Skip to main content

Advertisement

Log in

Analysis of Microstructure Evolution in Quenching and Partitioning Automotive Sheet Steel

  • Symposium: Austenite Formation and Decomposition IV
  • Published:
Metallurgical and Materials Transactions A Aims and scope Submit manuscript

Abstract

Extensive research efforts are underway globally to develop new steel microstructure concepts for high-strength sheet products, driven largely by the need for lightweight automotive structures in support of designs to enhance occupant safety and energy efficiency. One promising approach, involving the quenching and partitioning (Q&P) process, was introduced in the predecessor to this paper series, Austenite Formation and Decomposition, 2003.[1] Development of the Q&P process has continued through to the present, and the current status is highlighted in this article, along with some alternative approaches that are also receiving attention. Special emphasis is placed on the synthesis and interpretation of the fundamental phase transformation responses, perspectives related to alloying and processing, and the resulting microstructure and properties. Key mechanistic issues are discussed, including carbide formation and suppression, migration of the martensite/austenite interface, carbon partitioning, and partitioning kinetics.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13

Similar content being viewed by others

Notes

  1. Although the ability to apply the desired thermal process signature consistently raises important issues being considered in industrial scale-up investigations (related to microstructure and property variability), these engineering aspects are not addressed in this article.

  2. Substantial similarities also exist between (one-step) Q&P and some other processes proposed recently such as TRIP-dual,[23] Interrupted quenching plus tempering,[39] and TRIP aided bainitic ferrite.[40] These process variants incorporate a somewhat wider range of responses, including higher process temperatures where martensite formation is deemphasized and austempered carbide-free bainite is the primary constituent.

  3. One might envision that a glissile austenite/martensite interface could have potentially even greater mobility,[54] but this situation has not yet been explored.

  4. The characteristic behaviors in the figure are different than observed in similar work involving bainite transformation, and bainite formation would clearly be accompanied by an increase in the bcc fraction and a decrease in the face-centered cubic fraction.[58]

References

  1. J.G. Speer, A.M. Streicher, D.K. Matlock, F. Rizzo, and G. Krauss: Austenite Formation and Decomposition, ISS/TMS, Warrendale, PA, 2003, pp. 505-22.

    Google Scholar 

  2. D.K. Matlock and J.G. Speer: Proc. of the 3rd International Conference on Structural Steels, Korean Institute of Metals and Materials, Seoul, South Korea, 2006, pp. 774-81.

    Google Scholar 

  3. O. Kwon, K. Lee, G. Kim, and K.G. Chin: Mater. Sci. Forum, 2010, vols. 638-42, pp. 136-41.

    Article  Google Scholar 

  4. M.L. Brandt and G.B. Olson: Iron Steelmaker, 1993, vol. 20, no. 5, pp. 55-60.

    CAS  Google Scholar 

  5. P. Gibbs, E. De Moor, M. Merwin, B. Clausen, J.G. Speer, and D.K. Matlock: Metall. Mater. Trans. A, DOI:10.1007/s11661-011-0687-y.

  6. D.K. Matlock and J.G. Speer: Microstructure and Texture in Steels and Other Materials, Springer, London, UK, 2009, pp. 185-205.

    Book  Google Scholar 

  7. E. De Moor, P.J. Gibbs, J.G. Speer, D.K. Matlock, and J.G. Schroth: AIST Trans., 2010, vol. 7, no. 3, pp. 133-44.

    Google Scholar 

  8. H.N. Han, C.S. Oh, G. Kim, and O. Kwon: Mater. Sci. Eng. A, 2009, vol. A499, pp. 462-68.

    CAS  Google Scholar 

  9. M.J. Merwin: Mater. Sci. Forum, 2007, vols. 539-43, pp. 4327-32.

    Article  Google Scholar 

  10. E. De Moor, D.K. Matlock, J.G. Speer, and M.J. Merwin: Scripta Mater., 2011, vol. 64, pp. 185-88.

    Article  Google Scholar 

  11. E. De Moor, J.G. Speer, D.K. Matlock, J.H. Kwak, and S.B. Lee: ISIJ Int., 2011, vol. 51, no 1, pp. 137-44.

    Article  Google Scholar 

  12. S. Lee, K. Lee, and B.C. De Cooman: Mater. Sci. Forum, 2010, vols. 654-56, pp. 286-89.

    Article  Google Scholar 

  13. J. Shi, X. Sun, M. Wang, W. Hui, H. Dong, and W. Cao: Scripta Mater., 2010, vol. 63, pp. 815-18.

    Article  CAS  Google Scholar 

  14. ISO 2566/1-1984(E): Steel—Conversion of Elongation Values – Part 1: Carbon and Low Alloy Steels, 1984, pp. 1–28.

  15. O. Matsumura, Y. Sakuma, and H. Takechi: Trans. ISIJ, 1987, vol. 27, pp. 570-79.

    Article  CAS  Google Scholar 

  16. F. Rizzo, A.R. Martins, J.G. Speer, D. Matlock, A. Streicher, and B. De Cooman: Mater. Sci. Forum, 2007, vols. 539-543, pp. 4476-81.

