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Modeling the Viscosity of Silicate Melts Containing Lead Oxide

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Abstract

Our recently developed model for the viscosity of silicate melts is applied to describe and predict the viscosities of oxide melts containing lead oxide. The model requires three pairs of adjustable parameters that are fitted to the experimental viscosities in the following systems: pure PbO, PbO-SiO2, and PbO-Al2O3-SiO2. The viscosity of other ternary and multicomponent silicate melts containing PbO is then predicted by the model without any additional adjustable model parameters. Experimental viscosity data are reviewed for melts formed by PbO with SiO2, Al2O3, CaO, MgO, Na2O, and K2O. The deviation of the available experimental data from the viscosities predicted by the model is within experimental error limits.

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Acknowledgments

Financial assistance from the Natural Sciences and Engineering Research Council of Canada through a CRD grant in collaboration with POSCO Steel, Rio Tinto, Dupont, Vale INCO, and Teck Cominco is gratefully acknowledged. The authors are indebted to Eve Bélisle and Christopher Bale for programming the model into software for viscosity calculations.

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Author notes

  1. Wan-Yi Kim (formerly Ph.D. Student, Postdoctoral Fellow)

    Present address: Department of Mining and Materials Engineering, McGill University, Montreal, QC, H3A 2B2, Canada

Authors and Affiliations

  1. Center for Research in Computational Thermochemistry, École Polytechnique de Montréal, Montreal, QC, H3C 3A7, Canada

    Wan-Yi Kim (formerly Ph.D. Student, Postdoctoral Fellow), Arthur D. Pelton (Emeritus Professor and Director) & Sergei A. Decterov (Research Professor)

Authors
  1. Wan-Yi Kim
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  2. Arthur D. Pelton
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  3. Sergei A. Decterov
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Corresponding author

Correspondence to Sergei A. Decterov.

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Manuscript submitted May 6, 2011.

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Kim, WY., Pelton, A.D. & Decterov, S.A. Modeling the Viscosity of Silicate Melts Containing Lead Oxide. Metall Mater Trans B 43, 325–336 (2012). https://doi.org/10.1007/s11663-011-9610-6

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