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Grain Coarsening of Cast Magnesium Alloys at High Cooling Rate: A New Observation

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Abstract

Most studies in the area of grain refinement have always taken for granted that higher cooling rate results in finer grains. However, when microstructural variation of the as-cast Mg with cooling rate was investigated using a specially designed V-shaped copper mold, the results were different. Although fast cooling during solidification led to microstructural refining in pure Mg, grain coarsening was observed at a higher cooling rate in Mg alloys that were inoculation treated with 1.0wt pctZr and 1.4wt pctCaO, and in the Mg-Al binary alloys. It is considered that the grain coarsening at higher cooling rate was attributed to the smaller constitutional undercooling zone formed at fast cooling due to the high temperature gradient in the three Mg alloys. These results can help in redefining the role of cooling rate in the grain refinement process.

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References

  1. L. Lu, A.K. Dahle, D.H. StJohn: Scripta Mater, 2005, vol. 53, pp. 517-522.

    Article  Google Scholar 

  2. Y. Ali,D. Qiu, B. Jiang, F. Pan, M.X. Zhang: J. Alloys Compd, 2015, vol. 619(0), pp. 639-651.

    Article  Google Scholar 

  3. S. Guo, Q. Le, Z. Zhao, Z. Wang, J. Cui: Metall. Mater. Trans. A, 2005, vol. 404(1–2), pp. 323-329.

    Google Scholar 

  4. Y.X. Jin, L. Hua, X. Xu, Q. Peng: Mater. Sci., 2009, vol. 27(1), pp. 171–185.

    Google Scholar 

  5. H. Han, S. Liu, L. Kang, L. Liu (2008) J. Wuhan Univ. Tech. Mater. Sci. 23(2):194-197.

    Article  Google Scholar 

  6. M. Qian, A. Ramirez, A. Das (2009) J. Cryst. Growth. vol. 311(14), pp. 3708-3715.

    Article  Google Scholar 

  7. M. Qian, A. Ramirez: Magnesium Alloys - Design, Processing and Properties, InTech. 2011, pp. 163-186.

    Google Scholar 

  8. A. Ramirez, M. Qian, B. Davis, T. Wilks, D.H. StJohn: Scripta Mater., 2008, vol. 59(1), pp. 19-22.

    Article  Google Scholar 

  9. D.H. StJohn, M. A. Easton, M. Qian, J. A. Taylor: Metall. Mater. Trans. A., 2012, vol. 44(7), pp. 2935-2949.

    Article  Google Scholar 

  10. J. Campbell: Castings, 2nd Ed., Butterworth-Heinemann, Oxford, 2003.

    Google Scholar 

  11. S. Pang, G. Wu, W. Liu, M. Sun, Y. Zhang, Z. Liu, W. Ding: Mater. Sci. Eng. A., 2013, vol. 562, pp. 152-160.

    Article  Google Scholar 

  12. J.N. Wang, K. Xie: Scripta Mater., 2000, vol. 43(5), pp. 441-446.

    Article  Google Scholar 

  13. H.B. Dong, P.D. Lee: Acta Mater., 2005, vol. 53(3), pp. 659-668.

    Article  Google Scholar 

  14. D.H. StJohn, M. Qian, M. A. Easton, P. Cao, Z. Hildebrand: Metall. Mater. Trans. A., 2005, vol. 36A, pp. 1671-1679.

    Google Scholar 

  15. M.Easton, D. StJohn: Metall. Mater. Trans. A., 1999, vol. 30(6), pp. 1625-1633.

    Article  Google Scholar 

  16. M.Easton, D. StJohn: Metall. Mater. Trans. A., 1999, vol. 30(6), pp. 1613-1623.

    Article  Google Scholar 

  17. B.L. Bramfitt: Metall. Trans. A., 1970, vol. 1 pp. 1987-1995.

    Article  Google Scholar 

  18. P.M. Kelly, M.X. Zhang: Mater. Forum, 1999 vol. 23, pp. 41-62.