    Article  Google Scholar 

  17. H.Y. Li, X.W. Lu, W.J. Li, and X.J. Jin: Metall. Mater. Trans. A, 2010, vol. 41A, pp. 1284-1300.

    Article  CAS  Google Scholar 

  18. M.J. Santofimia, T. Nguyen-Minh, L. Zhao, R. Petrov, I. Sabirov, and J. Sietsma: Mater. Sci. Eng. A, 2010, vol. A527, pp. 6429-39.

    CAS  Google Scholar 

  19. F.G. Caballero and H.K.D.H. Bhadeshia: Curr. Opin. Solid State Mater. Sci., 2004, vol. 8, pp. 251-57.

    Article  CAS  Google Scholar 

  20. H.Y. Li, X.W. Lu, X.C. Wu, Y.A. Min, and X.J. Jin: Mater. Sci. Eng. A, 2010, vol. A527, pp. 6255-59.

    CAS  Google Scholar 

  21. N. Zhong, X.D. Wang, L. Wang, and Y.H. Rong: Mater. Sci. Eng., 2009, vol. 506, pp. 111-16.

    Article  Google Scholar 

  22. H. Li and X. Jin: Chin. J. Mech. Eng., 2009, vol. 22, pp. 645-50.

    Article  CAS  Google Scholar 

  23. H.J. Jun and N. Fonstein: Proc. Intl. Conf. on New Developments in Advanced High-Strength Sheet Steels, AIST, Warrendale, PA, 2008, pp. 155-68.

    Google Scholar 

  24. L. Wang and W. Feng: Advanced Steels, Springer-Verlag, New York, NY, 2011, pp. 255-58.

    Book  Google Scholar 

  25. K.H. Kim: Patent Application WO2008KR7356A, 2008.

  26. A.M. Streicher, J.G. Speer, D.K. Matlock, and B.C. De Cooman: Int. Conf. on Advanced High-Strength Sheet Steels for Automotive Applications Proceedings, AIST, Warrendale, PA, 2004, pp. 51-62.

    Google Scholar 

  27. G.A. Thomas, J.G. Speer, and D.K. Matlock: AIST Trans., 2008, vol. 5, no. 10, pp. 209-17.

    CAS  Google Scholar 

  28. G.A. Thomas, J.G. Speer, and D.K. Matlock: Metall. Mater. Trans. A, DOI:10.1007/s11661-011-0648-5.

  29. M. Blankenau and R. Hughes: Private communication, June 9, 2004.

  30. H. Liu, X. Lu, X. Jin, H. Dong, and J. Shi: Scripta Mater., 2011, vol. 64, pp. 749-52.

    Article  CAS  Google Scholar 

  31. J.G. Speer, D.K. Matlock, B.C. De Cooman, and J.G. Schroth: Acta Mater., 2003, vol. 51, pp. 2611-22.

    Article  CAS  Google Scholar 

  32. J.G. Speer, D.K. Matlock, B.C. De Cooman, and J.G. Schroth: Scripta Mater., 2005, vol. 52, pp. 83-85.

    Article  CAS  Google Scholar 

  33. M. Hillert and J. Ågren: Scripta Mater., 2004, vol. 50, pp. 697-99.

    Article  CAS  Google Scholar 

  34. J.G. Speer, R.E. Hackenberg, B.C. De Cooman, and D.K. Matlock: Phil. Mag. Lett, 2007, vol. 87, pp. 379-82.

    Article  CAS  Google Scholar 

  35. M.F. Gallagher, J.G. Speer, D.K. Matlock, and N.M. Fonstein: 44th Mechanical Working and Steel Processing Conference Proc., 2002, Vol. XL, pp. 153–72.

  36. F.L.H. Gerdemann, J.G. Speer, and D.K. Matlock: Proc. Materials Science and Technology 2004, TMS/AIST, Warrendale, PA, 2004, pp. 439-49.

    Google Scholar 

  37. D.V. Edmonds, K. He, F.C. Rizzo, B.C. De Cooman, D.K. Matlock, and J.G. Speer: Mater. Sci. Eng. A, 2006, vols. A438-40, pp. 25-34.

    Google Scholar 

  38. A.J. Shutts, J.G. Speer, D.K. Matlock, D.V. Edmonds, F. Rizzo, and E.B. Damm: Int. Conf. on New Developments in Long and Forged Products: Metallurgy and Applications, AIST, Warrendale, PA, 2006, pp. 191-202.

    Google Scholar 

  39. S. Cobo, C. Colin, and S. Allain: New Developments on Metallurgy and Applications of High Strength Steels, vol. 1, TMS, Warrendale, PA, 2008, pp. 209–21.

