Abstract
Despite the extensive literature on grain refinement, there is not a consensus on the mechanism of grain refinement in aluminum alloys. Recently, there has been a shift in understanding of the grain-refinement paradigm from purely being concerned with the nucleation event, called here the “nucleant paradigm,” to also being concerned with the effect of solute elements, or, the “solute paradigm,” on the final grain structure. This article is divided into two parts. In Part I, the literature underpinning both paradigms is explained, and the validity of the paradigm shift toward the solute paradigm as a more complete understanding of grain refinement is presented. Part II experimentally confirms the validity of the solute paradigm and details a mechanism which explains the need for both effective nucleants and a solute of a good segregating power in order to obtain grain refinement.
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References
D.G. McCartney: Int. Mater. Rev., 1989, vol. 34, pp. 247–60.
J.A. Taylor: Cast Met., 1996, vol. 8, pp. 225–52.
A. Cibula: J. Inst. Met, 1949–50, vol. 76, pp. 321–60.
A. Cibula: J. Inst. Met., 1951–52, vol. 80, pp. 1–16.
F.A. Crossley and L.F. Mondolfo: J. Met., 1951, vol. 191, pp. 1143–51.
M. Johnsson: Thermochimica Acta, 1995, vol. 256, pp. 107–21.
M. Johnsson and L. Backerud: Z. Metallkd. 1996, vol. 87 (3), pp. 216–20.
M. Johnsson: Ph.D. Thesis, Stockholm University, Stockholm, 1993.
G.P. Jones and J. Pearson: Metall. Trans. B, 1976, vol. 7B, pp. 223–34.
R.A. Rapp and X. Zheng: Metall. Trans. A, 1991, vol. 22A, pp. 3071–75.
A. Banjeri, W. Reif, and Q. Feng: J. Mater. Sci. 1994, vol. 29, pp. 1958–65.
A. Banjeri and W. Reif: Solidification Processing 1987, The Institute of Metals, London, 1988, pp. 145–48.
A. Banjeri and W. Reif: Metall. Trans. A, 1986, vol. 17A, pp. 2127–36.
M.E. Fine and J.G. Conley: Metall. Trans. A, 1990, vol. 21A, pp. 2609–10.
L. Arnberg, L. Backerud, and H. Klang: Met. Technol., 1982, vol. 9, pp. 7–13.
J. Wanqi and W. Reif: Z. Metallkd., 1993, vol. 84, pp. 445–50.
I.G. Davies, J.M. Dennis, and A. Hellawell: Metall. Trans., 1970, vol. 1, pp. 275–80.
M. Johnsson: Light Metals 1993, S.K. Das, ed., TMS, Warrendale, PA, 1993, pp. 769–77.
M.M. Guzowski, G.K. Sigworth, and D.A. Sentner: Metall. Trans. A, 1987, vol. 18A, pp. 603–19.
P.S. Mohanty, F.H. Samuel, J.E. Gruzleski, and T.J. Kosto: Light Metals 1994, U. Mannweiler, ed., TMS, Warrendale, PA, 1994, pp. 1039–45.
P.S. Mohanty and J.E. Gruzleski: Acta Metall. Mater., 1995, vol. 43, pp. 2001–12.
I. Maxwell and A. Hellawell: Metall. Trans., 1972, vol. 3, pp. 1487–93.
I. Maxwell and A. Hellawell: Acta Metall., 1975, vol. 23, pp. 229–37.
M Johnsson and L. Backerud: Z. Metallkd., 1992, vol. 83, pp. 774–80.
L.F. Mondolfo, S. Farooq, and C. Tse: Solidification Processing 1987, The Institute of Metals, London, 1988, pp. 133–36.
A.J. Cornish: Met. Sci., 1975, vol. 9, pp. 477–84.
J.A. Marcantonio and L.F. Mondolfo: Metall. Trans, 1971, vol. 2, pp. 465–71.
I. Maxwell and A. Hellawell: Acta Metall., 1975, vol. 23, pp. 901–09.
G.K. Sigworth: Metall. Trans. A, 1984, vol. 15A, pp. 277–82.
G.K. Sigworth: Metall. Trans. A, 1986, vol. 22A, pp. 349–51.
L. Backerud, P. Gustafson, and M. Johnsson: Aluminum, 1991, vol. 67, pp. 910–15.
L. Arnberg, L. Backerud, and H. Klang: Met. Technol., 1982, vol. 9, pp. 1–6.
M. Vader, J. Noordegraaf, and P.C. van Wiggen: Light Metals 1991, E.L. Rooy, ed., TMS, Warrendale, PA, 1991, pp. 1123–30.
R. Kiusaalas and L. Backerud: Solidification Processing 1987, The Institute of Metals, London, 1988, pp. 137–40.
M. Johnsson, L. Backerud, and G.K. Sigworth: Metall. Trans. A, 1993, vol. 24A, pp. 481–91.
C.D. Mayes, D.G. McCartney, and G.J. Tatlock: Light Metals 1992, E.R. Cutshall, ed., TMS, Warrendale, PA, 1992, pp. 813–19.
M. Vader and J. Noordegraaf: Light Metals 1989, P.G. Campbell, ed., TMS, Warrendale, PA, 1989, pp. 937–41.
M. Vader and J. Noordegraaf: Light Metals 1990, C.M. Bickert, ed., TMS Warrendale, PA, 1990, pp. 851–57.
M. Vader, J. Noordegraaf, P.C.van Wiggen, and P. Gudde: 2nd Aus. Asian Pacific Course and Conf. on aluminium Melt Treatment and Casting, M. Nilmani, University of Melbourne, July 1–4, 1991, Melbourne, pp. 30:1–7.
