Abstract
Growing demands on thermal barrier coatings (TBCs) for gas turbines regarding their temperature and cyclic capabilities, corrosion resistance, and erosion performance have instigated the development of new materials and coating systems. Different pyrochlores, perovskites, doped yttria-stabilized zirconia, and hexaaluminates have been identified as promising candidates. However, processing these novel TBC materials by plasma spraying is often challenging. During the deposition process, stoichiometric changes, formation of undesired secondary phases or non-optimum amorphous contents, as well as detrimental microstructural effects can occur in particular. This article describes these difficulties and the development of process-related solutions by employing diagnostic tools.
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References
R.A. Miller, Current Status of Thermal Barrier Coatings—An Overview, Surf. Coat. Technol., 1987, 30, p 1-11
R. Vaßen, H. Kaßner, A. Stuke, F. Hauler, D. Hathiramani, and D. Stöver, Advanced Thermal Spray Technologies for Applications in Energy Systems, Surf. Coat. Technol., 2008, 202, p 4432-4437
G. Mauer and R. Vaßen, Technology Vision: Current Developments and Challenges in Thermal Barrier Coatings, Surf. Eng., 2011, 27(7), p 477-479
D.J. de Wet, R. Taylor, and F.H. Stott, Corrosion Mechanisms of ZrO2-Y2O3 Thermal Barrier Coatings in the Presence of Molten Middle-East Sand, J. Phys. IV France, 1993, 3, p C9-655-C9-663
A. Aygun, A.L. Vasilev, N.P. Padture, and X. Ma, Novel Thermal Barrier Coatings that are Resistant to High-Temperature Attack by Glassy Deposits, Acta Mater., 2007, 55(20), p 6734-6745
S. Krämer, J. Yang, and C.G. Levi, Infiltration-Inhibiting Reaction of Gadolinium Zirconate Thermal Barrier Coatings with CMAS Melts, J. Am. Ceram. Soc., 2008, 91(2), p 576-583
R. Wenglarz and J. Oakey, Gas Turbine Issues in Advanced Gasification Systems, Materials for Advanced Power Engineering 2006: Proceedings of the 8th Liège Conference, J. Lecomte-Beckers, M. Carton, F. Schubert, and P.J. Ennis, Ed., Forschungszentrum Jülich, Jülich, 2006
P. Mohan, B. Yuan, T. Patterson, V.H. Desai, and Y.H. Sohn, Degradation of Yttria-Stabilized Zirconia Thermal Barrier Coatings by Vanadium Pentoxide, Phosphorous Pentoxide, and Sodium Sulfate, J. Am. Ceram. Soc., 2007, 90(11), p 3601-3607
U. Schulz, B. Saruhan, K. Fritscher, and C. Leyens, Review on Advanced EB-PVD Ceramic Topcoats for TBC Applications, Int. J. Appl. Ceram. Technol., 2004, 1(4), p 302-315
L. Pawlowski, The Science and Engineering of Thermal Spray Coatings, 2nd ed., John Wiley & Sons, Chichester, 2008
R.B. Heimann, Plasma Spray Coating, 2nd ed., Wiley-VCH, Weinheim, 2008
R. Vaßen, M.O. Jarligo, T. Steinke, D.E. Mack, and D. Stöver, Overview on Advanced Thermal Barrier Coatings, Surf. Coat. Technol., 2010, 205, p 938-942
A. Kulkarni, A. Vaidya, A. Goland, S. Sampath, and H. Herman, Processing Effects on Porosity-Property Correlations in Plasma Sprayed Yttria-Stabilized Zirconia Coatings, Mater. Sci. Eng. A, 2003, 359, p 100-111
A. Feuerstein, J. Knapp, T. Taylor, A. Ashary, A. Bolcavage, and N. Hitchmann, Technical and Economical Aspects of Current Thermal Barrier Coating Systems for Gas Turbine Engines by Thermal Spray and EBPVD: A Review, J. Therm. Spray Technol., 2008, 17, p 199-213
