Abstract
Based on the available thermodynamic parameters and experimental diffusivities in the literature as well as measured in the present work, the diffusion mobilities of Ni, Cr, and Mo for fcc Ni-Cr-Mo alloys have been assessed by means of the CALPHAD method. Comprehensive comparisons between the calculated and experimental data show that an excellent agreement is obtained for the diffusion data of ternary diffusion couples, such as the interdiffusion coefficients, concentration profiles, and the diffusion path.
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R.B. Rebak: Adv. Mater. Processes, 2000, vol. 157, pp. 37-42.
I. Choudhury and M. El-Baradie: J. Mater. Process. Technol., 1998, vol. 77, no. 1, pp. 278-284.
J.N. DuPont, J.C. Lippold, and S.D. Kiser: Welding Metallurgy and Weldability of Nickel-Base Alloys, 1st ed., Wiley, New Jersey, 2009, pp. 15–45.
P.E.A. Turchi, L. Kaufman and Zi-Kui Liu: Calphad, 2006, vol. 30, pp. 70-87.
P.E.A. Turchi, L. Kaufman and Zi-Kui Liu: Calphad, 2007, vol. 31, pp. 237-248.
K. Frisk: Calphad, 1990, vol. 14, pp. 311-320.
S.H. Zhou, Y. Wang, C. Jiang, J.Z. Zhu, L.Q. Chen and Z.K. Liu: Mater. Sci. Eng., A, 2005, vol. 397, pp. 288-296.
Lijun Zhang, Yong Du, Qing Chen, Ingo Steinbach and Baiyun Huang: Int. J. Mater. Res., 2010, vol. 101, pp. 1461-1475.
A. Borgenstam, L. Höglund, J. Ågren and A. Engström: J. Phase Equilib., 2000, vol. 21, pp. 269-280.
M.S.A. Karunaratne and R.C. Reed: Defect and Diffusion Forum, Trans. Tech. Publ. Inc., Dürnten, 2005, vol. 237-240, pp. 420-425.
Y. Minamino, H. Yoshida, S.B. Jung, K. Hirao, and T. Yamane, Defect and Diffusion Forum, Trans. Tech. Publ. Inc., Dürnten, 1997 vol. 143–147, pp. 257–262.
C.P. Heijwegen, G.D. Rieck: Acta Metall., 1974, vol. 22, pp. 1269-1281.
Y. Ugaste and V. Pimenov: Phys. Met. Metallogr., 1972, vol. 33, pp. 125-130.
A. Davin, V. Leroy, D. Coutsouradis and L. Habraken: Cobalt, 1963, vol. 19, pp. 51-56.
R.A. Swalin, A. Martin and R. Olson: J. Met., 1957, vol. 9, pp. 936-939.
V.D. Divya, S.S.K. Balam, U. Ramamurty and A. Paul: Scr. Mater., 2010, vol. 62, pp. 621-624.
F. Sauer and V. Freise: Z. Elektrochem., 1962, vol. 66, pp. 353-362.
K. Monma, H. Suto and H. Oikawa: J. Jpn. Inst. Met., 1964, vol. 28, p. 188-192.
G.B. Fedorov, E. A. Smirnov, F. I. Zhomov: Metall. Metalloved. Chist. Met., 1963, vol. 4, pp. 110-121.
J. Růžičková and B. Million: Mater. Sci. Eng., 1981, vol. 50, pp. 59-64.
S.B. Jung, T. Yamane, Y. Minamino, K. Hirao, H. Araki and S. Saji: J. Mater. Sci. Lett., 1992, vol. 11, pp. 1333-1337.
A.V. Jaques and J.C. LaCombe: Defect and Diffusion Forum, Trans. Tech. Publ. Inc., Dürnten, 2007, vol. 266, pp. 181–190.
D.P. Whittle and A. Green: Scr. Metall., 1974, vol. 8, pp. 883-884.
B.J. Lee: Calphad, 1992, vol. 16, pp. 121-149.
K. Frisk and P. Gustafson: Calphad, 1988, vol. 12, pp. 247-254.
J. Mayer and K. Urban: Phys. Status Solidi A, 1985, vol. 90, pp. 469-475.
G. Grube and H. Schlecht: Z. Elektrochem., 1938, vol. 44, pp. 413-422.
R.E.W. Casselton and W. Hume-Rothery: J. Less-Common Met., 1964, vol. 7, pp. 212-221.