  40. K. Sugimoto, M. Murata, and S.M. Song: ISIJ Int., 2010, vol. 50, pp. 162-68.

    Article  CAS  Google Scholar 

  41. D.V. Edmonds, K. He, F.C. Rizzo, J.G. Speer, and D.K. Matlock: New Developments on Metallurgy and Applications of High Strength Steels, vol. 2, TMS, Warrendale, PA, 2008, pp. 829–41.

  42. M.J. Santofimia, T. Nguyen-Minh, L. Zhao, D.N. Hanlon, T.A. Kop, and J. Sietsma: Proc. of the Intl. Conf. on New Developments in Advanced High-Strength Sheet Steels, AIST, Warrendale, PA, 2008, pp. 191-98.

    Google Scholar 

  43. E. De Moor, J. Penning, C. Föjer, A.J. Clarke, and J.G. Speer: Proc. of the Intl. Conf. on New Developments in Advanced High-Strength Sheet Steels, AIST, Warrendale, PA, 2008, pp. 199-207.

    Google Scholar 

  44. A.J. Clarke, J.G. Speer, M.K. Miller, R.E. Hackenberg, D.V. Edmonds, D.K. Matlock, F.C. Rizzo, K.D. Clarke, and E. De Moor: Acta Mater., 2008, vol. 56, pp. 16-22.

    Article  CAS  Google Scholar 

  45. D.H. Kim, J. Speer, H.S. Kim, and B. De Cooman: Metall. Mater. Trans. A, 2009, vol. 40A, pp. 2048-60.

    Article  CAS  Google Scholar 

  46. M.J. Santofimia, J.G. Speer, A. Clarke, L. Zhao, and J. Sietsma: Acta Mater., 2009, vol. 57, pp. 4548-57.

    Article  CAS  Google Scholar 

  47. M. Hillert, L. Hoglund, and J. Ågren: Acta Metall. Mater., 1993, vol. 41, pp. 1951-57.

    Article  CAS  Google Scholar 

  48. F. Rizzo, D Edmonds, K. He, J. Speer, D. Matlock, and A.M. Streicher: Solid-to-Solid Phase Transformations in Inorganic Materials 2005, vol. 1, TMS, Warrendale, PA, 2005, pp. 535–44.

  49. A. Clarke, J.G. Speer, D.K. Matlock, F.C. Rizzo, D.V. Edmonds, and K. He: Solid-to-Solid Phase Transformations in Inorganic Materials 2005, vol. 2, TMS, Warrendale, PA, 2005, pp. 99–108.

  50. D. Kalish and M. Cohen: Mater. Sci. Eng., 1970, vol. 6, pp. 156-66.

    Article  CAS  Google Scholar 

  51. A.J. Clarke, J.G. Speer, D.K. Matlock, F.C. Rizzo, D.V. Edmonds, and M.J. Santofimia: Scripta Mater., 2009, vol. 61, pp. 149-52.

    Article  CAS  Google Scholar 

  52. M.J. Santofimia, L. Zhao, and J. Sietsma: Scripta Mater., 2008, vol. 59, pp. 159-62.

    Article  CAS  Google Scholar 

  53. M.J. Santofimia, L. Zhao, and J. Sietsma: Metall. Mater. Trans. A, DOI:10.1007/s11661-011-0706-z.

  54. G.R. Purdy: Personal communication, May 11, 2011.

  55. Y. Cao, F. Ernst, and G.M. Michal: Acta Mater., 2003, vol. 51, pp. 4171-81.

    Article  CAS  Google Scholar 

  56. T.D. Bigg, D.K. Matlock, J.G. Speer, and D.V. Edmonds: Solid State Phenom., 2011, vols. 172-4, pp. 827-32.

    Article  Google Scholar 

  57. D.V. Edmonds, D.K. Matlock, and J.G. Speer: Proc. 1st Int. Conf. Advanced Steels, Metallurgical Industry Press, Beijing, China, 2010, pp. 229-41.

    Google Scholar 

  58. H.J. Stone, M.J. Peet, H.K.D.H. Bhadeshia, P.J. Withers, S.S. Babu, and E.D. Specht: Proc. R. Soc. A, 2008, vol. 464, pp. 1009-27.

    Article  CAS  Google Scholar 

  59. F. Danoix: unpublished research, Universite de Rouen, 2011.

  60. E. De Moor, C. Föjer, J. Penning, A.J. Clarke, and J.G. Speer: Phys. Rev. B, 2010, vol. 82, pp. 104210-1-5.

Download references

Acknowledgments

The authors gratefully acknowledge the sponsors of the Advanced Steel Processing and Products Research Center, an industry/university cooperative research center at the Colorado School of Mines, and the National Science Foundation through award number CMMI-0729114.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to John G. Speer.

Additional information

Manuscript submitted February 16, 2011.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Speer, J.G., De Moor, E., Findley, K.O. et al. Analysis of Microstructure Evolution in Quenching and Partitioning Automotive Sheet Steel. Metall Mater Trans A 42, 3591–3601 (2011). https://doi.org/10.1007/s11661-011-0869-7

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11661-011-0869-7

Keywords

Navigation