Abstract
Factors such as inhibitor concentration, solution hydrodynamics, and temperature influence the performance of corrosion inhibitor mixtures. The simultaneous studying of the impact of different factors is a time- and cost-consuming process. The use of experimental design methods can be useful in minimizing the number of experiments and finding local optimized conditions for factors under the investigation. In the present work, the inhibition performance of a three-component inhibitor mixture against corrosion of St37 steel rotating disk electrode, RDE, was studied. The mixture was composed of citric acid, lanthanum(III) nitrate, and tetrabutylammonium perchlorate. In order to decrease the number of experiments, the L16 Taguchi orthogonal array was used. The “control factors” were the concentration of each component and the rotation rate of RDE and the “response factor” was the inhibition efficiency. The scanning electron microscopy and energy dispersive x-ray spectroscopy techniques verified the formation of islands of adsorbed citrate complexes with lanthanum ions and insoluble lanthanum(III) hydroxide. From the Taguchi analysis results the mixture of 0.50 mM lanthanum(III) nitrate, 0.50 mM citric acid, and 2.0 mM tetrabutylammonium perchlorate under the electrode rotation rate of 1000 rpm was found as optimum conditions.
Similar content being viewed by others
References
F.R. Murillo, A.A. Alonso, and R.T. Sanchez, Improving the Corrosion Resistance of a Cooling Water System at an Ammonium Sulfate Crystallization Plant by Corrosion Inhibitors, Mater. Corros., 2002, 53, p 820–826
B.V.A. Rao, M.V. Rao, S.S. Rao, and B. Sreedhar, Synergistic Effect of N,N-Bis(phosphonomethyl) Glycine and Zinc Ions in Corrosion Control of Carbon Steel in Cooling Water Systems, Chem. Eng. Commun., 2011, 198, p 1505–1529
O. Olivares, N.V. Likhanova, B. Gómez, J. Navarrete, M.E. Llanos-Serrano, E. Arce et al., Electrochemical and XPS Studies of Decylamides of α-Amino Acids Adsorption on Carbon Steel in Acidic Environment, Appl. Surf. Sci., 2006, 252, p 2894–2909. doi:10.1016/j.apsusc.2005.04.040
P.B. Raja and M.G. Sethuraman, Natural Products as Corrosion Inhibitor for Metals in Corrosive Media—A Review, Mater. Lett., 2008, 62, p 113–116. doi:10.1016/j.matlet.2007.04.079
A.J.S. John, B. Joseph, and K.K. Aravindakshan, Inhibition of Mild Steel Corrosion in 1M Hydrochloric Acid by 4-(N,N-Dimethylaminobenzilidine)-3-mercapto-6-methyl- 1,2,4-triazin(4H)-5-one (DAMMT), Mater. Chem. Phys., 2010, 122, p 374–379
D.E. Abd-El-Khalek and B.A. Abd-El-Nabey, Evaluation of Sodium Hexametaphosphate as Scale and Corrosion Inhibitor in Cooling Water Using Electrochemical Techniques, Desalination., 2013, 311, p 227–233
J. Mar´ın-Cruz, R. Cabrera-Sierra, M.A. Pech-Canul, and I. Gonz´alez, EIS Study on Corrosion and Scale Processes and Their Inhibition in Cooling System Media, Electrochim. Acta., 2006, 51, p. 1847–1854.