C.P. Heijwegen and G.D. Rieck: Z. Metallkd., 1973, vol. 64, pp. 450-453.
S.J.L. Kang, Y.D. Song, W.A. Kaysser and H. Hofmann: Z. Metallkd., 1984, vol. 75, pp. 86-91.
V.N. Svechnikov and V.M. Pan: Sb. Nauchn. Rab. Inst. Metallofiz., Akad. Nauk Ukr. SSR, 1962, vol. 15, pp. 164-178.
C.H.M. Jenkins, E.H. Bucknall, C.R. Austin and G.A. Mellor: J. Iron Steel Inst., London, 1937, vol. 136, pp. 187-222.
A. Chiba: Ph. D. Thesis, Tohoku University, Sendai, Japan, 1971 (cited in Ref. [24]).
E. R. Jette, V.H. Nordstrom, B. Queneau and F. Foote: Trans. AIME, 1934, vol. 111, p. 361-371.
A. Taylor and R.W. Floyd: J. Inst. Met., 1952, vol. 81, pp. 577-587.
C.J. Bechtoldt and H.C. Vacher: Trans. Metall. Soc. AIME, 1961, vol. 221, pp. 14-18.
L. Karmazin: Mater. Sci. Eng., 1982, vol. 54, pp. 247-256.
M. Kikuchi, M. Kajihara, Y. Kadoya, S. Takeda, and R. Tanaka: Report of the 123rd Committee on Heat-Resisting Metals and Alloys, 1981, vol. 22, pp. 31; J. Iron Steel Inst. Jpn., 1984, vol. 70, pp. 2246-2253; J. Iron Steel Inst. Jpn., 1985, vol. 71, pp. 1773-79 (cited in Ref. [24]).
H. Davies and W.W. Smeltzer: J. Electrochem. Soc., 1974, vol. 121, pp. 543-549.
R.O. Williams: Trans. AIME, 1957, vol. 209, pp. 1257-1260.
H.G. Baer: Z. Metallkd., 1958, vol. 49, pp. 614-622.
J.W. Putman, R.D. Potter and N.J. Grant: Trans. Am. Soc. Met., 1951, vol. 43, pp. 824-845.
D.S. Bloom, N.J. Grant: Trans. AIME, 1954, vol. 200, pp. 261–68.
V.N. Svechnikov and G.F. Kobzenko: Dokl. Chem., 1964, vol. 155, pp 287-90.
Y.A. Kocherzhinskii, V.I. Vasilenko Izv. Akad. Nauk SSSR Met. 4 205-07 1979
E. Rudy: Ternary Phase Equilibria in Transition Metal-boron-carbon-silicon Systems. Part 5. Compendium of Phase Diagram Data, Air Force Mat. Lab., Wright-Patterson, AFB, Ohio, Rep. No. AFML-TR-65-2, 1969 (cited in Ref. [25]).
O. Kubaschewski, T.G. Chart: J. Inst. Met., 1965, vol. 93, pp. 329–38.
J.O. Andersson and J. Ågren: J. Appl. Phys., 1992, vol. 72, pp. 1350-55.
B. Jönsson: Z. Metallkd., 1994, vol. 85, pp. 498-501.
K. Wu, J.E. Morral and Y. Wang: Acta Mater., 2004, vol. 52, pp. 1917-25.
B. Jönsson: Scand. J. Metall., 1995, vol. 24, pp. 21-27.
X.J. Liu, H.H. Hu, J.J. Han, Y. Lu and C.P. Wang: Calphad, 2012, vol. 38, pp. 140-45.
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The financial support from the National Key Project of Science and Technology (Grant Number: 2012ZX06004-012) is gratefully acknowledged.
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Manuscript submitted January 31, 2015.
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Zhu, N., Li, J., Lu, XG. et al. Experimental and Computational Study of Diffusion Mobilities for fcc Ni-Cr-Mo Alloys. Metall Mater Trans A 46, 5444–5455 (2015). https://doi.org/10.1007/s11661-015-3114-y
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DOI: https://doi.org/10.1007/s11661-015-3114-y