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Reconsideration of Viscosity Variation Mechanism in Calcium Ferrite Melt During Isothermal Melting Process

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Abstract

Two hypotheses exist to explain the viscosity decrease mechanism of calcium ferrite (CF) melts during isothermal melting in air: variations in either the short-range structure near Fe3+ or the Fe redox state. Here, the synchrotron X-ray total scattering pattern of an aerodynamically levitated CF droplet was monitored during isothermal melting. No variations were observed in the short-range structure of the melt for 1800 seconds, indirectly suggesting that redox state variations dominate the viscosity.

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Acknowledgments

This experiment was carried out at the BL04B2 beamline at SPring-8 with the approval of JASRI (Proposal No. 2017B1400). This work was performed under the “Dynamic Alliance for Open Innovation Bridging Human, Environment and Materials” from the Ministry of Education, Culture, Sports, Science and Technology of Japan (MEXT). This work was partially supported by JSPS KAKENHI (Grant Number 19K05106). S.S. would like to thank Dr. Daniel R. Neuville (Institut de Physique du Globe de Paris) for fruitful discussions on the viscosity variation of the CF melt.

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Authors and Affiliations

  1. Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, 9808577, Japan

    Sohei Sukenaga & Hiroyuki Shibata

  2. Japan Synchrotron Radiation Research Institute, (SPring-8/JASRI), 1-1-1 Kouto, Sayo, Hyogo, 6795198, Japan

    Koji Ohara & Hiroki Yamada

  3. Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi 2-11-16, Bunkyo-ku, Tokyo, 1138656, Japan

    Toru Wakihara

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  1. Sohei Sukenaga
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  2. Koji Ohara
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Correspondence to Sohei Sukenaga.

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Manuscript submitted on March 11, 2021; accepted May 14, 2021.

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Sukenaga, S., Ohara, K., Yamada, H. et al. Reconsideration of Viscosity Variation Mechanism in Calcium Ferrite Melt During Isothermal Melting Process. Metall Mater Trans B 52, 1945–1949 (2021). https://doi.org/10.1007/s11663-021-02227-1

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  • DOI: https://doi.org/10.1007/s11663-021-02227-1

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