R. Vaßen, A. Stuke, and D. Stöver, Recent Developments in the Field of Thermal Barrier Coatings, J. Therm. Spray Technol., 2009, 18, p 181-186
G. Mauer, R. Vaßen, and D. Stöver, Atmospheric Plasma Spraying of Yttria-Stabilized Zirconia Coatings with Specific Porosity, Surf. Coat. Technol., 2009, 204, p 172-179
M. Karger, R. Vaßen, and D. Stöver, Atmospheric Plasma Sprayed Thermal Barrier Coatings with High Segmentation Crack Densities: Spraying Process, Microstructure and Thermal Cycling Behavior, Surf. Coat. Technol., 2011, 206, p 16-23
U. Schulz, Phase Transformation in EB-PVD Yttria Partially Stabilized Zirconia Thermal Barrier Coatings During Annealing, J. Am. Ceram. Soc., 2000, 83(4), p 904-910
A. Cipitria, I.O. Golosnoy, and T.W. Clyne, A Sintering Model for Plasma-Sprayed Zirconia TBCs. Part I: Free-Standing Coatings, Acta Mater., 2009, 57(4), p 980-992
R. Vassen, X. Cao, F. Tietz, D. Basu, and D. Stöver, Zirconates as New Materials for Thermal Barrier Coatings, J. Am. Ceram. Soc., 2000, 83(8), p 2023-2028
H. Lehmann, D. Pitzer, G. Pracht, R. Vaßen, and D. Stöver, Thermal Conductivity and Thermal Expansion Coefficients of the Lanthanum Rare-Earth-Element Zirconate System, J. Am. Ceram. Soc., 2004, 86(8), p 1338-1344
R. Vaßen, F. Traeger, and D. Stöver, New Thermal Barrier Coatings Based on Pyrochlore/YSZ Double-Layer Systems, Int. J. Appl. Ceram. Technol., 2004, 1(4), p 351-361
X.Q. Cao, R. Vaßen, F. Tietz, and D. Stöver, New Double-Ceramic-Layer Thermal Barrier Coatings Based on Zirconia-Rare Earth Composite Oxides, J. Eur. Ceram. Soc., 2006, 26, p 247-251
R. Vaßen, H. Kaßner, G. Mauer, and D. Stöver, Suspension Plasma Spraying: Process Characterization and Applications, J. Therm. Spray Technol., 2010, 19(1-2), p 219-225
A. Hospach, G. Mauer, R. Vaßen, and D. Stöver, Columnar Structured Thermal Barrier Coatings (TBCs) by Thin Film Low Pressure Plasma Spraying (LPPS-TF), J. Therm. Spray Technol., 2011, 20(1-2), p 116-120
B. Rajasekaran, G. Mauer, and R. Vaßen, Enhanced Characteristics of HVOF Sprayed MCrAlY Bond Coats for TBC Applications, J. Therm. Spray Technol., 2012, 20(6), p 1209-1216
A.V. Radha, S.V. Ushakov, and A. Navrotsky, Thermochemistry of Lanthanum Zirconate Pyrochlore, J. Mater. Res., 2009, 24(11), p 3350-3357
R. Vaßen, Entwicklung neuer oxidischer Wärmedämmschichten für Anwendungen in stationären und Flug-Gasturbinen, Schriften des Forschungszentrums Jülich, Energy Technology, vol 33, Forschungszentrum Jülich, Jülich, 2004 (in German)
H. Chen, Y. Gaoa, Y. Liua, and H. Luo, Coprecipitation Synthesis and Thermal Conductivity of La2Zr2O7, J. Alloy. Compd., 2009, 480, p 843-848
X.Q. Cao, R. Vaßen, W. Jungen, S. Schwartz, F. Tietz, and D. Stöver, Thermal Stability of Lanthanum Zirconate Plasma-Sprayed Coating, J. Am. Ceram. Soc., 2001, 84(9), p 2086-2090
H. Chen, Y. Gao, S. Tao, Y. Liu, and H. Luo, Thermophysical Properties of Lanthanum Zirconate Coating Prepared by Plasma Spraying and the Influence of Post Annealing, J. Alloy. Compd., 2009, 486, p 391-399
Z. Xu, L. He, R. Mu, S. He, and X. Cao, Preparation and Characterization of La2Zr2O7 Coating with the Addition of Y2O3 by EB-PVD, J. Alloy. Compd., 2010, 492, p 701-705
J.L. Margrave, Ed., The Characterization of High Temperature Vapors, Wiley, New York, 1967
