Advances in Colloid and Interface Science, 2011, 162(1):39–58.
SPARKS D L. Kinetics of soil chemical processes [M]. San Diego: Academic Press, 1989:30–33.
XU Ren-kou, ZHAO An-zhen, LI Qing-man, KONG Xiao-ling, JI Guo-liang. Acidity regime of the red soils in a subtropical region of southern China under field conditions [J]. Geoderma, 2003, 115(1):75–84.
BAO Shi-dan. Agricultural chemical analysis of soil [M]. Beijing: Chinese Agriculture Press, 2000:154–159. (in Chinese)
LU Ru-kun. Analytical methods of soil agrochemistry [M]. Beijing: China Agricultural Science and Technology Press, 1999:278–281. (in Chinese)
REDDY M R, DUNN S J. Distribution coefficients for nickel and zinc in soils [J]. Environmental Pollution Series B, Chemical and Physical, 1986, 11(4):303–313.
ANDERSON P R, CHRISTNSEN T H. Distribution coefficients of Cd, Co, Ni, and Zn in soils [J]. Journal of Soil Science, 2006, 39(1):15–22.
KAPLAN D I, SEME R J, PIEPHO M G. Geochemical factors affecting radionuclide transport through near and far fields at a low-level waste disposal site: Available sorption constants and recommendations for future studies [M]. Richland, WA: Pacific Northwest Laboratory, 1995:7–9.
SIPOS P. Sorption of copper and lead on soils and soil clay fractions with different clay mineralogy [J]. Carpathian Journal of Earth and Environmental Sciences, 2010, 5(2):111–118.
LU S G, XU Q F. Competitive adsorption of Cd, Cu, Pb and Zn by different soils of Eastern China [J]. Environmental Geology, 2009, 57(3):685–693.
VIBHAWARI, PANDEY N D. Single and competitive sorption of heavy metal ions (Cd2+ and Cu2+) on a clayey soil [J]. E-Journal of Chemistry, 2010, 7:S27–S34.
ELLIOTT H A, LIBERATI M R, HUANG C P. Competitive adsorption of heavy metals by soils [J]. Journal of Environmental Quality, 1986, 15(3):214–219.
ABD-ELFATTAH A, WADA K. Adsorption of lead, copper, zinc, cobalt, and cadmium by soils that differ in cation-exchange materials [J]. Journal of Soil Science, 1981, 32(2):271–283.
PARDO M T. Sorption of lead, copper, zinc, and cadmium by soils: Effect of nitriloacetic acid on metal retention [J]. Communications in Soil Science and Plant Analysis, 2000, 31(1/2):31–40.
SERRANO S, GARRIDO F, CAMPBELL C G, GARCIA- GONZALEZ M T. Competitive sorption of cadmium and lead in acid soils of central Spain [J]. Geoderma, 2005, 124(1):91–104.
APPEL C, MA L Q, RHUE R D, REVE W. Sequential sorption of lead and cadmium in three tropical soils [J]. Environmental Pollution, 2008, 155(1):132–140.
ECHEVERRIA J C, MORERA M T, MAZKIARAN C, GARRIDO J J. Competitive sorption of heavy metal by soils: Isotherms and fractional factorial experiments [J]. Environmental Pollution, 1998, 101(2):275–284.
GAO Su-duan, WALKER W J, DAHLGREN R A, BOLD J. Simultaneous sorption of Cd, Cu, Ni, Zn, Pb, and Cr on soils treated with sewage sludge supernatant [J]. Water, Air, and Soil Pollution, 1997, 93(1/2/3/4):331–345.
USMAN A R A. The relative adsorption selectivities of Pb, Cu, Zn, Cd and Ni by soils developed on shale in New Valley, Egypt [J]. Geoderma, 2008, 144(1):334–343.
HUANG Bin, LI Zhong-wu, HUANG Jin-quan, GUO Liang, NIE Xiao-dong, WANG Yan, ZHANG Yan, ZENG Guang-ming. Adsorption characteristics of Cu and Zn onto various size fractions of aggregates from red paddy soil [J]. Journal of Hazardous Materials, 2014, 264:176–183.
XU Ren-kou, XIAO Shuang-cheng, ZHAO An-zhen. Effect of Cu(II) on adsorption of Cr(VI) by red soils [J]. Journal of Agro-Environment Science, 2008, 27(3):944–947. (in Chinese)
ZOU Xian-zhong, ZHAO An-zhen, JI Guo-liang. Release of hydrogen ions during adsorption of copper ions by variable charge soils [J]. Acta Pedologica Sinica, 2002, 39(3):308–317. (in Chinese)
EVANS R C. An introduction to crystal chemistry [M]. Cambridge: Cambridge University Press, 1964:38–42.
NIGHTINGALE J E R. Phenomenological theory of ion solvation: effective radii of hydrated ions [J]. The Journal of Physical Chemistry, 1959, 63(9):1381–1387.
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Foundation item: Projects(40971179, 41271294) supported by the National Natural Science Foundation of China; Project(NCET-09-330) supported by the Program for New Century Excellent Talents in University, China; Project(11JJ3041) supported by the Natural Science Foundation of Hunan Province, China
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Wang, Y., Li, Zw., Huang, B. et al. Kinetics comparison on simultaneous and sequential competitive adsorption of heavy metals in red soils. J. Cent. South Univ. 22, 1269–1275 (2015). https://doi.org/10.1007/s11771-015-2643-2
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DOI: https://doi.org/10.1007/s11771-015-2643-2