Abstract
During the reflow process of Sn-8Zn-20In solder joints in the ball grid array (BGA) packages with Au/Ni/Cu and Ag/Cu pads, the Au and Ag thin films react with liquid solder to form γ3-AuZn4/γ-Au7Zn18 and ε-AgZn6 intermetallics, respectively. The γ3/γ intermetallic layer is prone to floating away from the solder/Ni interface, and the appearance of any interfacial intermetallics cannot be observed in the Au/Ni surface finished Sn-8Zn-20In packages during further aging treatments at 75°C and 115°C. In contrast, ε-CuZn5/γ-Cu5Zn8 intermetallics are formed at the aged Sn-8Zn-20In/Cu interface of the immersion Ag BGA packages. Bonding strengths of 3.8N and 4.0N are found in the reflowed Sn-8Zn-20In solder joints with Au/Ni/Cu and Ag/Cu pads, respectively. Aging at 75°C and 115°C gives slight increases of ball shear strength for both cases.
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References
H.J. Lau, C.P. Wong, N.C. Lee, and S.W. Ricky Lee, Electronics Manufacturing with Lead-Free, Halogen-Free & Conductive-Adhesive Materials (New York: McGraw-Hill Handbooks, 2003), pp. 14.1–14.36.
K. Zeng and K.N. Tu, Mater Sci. Eng. R38, 55 (2002).
M. McCormack, S. Jin, and H.S. Chen, J. Electron. Mater. 23, 687 (1994).
M. McCormack and S. Jin, J. Electron. Mater. 23, 635 (1994).
Y. Cui, X.J. Liu, I. Ohnuma, R. Kainuma, H. Ohtani, and K. Ishida, J. Alloys Compounds 320, 234 (2001).
S.W. Yoon, J.R. Son, H.M. Lee, and B.J. Lee, Acta Mater. 45, 951 (1997).
Y.C. Chan, M.Y. Chiu, and T.H. Chuang, Z. Metallkd. 93, 95 (2002).
R.K. Shiue, L.W. Tsay, C.L. Lin, and J.L. Ou, Microelectron. Reliab. 43, 453 (2003).
H.J. Lin and T.H. Chuang, J. Electron. Mater. 35, 154 (2006).
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Liu, YC., Lin, WH., Lin, HJ. et al. Intermetallic reactions in Sn-8Zn-20In solder ball grid array packages with Au/Ni/Cu and Ag/Cu pads. J. Electron. Mater. 35, 147–153 (2006). https://doi.org/10.1007/s11664-006-0197-7
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DOI: https://doi.org/10.1007/s11664-006-0197-7