G.P. Jones: Solidification Processing 1987, The Institute of Metals, London, 1988, pp. 496–99.
G.P. Jones: Int. Sem. on Refining and Alloying of Liquid Aluminium and Ferro-Alloys, T. A. Engh et al., Dusseldorf: Aluminium-Verlag, Aug. 26–28, 1985, Trondheim, Norway, pp. 213–28.
G.K. Sigworth: Scripta Mater., 1996, vol. 34 (6), pp. 919–22.
P.S. Mohanty, R.I.L. Guthrie, and J.E. Gruzleski: Light Metals 1995, J. Evans, ed., TMS, Warrendale, PA, 1995, pp. 859–68.
P.S. Mohanty, F.H. Samuel, and J.E. Gruzleski: Metall. Mater. Trans. B, 1995, vol. 26B, pp. 103–10.
P. Schumacher and A.L. Greer: Light Metals 1995, J. Evans, ed., TMS, Warrendale, PA, 1995, pp. 869–77.
P. Schumacher and A.L. Greer: Mater. Sci. Eng., 1994, vols. A181-182, pp. 1335–39.
P. Schumacher and A.L. Greer: Mater. Sci. Eng., 1994, vol. A178, pp. 309–13.
P. Schumacher and A.L. Greer: Key Eng. Mater., 1993, vols. 81–83, pp. 631–36.
M.A. Kearns, S.R. Thistlewaite, and P.S. Cooper PS: Light Metals 1996, 1996, pp. 713–20.
S.E. Naess and O. Berg: Z. Metallkd., 1974, vol. 65, pp. 599–602.
P.S. Mohanty and J.E. Gruzleski: Acta Mater., 1996, vol. 44 (9), pp. 3749–60.
L. Backerud: Jernkot. Ann., 1971, vol. 155, pp. 422–24.
I. Maxwell and A. Hellawell: Acta. Metall., 1975, vol. 23, pp. 229–37.
L. Backerud and S. Yidong: Aluminium, 1991, vol. 67, pp. 780–85.
P.A. Tøndel: Ph.D. Thesis, The University of Trondheim, Trondheim, 1994.
D.R. Uhlmann and B. Chalmers: J. Appl. Phys., 1964, vol. 35, pp. 2986–93.
M. Johnsson: Z. Metallkd., 1994, vol. 85, pp. 781–85.
M. Johnsson: Z. Metallkd., 1994, vol. 85, pp. 786–89.
J.A. Spittle and S. Sadli: Cast Met., 1995, vol. 7, pp. 247–53.
J.A. Spittle and S. Sadli: Mater. Sci. Technol., 1995, vol. 11, pp. 533–37.
D.K. Young, B.T. Dunville, W.C. Setzer, and F.P. Koch: Light Metals 1991. E.L. Rooy, ed., TMS, Warrendale, PA, 1991, pp. 1115–21.
H. Li, T. Sritharan, Y.M. Lam, and N.Y. Leng: J. Mater. Sci. Technol., 1997, vol. 66, pp. 253–57.
H.T. Wu, L.C. Wang, and S.K. Kung: J. Chin. Foundryman’s Assoc., 1981, vol. 29, pp. 10–18.
Li Hang, T. Sritharan, and H.P. Seow: Scripta Mater., 1996, vol. 35, pp. 869–72.
G.K. Sigworth and M.M. Guzowski: AFS Trans., 1985, vol. 172, pp. 907–12.
P.A. Tondel, G. Halvosen, and L. Arnberg: Light Metals 1993, K. Das, ed., TMS, Warrendale, PA, 1993, pp. 783–90.
P.S. Mohanty and J.E. Gruzleski: Acta Mater., 1996, vol. 44 (9), pp. 3749–60.
M. Johnsson and L. Backerud: Z. Metallkd., 1996, vol. 87 (3), pp. 216–20.
J. Hutt, M. Easton, L. Hogan, and D. StJohn: Solidification Processing 97, J. Beech and H. Jones, ed., Department of Engineering Materials, University of Sheffield, UK, 1997, pp. 268–72.
J.A. Spittle, J.M. Keeble, and M. Al Meshhedani: Light Metals 1997, R. Huglen, ed., TMS, Warrendale, PA, 1997, pp. 795–800.
P.A. Tondel and L. Arnberg: The 3rd Int. Conf. on Aluminium Alloys, 1992, pp. 129–34.
W.V. Youdelis: Met. Sci., 1978, vol. 12, pp. 363–66.
G. Chai: Ph.D. Dissertation, Stockholm University, Stockholm, 1994.
G. Chai, L. Backerud, and L. Arnberg: Z. Metallkd., 1995, vol. 86, pp. 54–59.
D.H. StJohn: Acta Metall. Mater., 1990, vol. 38, pp. 631–36.
D.H. StJohn and L.M. Hogan: J. Mater. Sci., 1982, vol. 17, pp. 2413–18.
L. Arnberg, L. Backerud and H. Klang: Metal. Technol., 1982, vol. 9, pp. 14–17.
M. Johnsson, L. Bakerud and G.K. Sigworth: Metall. Trans A, 1993, vol. 24A, pp. 481–91.
L. Arnberg: Norwegian Institute of Science and Technology, Trondheim, Norway, private communication, 1997.
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Easton, M., StJohn, D. Grain refinement of aluminum alloys: Part I. the nucleant and solute paradigms—a review of the literature. Metall Mater Trans A 30, 1613–1623 (1999). https://doi.org/10.1007/s11661-999-0098-5
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DOI: https://doi.org/10.1007/s11661-999-0098-5