Abstract
While the role of Nb during the processing of austenite is quite clear, what happens in subsequent stages to the concentration of this element left in solution is subject to some debate. In particular, some uncertainty still subsists concerning the eventual homogeneous precipitation in Nb supersaturated polygonal ferrite. The present work was aimed at clarifying the precipitation sequence of Nb during coiling, through a systematic work and a careful selection of the processing conditions in order to produce different scenarios concerning the initial state of Nb. A Nb-microalloyed steel was thermomechanically processed in the laboratory followed by simulated coiling at different temperatures in the 873 K to 1023 K (600 °C to 750 °C) range. Transmission electron microscopy (TEM) showed interphase precipitation of NbC at high coiling temperatures, while at 873 K (600 °C), homogeneous general precipitation took place in ferrite and followed a Baker–Nutting orientation relationship.
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References
F.B. Pickering: Microalloying ‘75, Int. Symp. on HSLA Steels, Union Carbide Corp., New York, NY, 1975, pp. 9–31.
M. Cohen and W. Owen: Microalloying ‘75, Int. Symp. on HSLA Steels, Union Carbide Corp., New York, NY, 1975, pp. 2–8.
J.M. Rodríguez-Ibabe: Mater. Sci. Forum, 2005, vols. 500–501, pp. 49–62.
T. Gladman: The Physical Metallurgy of Microalloyed Steels, The Institute of Materials, London, 1997, pp. 1–363.
B. Dutta and C.M. Sellars: Mater. Sci. Technol., 1987, vol. 3, pp. 197–206.
W.J. Liu and J.J. Jonas: Metall. Trans. A, 1989, vol. 20A, pp. 689–97.
R. Abad, A.I. Fernandez, B. Lopez, and J.M. Rodriguez-Ibabe: ISIJ Int., 2001, vol. 41, pp. 1373–82.
E.J. Palmiere, C.I. García, and A.J. DeArdo: Metall. Mater. Trans. A, 1996, vol. 27A, pp. 951–60.
O. Kwon and A.J. DeArdo: Acta Metall. Mater., 1991, vol. 39, pp. 529–38.
Q. B. Yu, Z.D. Wang, X.H. Liu, and G.D. Wang: Mater. Sci. Eng. A, 2004, vol. A379, pp. 384–90.
S. Yamamoto, C. Ouchi, and T. Osuka: Thermomechanical Processing of Microalloyed Austenite, A.J. DeArdo, G.A. Ratz, and P.J. Wray, eds., TMS-AIME, Warrendale, PA, 1982, pp. 613–39.
S. Okaguchi, T. Hashimoto, and H. Ohtani: Proc. Conf. Thermec′87, Iron Steel Institute of Japan, Tokyo, 1988, vol. 1, pp. 330–36.
M. Takahashi and H.K.D.H. Bhadeshia: Mater. Sci. Technol., 1990, vol. 6, pp. 592–603.
C. Garcia-Mateo, F.G. Caballero, C. Capdevila, and C. Garcia de Andres: Scripta Mater., 2009, vol. 61, pp. 855–58.
R.Z. Wang, C.I. Garcia, M. Hua, K. Cho, H.T. Zhang, and A.J. DeArdo: ISIJ Int., 2006, vol. 46, pp. 1345–53.
S.S. Campos, E.V. Morales, and H.J. Kestenbach: Metall. Mater. Trans. A, 2001, vol. 32A, pp. 1245–48.
J.C. Herman, B. Donnay, and V. Leroy: ISIJ Int., 1992, vol. 32, pp. 779–85.
T. Sakuma and R.W.K. Honeycombe: Met. Sci., 1984, vol. 18, pp. 449–54.
T. Sakuma and R.W.K. Honeycombe: Mater. Sci. Technol., 1985, vol. 1, pp. 351–56.
A. Itman, K.R. Cardoso, and H.J. Kestenbach: Mater. Sci. Technol., 1997, vol. 13, pp. 49–55.
R.G. Baker and J. Nutting: Special Report No. 64, Iron Steel Institute, London, 1959, pp. 1–22.
H.J. Kestenbach, S.S. Campos, J. Gallego, and E.V. Morales: Metall. Mater. Trans. A, 2003, vol. 34A, pp. 1013–17.
H.J. Kestenbach: Mater. Sci. Technol., 1997, vol. 13, pp. 731–39.
A.J. DeArdo: Int. Mater. Rev., 2003, vol. 48, pp. 371–402.
V. Thillou, M. Hua, C.I. Garcia, C. Perdrix, and A.J. DeArdo: Mater. Sci. Forum, 1998, vols. 284–286, pp. 311–18.
M. Charleux, W.J. Poole, M. Militzer, and A. Deschamps: Metall. Mater. Trans. A, 2001, vol. 32A, pp. 1635–47.
T. Parayil and G. Ludkovsky: Proc. Int. Symp. on Accelerated Cooling of Rolled Steel, G.E. Ruddle and A.F. Crawley, eds., Pergamon Press, Oxford, United Kingdom, 1987, pp. 131–44.