G. Mauer, D. Sebold, R. Vaßen, and D. Stöver, Improving Atmospheric Plasma Spraying of Zirconate Thermal Barrier Coatings Based on Particle Diagnostics, J. Therm. Spray Technol., 2012, 21(3-4), p 363-371
G. Mauer, R. Vaßen, and D. Stöver, Comparison and Applications of DPV-2000 and Accuraspray-g3 Diagnostic Systems, J. Therm. Spray Technol., 2007, 16(3), p 414-424
W. Braue and P. Mechnich, Recession of an EB-PVD YSZ Coated Turbine Blade by CaSO4 and Fe, Ti-Rich CMAS-Type Deposits, J. Am. Ceram. Soc., 2011, 94(12), p 4483-4489
J.M. Drexler, A.D. Gledhill, K. Shinoda, A.L. Vasiliev, K.M. Reddy, S. Sampath, and N.P. Padture, Jet Engine Coatings for Resisting Volcanic Ash Damage, Adv. Mater., 2011, 23, p 2419-2424
A.D. Gledhill, K.M. Reddy, J.M. Drexler, K. Shinoda, S. Sampath, and N.P. Padture, Mitigation of Damage from Molten Fly Ash to Air-Plasma-Sprayed Thermal Barrier Coatings, Mater. Sci. Eng. A, 2011, 528, p 7214-7221
M.O. Jarligo, D.E. Mack, and R. Vaßen, Gd2Zr2O7-YSZ Composites for High Temperature Corrosion Resistant Thermal Barrier Coatings, Abstracts from the 36th International Conference and Exposition on Advanced Ceramics and Composites, January 22-27, 2012 (Daytona Beach, FL, USA), 2012
B. Heimberg, W. Beele, K. Kempter, U. Bast, T. Haubold, M. Hoffmann, A. Endriss, P. Greil, C. Hong, F. Alding, and H. Seifert, “Process for Producing a Ceramic Thermal Barrier Layer for Gas Turbine Engine Component,” U.S. Patent 06602553 B2, 2003
A.S. Bhalla, R. Guo, and R. Roy, The Perovskite Structure—A Review of Its Role in Ceramic Science and Technology, Mater. Res. Innov., 2000, 4, p 3-26
R. Guo, A.S. Bhalla, and L.E. Cross, Ba(Mg1/3Ta2/3)O3 Single Crystal Fiber Grown by the Laser Heated Pedestal Growth Technique, J. Appl. Phys., 1994, 75, p 4704-4708
W. Ma, M.O. Jarligo, D.E. Mack, D. Pitzer, J. Malzbender, R. Vaßen, and D. Stöver, New Generation Perovskite Thermal Barrier Coating Materials, J. Therm. Spray Technol., 2008, 17(5-6), p 831-837
M.O. Jarligo, D.E. Mack, R. Vaßen, and D. Stöver, Application of Plasma Sprayed Complex Perovskites as Thermal Barrier Coatings, J. Therm. Spray Technol., 2009, 18, p 187-193
A. Ansar, G. Schiller, O. Patz, J.B. Gregoire, and Z. Ilhan, Plasma Sprayed Oxygen Electrode for Solid Oxide Fuel Cells and High Temperature Electrolyzers, Thermal Spray 2008: Crossing Borders, on CD-ROM, E. Lugscheider, Ed., June 2-4, 2008 (Maastricht, The Netherlands), DVS Media, Düsseldorf, Germany, 2008
G. Schiller, M. Müller, and F. Gitzhofer, Preparation of Perovskite Powders and Coatings by Radio Frequency Suspension Plasma Spraying, J. Therm. Spray Technol., 1999, 8, p 389-392
C. Zhang, W.-Y. Li, H. Liao, C.-J. Li, C.-X. Li, and C. Coddet, Microstructure and Electrical Conductivity of Atmospheric Plasma-Sprayed LSM/YSZ Composite Cathode Materials, J. Therm. Spray Technol., 2007, 16, p 1005-1010
M.O. Jarligo, D.E. Mack, G. Mauer, R. Vaßen, and D. Stöver, Atmospheric Plasma Spraying of High Melting Temperature Complex Perovskites for TBC Application, J. Therm. Spray Technol., 2010, 19(1-2), p 303-310
G.V. Samsonov, Ed., The Oxide Handbook, 2nd ed., IFI/Plenum, New York, 1986
M.O. Jarligo, G. Mauer, D. Sebold, D.E. Mack, R. Vaßen, and D. Stöver, Decomposition of Ba(Mg1/3Ta2/3)O3 Perovskite During Atmospheric Plasma Spraying, Surf. Coat. Technol., 2012, 206(8-9), p 2515-2520
