Abstract
A higher Co content in Ni-Co coatings leads to better corrosion resistance to a certain degree. In this paper, centrifugal acceleration was introduced in the electrodeposition of Ni-Co coatings in order to obtain improved Ni-Co coatings with high Co content. With different centrifugal accelerations, the Co content, morphology, preferred coating orientation, microhardness, and wear and corrosion resistance were examined. Under large centrifugal acceleration, a maximal Co content of 38.25% was obtained according to the EDS results, which was higher than that obtained using normal electrodeposition. The SEM images indicated that the morphology of the prepared Ni-Co coatings with the highest Co content was smoothened. In addition, the microhardness of Ni-Co coatings with increased Co content was improved to about 530HV, which was hardly achieved under normal electrodeposition. Most of all, based on the polarization curve and EIS results, the corrosion resistance was significantly enhanced as the Co content reached the maximum. In general, corrosion resistance of the deposited Ni-Co coatings can be improved with large centrifugal acceleration.
Similar content being viewed by others
References
X.W. Zhou and Y.F. Shen, Beneficial Effects of CeO2 Addition on Microstructure and Corrosion Behavior of Electrodeposited Ni Nanocrystalline Coatings, Surf. Coat. Technol., 2013, 235, p 433–446
K.M. Sivaraman, O. Ergeneman, S. Pané, E. Pellicer, J. Sort, K. Shou, S. Suriñach, M.D. Baró, and B.J. Nelson, Electrodeposition of Cobalt-Yttrium Hydroxide/Oxide Nanocomposite Films from Particle-Free Aqueous Baths Containing Chloride Salts, Electrochim. Acta, 2011, 56, p 5142–5150
W. Shao, D. Nabb, N. Renevier, I. Sherrington, Y. Fu, and J. Luo, Mechanical and Anti-corrosion Properties of TiO2 Nanoparticle Reinforced Ni Coating by Electrodeposition, J. Electrochem. Soc., 2012, 159, p D671–D676
C.N. Tharamani, F.S. Hoor, N.S. Begum, and S.M. Mayanna, Microstructure, Surface and Electrochemical Studies of Electroless Cr-P Coatings Tailored for the Methanol Oxidative Fuel Cell, J. Solid State Electrochem., 2005, 9, p 476–482
Z. Zeng, L. Wang, A. Liang, and J. Zhang, Tribological and Electrochemical Behavior of thick Cr-C Alloy Coatings Electrodeposited in Trivalent Chromium Bath as an Alternative to Conventional Cr Coatings, Electrochim. Acta, 2006, 52, p 1366–1373
L. Benea, Electrochemical Impedance Spectroscopy and Corrosion Behavior of Co/CeO2 Nanocomposite Coatings in Simulating Body Fluid Solution, Metall. Mater. Trans. A, 2013, 44, p 1114–1122
S. Bindiya, S. Basavanna, and Y.A. Naik, Electrodeposition and Corrosion Properties of Zn-V2O5 Composite Coatings, J. Mater. Eng. Perform., 2012, 21, p 1879–1884
N.S. Qu, W.H. Qian, X.Y. Hu, and Z.W. Zhu, Fabrication of Ni-CeO2 Nanocomposite Coatings Synthesised via a Modified Sediment Co-Deposition Process, Int. J. Electrochem. Sci., 2013, 8, p 11564–11577
A. Bigos, E. Beltowska-Lehman, E. García-Lecina, M. Bieda, M.J. Szczerba, and J. Morgiel, Ultrasound-Assisted Electrodeposition of Ni and Ni-Mo Coatings from a Citrate-Ammonia Electrolyte Solution, J. Alloys Compd., 2017, 726, p 410–416
J.R. Lopez, G. Stremsdoerfer, G. Trejo, R. Ortega, J.J. Perez, and Y. Meas, Corrosion Resistance of Nickel Coatings Obtained by Electrodeposition in a Sulfamate Bath in the Presence of Samarium (III), Int. J. Electrochem. Sci., 2012, 7, p 12244–12253
H. Zhao, L. Liu, J. Zhu, Y. Tang, and W. Hu, Microstructure and Corrosion Behavior of Electrodeposited Nickel Prepared from a Sulphamate Bath, Mater. Lett., 2007, 61, p 1605–1608