    Google Scholar 

  19. A.L. Greer, A. M. Bunn, A. Tronche, P.V. Evans, D.J. Bristow: Acta Mater., 2000, vol. 48, pp. 2823-2835.

    Article  Google Scholar 

  20. D. Qiu, M. X. Zhang, P.M. Kelly: Scripta Mater., 2009, vol. 61(3) pp. 312-315.

    Article  Google Scholar 

  21. Q. Ma, D.H. StJohn, M.T. Frost.: Scripta Mater., 2002, vol. 46(9), pp. 649-654.

    Article  Google Scholar 

  22. Y. Ali, D. Qiu, B. Jiang, F. Pan, M.X. Zhang: Scripta Mater., 2016, vol. 114, pp. 103-107.

    Article  Google Scholar 

  23. H.M. Fu, D. Qiu, M.X. Zhang, H. Wang, P. M. Kelly, J. A. Taylor: J. Alloys Compd., 2008, vol. 456(1-2), pp. 390-394.

    Google Scholar 

  24. M.Qian, D.H. Stjohn, M.T. Frost: Magnesium Technology. In: H.I. Kaplan (ed.) Magnesium Technology. TMS, Warrendale (2003).

    Google Scholar 

  25. M. Qian, A. Das: Scripta Mater., 2006, vol. 54, pp. 881-886.

    Article  Google Scholar 

  26. M. Johnsson: Thermochim. Acta., 1995, vol. 256(1) pp. 107-121.

    Article  Google Scholar 

  27. M.A. Easton, D.H. StJohn: Mater. Sci. Eng. A, 2008, vol. 486(1–2), pp. 8-13.

    Article  Google Scholar 

  28. F. Ochoa, J.J. Williams N. Chawla: J. Electron. Mater., 2003, vol. 32(12), pp. 1414-1420.

    Article  Google Scholar 

  29. Y. Zuo, J. Cui, Z. Zhao, Q. Zhu, F. Qu, X. Wang (2008) Chin. J. Rare Met., 32(5): 589-592.

    Google Scholar 

  30. J.H. Perepezko: Prog. Mater Sci. 2004, vol. 49(3–4), pp. 263-284.

    Article  Google Scholar 

  31. 31. J.A. Spittle: Int. Mater. Rev., 2006, vol. 51(4) pp. 247-269.

    Article  Google Scholar 

  32. J. Hunt: Mater. Sci. Eng., 1984, vol. 65(1) pp. 75-83.

    Article  Google Scholar 

  33. D.H. StJohn, M. Qian, M. A. Easton, P. Cao: Acta Mater., 2011 vol. 59(12) pp. 4907-4921.

    Article  Google Scholar 

  34. W. Yang, G.S. Peng, Z. Fan: in ICASP-4, 2014. London.

  35. MATLAB R2013b, 2013, MathWorks Inc. Natick, MA, USA.

  36. E-112, A: 2010, ASTM International USA.

  37. B.S. Murty, S.A. Kori, M. Chakraborty: Int. Mater. Rev., 2002, vol. 47(1), pp. 3-29.

    Article  Google Scholar 

  38. S.A. Kori, B.S. Murty, M. Chakraborty: J. Mater. Sci. Technol., 1999, vol. 15(9), pp. 986-992.

    Article  Google Scholar 

  39. D. Qiu, J.A. Taylor, M.X. Zhang, P.M. Kelly: Acta Mater. 2007, vol. 55(4), pp. 1447-1456.

    Article  Google Scholar 

  40. W. Kurz and D.J. Fisher: Fundamentals of solidification, 4th ed., Trans Tech Publications, Switzerland, 2005.

    Google Scholar 

  41. J.A. Dantzig, M. Rappaz: Solidification, 1st ed., EFPL Press, London, 2009.

    Book  Google Scholar 

  42. B. C. Zhou, S. L. Shang, Y. Wang, Z. K. Liu, Acta Mater., 2016, vol. 103, pp. 573-586.

    Article  Google Scholar 

Download references

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Correspondence to Ming-Xing Zhang Professor.

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Manuscript submitted August 13, 2016.

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Ali, Y., You, G., Pan, F. et al. Grain Coarsening of Cast Magnesium Alloys at High Cooling Rate: A New Observation. Metall Mater Trans A 48, 474–481 (2017). https://doi.org/10.1007/s11661-016-3852-5

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