R. Touir, N. Dkhireche, M.E. Touhami, M. Lakhrissi, B. Lakhrissi, and M. Sfaira, Corrosion and Scale Processes and Their Inhibition in Simulated Cooling Water Systems by Monosaccharides Derivatives Part I: EIS Study, Desalination., 2009, 249, p 922–928
A.K. Mishra and R. Balasubramaniam, Corrosion Inhibition of Aluminum Alloy AA, by Rare Earth Chlorides, Corros. Sci., 2014, 49(2007), p 1027–1044
A. Aballe, M. Bethencourt, F.J. Botana, and M. Marcos, CeCl3 and LaCl3 Binary Solutions as Environment-Friendly Corrosion Inhibitors of AA5083 Al–Mg Alloy in NaCl Solutions, J. Alloys Compd., 2001, 323–324, p 855–858
S.S. Viswanathan, A Review on Recent Patents in Corrosion Inhibitors, Recent Pat. Corros. Sci., 2010, 2, p 6–12
Z. Yanhua, Z. Jia, Y. Yongsheng, and Z. Xianguang, Research on Anti-corrosion Property of Rare Earth Inhibitor for X70 Steel, J. Rare Earths, 2013, 31, p 734–740
T.H. Muster, H. Sullivan, D. Lau, D.L.J. Alexander, N. Sherman, S.J. Garcia et al., A Combinatorial Matrix of Rare Earth Chloride Mixtures as Corrosion Inhibitors of AA2024-T3: Optimisation Using Potentiodynamic Polarisation and EIS, Electrochim. Acta., 2012, 67, p 95–103
F. Liu, X. Lu, W. Yang, J. Lu, H. Zhong, X. Chang et al., Optimizations of Inhibitors Compounding and Applied Conditions in Simulated Circulating Cooling Water System, Desalination., 2013, 313, p 18–27
K.-H. Goh, T.-T. Lim, and P.-C. Chui, Evaluation of the Effect of Dosage, pH and Contact Time on High-Dose Phosphate Inhibition for Copper Corrosion Control Using Response Surface Methodology (RSM), Corros. Sci., 2008, 50, p 918–927
S. Subhashini and A.A.F. Sabirneeza, Study of Synergistic Influence of l-Cysteine on Polyvinyl Alcohol–Taguchi Method: Continuous Electrochemical Monitoring of Corrosion Inhibition of Mild Steel by Poly(vinyl alcohol-cysteine), J. Adhes. Sci. Technol., 2015, 29, p 1268–1294
H. Ashassi-Sorkhabi, E. Asghari, and M. Mohammadi, Effects of Solution Hydrodynamics on Corrosion Inhibition of Steel by Citric Acid in Cooling Water, J. Mater. Eng. Perform., 2014, 23, p 2992–3000
M. Moradi, Z. Song, L. Yang, J. Jiang, and J. He, Effect of Marine Pseudoalteromonas sp. on the Microstructure and Corrosion Behaviour of 2205 Duplex Stainless Steel, Corros. Sci., 2014, 84, p 103–112
H. Ashassi-Sorkhabi and E. Asghari, Electrochemical Corrosion Behavior of Al7075 Rotating Disc Electrode in Neutral Solution Containing l-Glutamine as a Green Inhibitor, J. Appl. Electrochem., 2010, 40, p 631–637
R. Baboian, Ed., Corrosion Tests and Standards, Application and Interpretation, 2nd ed, ASTM International, West Conshohocken, 1995.
W.S. Tait, An Introduction to Electrochemical Corrosion Testing for Practicing Engineers and Scientists, ParisODocs Publication, Racine, 1994
Microsoft, Minitab 16.2.4, (2013).
Y. Takada, N. Takahashi, and O. Okuno, Corrosion Characteristics of Magnetic Assemblies Composing Dental Magnetic Attachments, Proceedings of 2nd International Symposium for Interface Oral Health Science, M.W.K. Sasaki, O. Suzuki, O. Okuno, N. Takahashi, Eds., Springer, Sendai, 2007, p 343–344.
M. Bethencourt, F.J. Botana, J.J. Calvino, M. Marcos, and M.A. Rodriguez-Chacon, Lanthanide Compounds as Environmentally-Friendly Corrosion Inhibitors of Aluminum Alloys—A Review, Corros. Sci., 1998, 40, p 1803–1819
Acknowledgment
The authors would like to thank the University of Tabriz for financial supports of this project.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Asghari, E., Ashassi-Sorkhabi, H., Ahangari, M. et al. Optimization of a Three-Component Green Corrosion Inhibitor Mixture for Using in Cooling Water by Experimental Design. J. of Materi Eng and Perform 25, 1416–1425 (2016). https://doi.org/10.1007/s11665-015-1865-7
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11665-015-1865-7