Z.J. Tian, D.S. Wang, G.F. Wang, L.D. Shen, Z.D. Liu, and Y.H. Huang, Microstructure and Properties of Nanocrystalline Nickel Coatings Prepared by Pulse Jet Electrodeposition, Trans. Nonferr. Met. Soc., 2010, 20, p 1037–1042
B. Bakhit and A. Akbari, A Comparative Study of the Effects of Saccharin and β-SiC Nano-Particles on the Properties of Ni and Ni-Co Alloy coatings, Surf. Coat. Technol., 2014, 253, p 76–82
L. Wang, Y. Gao, Q. Xue, H. Liu, and T. Xu, Microstructure and Tribological Properties of Electrodeposited Ni-Co Alloy Deposits, Appl. Surf. Sci., 2005, 242, p 326–332
M. Srivastava, V.E. Selvi, V.W. Grips, and K.S. Rajam, Corrosion Resistance and Microstructure of Electrodeposited Nickel-Cobalt Alloy Coatings, Surf. Coat. Technol., 2006, 201, p 3051–3060
B. Bakhit and A. Akbari, Nanocrystalline Ni-Co Alloy Coatings: Electrodeposition Using Horizontal Electrodes and Corrosion Resistance, J. Coat. Technol. Res., 2013, 10, p 285–295
G.Y. Qiao, T.F. Jing, N. Wang, Y.W. Gao, X. Zhao, J.F. Zhou, and W. Wang, High-Speed Jet Electrodeposition and Microstructure of Nanocrystalline Ni-Co Alloys, Electrochim. Acta, 2005, 51, p 85–92
D. Golodnitsky, R. Yu, and A. Ulus, The Role of Anion Additives in the Electrodeposition of Nickel-Cobalt Alloys from Sulfamate Electrolyte, Electrochim. Acta., 2003, 47, p 2707–2714
B. Löchel, A. Maciossek, H.J. Quenzer, B. Wagner, and G. Engelmann, Magnetically Driven Microstructures Fabricated with Multilayer Electroplating, Sens. Actuators A Phys., 1995, 46, p 98–103
A.R. Shetty and A.C. Hegde, Ultrasound Induced Multilayer Ni-Co Alloy Coatings for Better Corrosion Protection, Surf. Coat. Technol., 2017, 322, p 99–107
B. Bakhita, A. Akbaria, F. Nasirpouria, and M.G. Hosseini, Corrosion Resistance of Ni-Co Alloy and Ni-Co/SiC Nanocomposite Coatings Electrodeposited by Sediment Codeposition Technique, Appl. Surf. Sci., 2014, 307, p 351–359
A.C. Lokhande and J.S. Bagi, Studies on Enhancement of Surface Mechanical Properties of Electrodeposited Ni-Co Alloy Coatings Due to Saccharin Additive, Surf. Coat. Technol., 2014, 258, p 225–231
C. Liu, F. Su, and J. Liang, Nanocrystalline Co-Ni Alloy Coating Produced with Supercritical Carbon Dioxide Assisted Electrodeposition with Excellent Wear and Corrosion Resistance, Surf. Coat. Technol., 2016, 292, p 37–43
Z.C. Guo, Y.P. Gong, and W.C. Lu, Electrochemical Studies of Nickel Deposition from Aqueous Solution in Supergravity Field, Sci. China Ser. E Technol. Sci., 2007, 50, p 39–50
T. Liu, Z.C. Guo, Z. Wang, and M.Y. Wang, Effects of Gravity on the Electrodeposition and Characterization of Nickel Foils, Int. J. Min. Met. Mater., 2011, 18, p 59–65
T. Liu, Z. Guo, Z. Wang, and M. Wang, Structure and Corrosion Resistance of Nickel Foils Deposited in a Vertical Gravity Field, Appl. Surf. Sci., 2010, 25, p 6634–6640
M. Wang, Z. Wang, and Z. Guo, Electrodeposited Free-Crack NiW Films Under Super Gravity Filed: Structure and Excellent Corrosion Property, Mater. Chem. Phys., 2014, 148, p 245–252
M.Y. Wang, Z. Wang, and Z.C. Guo, Understanding of the Intensified Effect of Super Gravity on Hydrogen Evolution Reaction, Int. J. Hydrogen Energy, 2009, 34, p 5311–5317
G. Marshall, E. Mocskos, G. González, S. Dengra, F.V. Molina, and C. Iemmi, Stable, Quasi-Stable and Unstable Physicochemical Hydrodynamic Flows in Thin-Layer Cell Electrodeposition, Electrochim. Acta, 2006, 51, p 3058–3065
H. Cheng and K. Scott, An Empirical Model Approach to Gas Evolution Reactions in a Centrifugal Field, J. Electroanal. Chem., 2003, 544, p 75–85