G. Mauer, M.O. Jarligo, D.E. Mack, R. Vaßen, and D. Stöver, Development of Plasma Spray Parameters for Ceramic Coatings in Gas Turbines, Proceedings of the 24th International Conference on Surface Modification Technologies (SMT 24), T.S. Sudarshan, E. Beyer, and L.M. Berger, Ed., September 7-9, 2010 (Dresden), Valardocs, Chennai, India, 2011, p 35-46
W. Ma, D.E. Mack, R. Vaßen, and D. Stöver, Perovskite-Type Strontium Zirconate as a New Material for Thermal Barrier Coatings, J. Am. Ceram. Soc., 2008, 91(8), p 2630-2635
Y. Zhang, D.E. Mack, M.O. Jarligo, X. Cao, R. Vaßen, and D. Stöver, Partial Evaporation of Strontium Zirconate During Atmospheric Plasma Spraying, J. Therm. Spray Technol., 2009, 18(4), p 694-701
C. Friedrich, R. Gadow, and T. Schirmer, Lanthanum Hexaaluminate—A New Material for Atmospheric Plasma Spraying of Advanced Thermal Barrier Coatings, J. Therm. Spray Technol., 2001, 10(4), p 592-598
C.M. Weyant and K.T. Faber, Processing-Microstructure Relationships for Plasma-Sprayed Yttrium Aluminum Garnet, Surf. Coat. Technol., 2008, 202(24), p 6081-6089
G. Pracht, R. Vaßen, and D. Stöver, Lanthanum-Lithium Hexaaluminate—A New Material for Thermal Barrier Coatings in Magnetoplumbite Structure—Material and Process Development, Ceram. Eng. Sci. Proc., 2008, 27(3), p 87-99
A. Doncieux, D. Stagnol, M. Huger, T. Chotard, C. Gault, T. Ota, and S. Hashimoto, Thermo-Elastic Behaviour of a Natural Quartzite: Itacolumite, J. Mater. Sci., 2008, 43(12), p 4167-4174
T.A. Schaedler, R.M. Leckie, S. Krämer, A.G. Evans, and C.G. Levi, Toughening of Non-transformable t′-YSZ by Addition of Titania, J. Am. Ceram. Soc., 2007, 90, p 3896-3901
M.O. Jarligo, G. Mauer, D.E. Mack, R. Vaßen, and D. Stöver, The Influence of Titania Doping on Plasma-Sprayed YSZ Thermal Barrier Coatings Proceedings of the 25th International Conference on Surface Modification Technologies (SMT 25), T.S. Sudarshan and P. Nylén, Ed., June 20-22, 2011 (Trollhättan, Sweden), Valardocs, 2012, p 165-173
T.A. Schaedler, O. Fabrichnaya, and C.G. Levi, Phase Equilibria in the TiO2-YO1.5-ZrO2 System, J. Eur. Ceram. Soc., 2008, 28, p 2509-2520
M.O. Jarligo, G. Mauer, D.E. Mack, R. Vaßen, and D. Stöver, Advanced Thermal Barrier Coatings from Ti-Doped YSZ Systems, International Thermal Spray Conference 2011, Sep 27-29, 2011 (Hamburg, Germany), DVS-Berichte 276, DVS Media, Düsseldorf, Germany, 2011
D. Zhu and R.A. Miller, Development of Advanced Low Conductivity Thermal Barrier Coatings, Int. J. Appl. Ceram. Technol., 2004, 1(1), p 86-94
M.O. Jarligo, D.E. Mack, and R. Vaßen, Ti,Yb-Doped YSZ Systems for Advanced Thermal Barrier Coating Applications, 10th CMCEE—International Symposium on Ceramic Materials and Components for Energy and Environmental Applications, May 20-23, 2012 (Dresden, Germany), 2012
Acknowledgments
The authors are grateful to Dr. Jürgen Malzbender (IEK-2), Mr. Mirko Ziegner (IEK-2), Mrs. Hannelore Lippert (ZCH), and the colleagues of IEK-1 in Forschungszentrum Jülich GmbH for their help in carrying out the experiments which results are reported in this article.
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Mauer, G., Jarligo, M.O., Mack, D.E. et al. Plasma-Sprayed Thermal Barrier Coatings: New Materials, Processing Issues, and Solutions. J Therm Spray Tech 22, 646–658 (2013). https://doi.org/10.1007/s11666-013-9889-8
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DOI: https://doi.org/10.1007/s11666-013-9889-8