E. Courtois, T. Epicier, and C. Scott: Micron, 2006, vol. 32, pp. 492–502.
M. Perez, E. Courtois, D. Acevedo, T. Epicier, and P. Maugis: Phil. Mag. Lett., 2007, vol. 87 (9), pp. 645–56.
C. Hin, Y. Bréchet, P. Maugis, and F. Soisson: Acta Mater., 1998, vol. 56, pp. 5535–43.
M.A. Altuna, A. Iza-Mendia, and I. Gutierrez: Proc. 3rd Int. Conf. on Thermomechanical Processing of Steels, CD edited by Associazione Italiana di Metallurgia, Padua, Italy, Sept. 10–12, 2008; also published in La Metallurgia Italiana, 2009, June, pp. 41–47.
M.A. Altuna, A. Iza-Mendia, and I. Gutiérrez: Metall. Mater. Trans. A, DOI: 10.1007/s11661-012-1270-x.
I. Gutierrez, M.A. Altuna, G. Paul, S.V. Parker, J.H. Bianchi, P. Vescovo, C. Mesplont, M. Wojcicki, and R. Kawalla: EUR 23181 EN, Technical Steel Research, Luxembourg, 2008.
R.L. Higginson and C.M. Sellars: Worked Examples in Quantitative Metallography, Minerals and Mining, The Institute of Materials, London, 2003, pp. 1–116.
B. López, C. Scott, A. Rose, B. Soenen, B. Lopez, and G. Paul: EUR 22431, Technical Steel Research, Luxembourg, 2006.
H.S. Zurob, C.R. Hutchinson, Y. Brechet, and G. Purdy: Acta Mater., 2002, vol. 50, pp. 3075–92.
A. Deschamps and Y. Brechet: Acta Mater., 1998, vol. 47, pp. 293–305.
B. Dutta, E.J. Palmiere, and C.M. Sellars: Acta Mater., 2001, vol. 49, pp. 785–94.
C. Zhou and R. Priestner: ISIJ Int., 1996, vol. 36, pp. 1397–1405.
A.J. Craven, K. He, L.A.J. Garvie, and T.N. Baker: Acta Mater., 2000, vol. 48, pp. 3857–68.
A.J. Craven, K. He, L.A.J. Garvie, and T.N. Baker: Acta Mater., 2000, vol. 48, pp. 3869–78.
H.J. Jun, K.B. Kang, and C.G. Park: Scripta Mater., 2003, vol. 49, pp. 1081–86.
E. Novillo, D. Hernández, I. Gutiérrez, and B. Lopez: Mater. Sci. Eng. A, 2004, vol. 385, pp. 83–90.
E. Novillo, E. Cotrina, A. Iza-Mendia, B. López, and I. Gutierrez: Mater. Sci. Forum, 2005, vols. 500–501, pp. 355–62.
J.H. Wu, P.J. Wray, C.I. Garcia, M.J. Hua, and A.J. DeArdo: ISIJ Int., 2005, vol. 45, pp. 254–62.
J. Wu, C.I. Garcia, M. Hua, W. Gao, K. Cho, and A.J. DeArdo: Mater. Sci. Technol., (MS&T) 2006: Product Manufacturing, Materials, (ACerS, AIST, ASM, and TMS), Warrendale, PA, pp. 305–16.
R. Lagneborg and S. Zajac: Metall. Mater. Trans. A, 2000, vol. 21A, pp. 1–12.
R. Okamoto and J. Agren: Acta Mater., 2010, vol. 58, pp. 4791–4803.
N. Isasti: Ph.D. Thesis, University of Navarra, Basque Country, Spain, In course.
T. Sakuma and R.W.K. Honeycombe: Met. Sci., 1984, vol. 18, pp. 449–54.
R.W.K. Honeycombe: Metall. Trans. A, 1976, vol. 7A, pp. 915–36.
R.M. Smith and D.P. Dune: Mater. Forum, 1988, vol. 11, pp. 166–81.
Y. Kang, H. Yu, J. Fu, K. Wang, and Z. Wang: Mater. Sci. Eng. A, 2003, vol. 351A, pp. 265–71.
Y. Maehara and Y. Ohmori: Mater. Sci. Eng., 1984, vol. 62, pp. 109–19.
F.G. Wilson and T. Gladman: Int. Mater. Rev., 1988, vol. 33, pp. 221–86.
M. Doi and Z. Nishiyama: Nippon Kiugoku Gakkai-Si, 1953, vol. 17, p. 487.
K.H. Jack: JISI, 1951, vol. 169, pp. 26–36.
D.H. Huang and G. Thomas: Metall. Trans. A, 1977, vol. 8A, pp. 1661–75.
N. Takahashi, M. Shibata, Y. Furuno, H. Hayakawa, K. Kakuta, and K. Yamamoto: Proc. Metallurgy of Continuous Annealed Sheet Steel, B.L. Bramfitt and P.L. Mangonon, eds., TMS-AIME, Warrendale, PA, 1982, pp. 133–53.
B. Engl and E.J. Drewes: Proc. Technology of Continuously Annealed Cold-Rolled Sheet Steel, R. Pradhan, ed., TMS-AIME, Warrendale, PA, 1985, pp. 123–38.
F.J. Revidriejo, R. Abad, B. López, I. Gutiérrez, and J.J. Urcola: Scripta Mater., 1996, vol. 34, pp. 1589–94.
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Iza-Mendia, A., Altuna, M.A., Pereda, B. et al. Precipitation of Nb in Ferrite After Austenite Conditioning. Part I: Microstructural Characterization. Metall Mater Trans A 43, 4553–4570 (2012). https://doi.org/10.1007/s11661-012-1395-y
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DOI: https://doi.org/10.1007/s11661-012-1395-y