M. Srivastava, V.K. William Grips, and K.S. Rajam, Electrodeposition of Ni-Co Composites Containing Nano-CeO2 and Their Structure, Properties, Appl. Surf. Sci., 2010, 257, p 717–722
J.S. Chen, Research on Direct Preparation of Porous Foam Nickle by Jet Electrodeposition, Doctoral Dissertation, Nanjing University of Aeronautics and Astronautics, 2009
J.A. Mac Geough, M.C. Leu, K.P. Rajurkar, A.K.M. De Silva, and Q. Liu, Electroforming Process and Application to Micro/Macro Manufacturing, Ann. CIRP, 2001, 50, p 499–514
S.M. Silaimani and S. John, Review on Recent Advances in Electroforming During the Last Decade, Bull. Electrochem., 2001, 17, p 553–560
Y. Li, H. Jiang, L. Pang, B. Wang, and X. Liang, Novel Application of Nanocrystalline Nickel Electrodeposit: Making Good Diamond Tools Easily, Efficiently and Economically, Surf. Coat. Technol., 2007, 201, p 5925–5930
C. Ma, S.C. Wang, R.J.K. Wood, J. Zekonyte, Q. Luo, and F.C. Walsh, Hardness of Porous Nanocrystalline Co-Ni Electrodeposits, Met. Mater. Int., 2013, 19, p 1187–1192
M. Zamani, A. Amadeh, and S.M.L. Baghal, Effect of Co Content on Electrodeposition Mechanism and Mechanical Properties of Electrodeposited Ni-Co Alloy, Trans. Nonferr. Met. Soc., 2016, 26, p 484–491
D.M. Dryden, T. Sun, R. Mccormick, R. Hickey, R. Vidu, and P. Stroeve, Anomalous Deposition of Co-Ni Alloys in Film and Nanowire Morphologies from Citrate Baths, Electrochim. Acta, 2016, 220, p 595–600
M. Sato and R. Aogaki, Gravity Effect on Copper Corrosion, Mater. Sci. Forum, 1998, 289-292, p 459–464
M. Sato, A. Yamada, and R. Aogaki, Electrochemical Reaction in a High Gravity Field Vertical to an Electrode Surface-Analysis of Diffusion Process with a Gravity Electrode, Jpn. J. Appl. Phys., 2003, 42, p 4230–4238
J.S. Chen, Y.H. Huang, and Z.D. Liu, Jet Electrodeposition Oriented by Rapid Prototyping, Trans. Nonferr. Met. Soc. China, 2005, 15, p 247–250
J.W. Dini, Electrodeposition: The Materials Science of Coatings and Substrates, Noyes, Park Ridge, 1993
J.Y. Li, C. Ni, J.Y. Liu, M.J. Jin, W. Li, and X.J. Jin, Extraordinary Stability of Nano-twinned Structure Formed During Phase Transformation Coupled with Grain Growth in Electrodeposited Co-Ni Alloys, Mater. Chem. Phys., 2014, 148, p 1202–1211
L.W. Wang, Z.Y. Liu, Z.Y. Cui, C.W. Du, X.H. Wang, and X.G. Li, In Situ Corrosion Characterization of Simulated Weld Heat Affected Zone on API, X80 Pipeline Steel, Corros. Sci., 2014, 85, p 401–410
Z.J. Zheng, Y. Gao, Y. Gui, and M. Zhu, Corrosion Behaviour of Nanocrystalline 304 Stainless Steel Prepared by Equal Channel Angular Pressing, Corros. Sci., 2012, 54, p 60–67
S.H. Hassani, K. Raeissi, M. Azzi, D. Li, M.A. Golozar, and J.A. Szpunar, Improving the Corrosion and Tribocorrosion Resistance of Ni-Co Nanocrystalline Coatings in NaOH Solution, Corros. Sci., 2009, 51, p 2371–2379
M. Srivastava, V.E. Selvi, V.K.W. Grips, and K.S. Rajam, Corrosion Resistance and Microstructure of Electrodeposited Nickel-Cobalt Alloy Coating, Surf. Coat. Technol., 2006, 201, p 3051–3060
Acknowledgments
The work described in this paper was supported by the Fundamental Research Funds Program and the Central Universities (NZ2016106) of the National Basic Research Program of China (973 Program, Grant 2015CB057502).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Hu, X., Qu, N. Improved Corrosion Resistance of Ni-Co Coatings Prepared by Electrodeposition with Large Centrifugal Acceleration. J. of Materi Eng and Perform 28, 2104–2114 (2019). https://doi.org/10.1007/s11665-019-03946-y
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11665-019-03946-y