Abstract
Extensive research efforts are underway globally to develop new steel microstructure concepts for high-strength sheet products, driven largely by the need for lightweight automotive structures in support of designs to enhance occupant safety and energy efficiency. One promising approach, involving the quenching and partitioning (Q&P) process, was introduced in the predecessor to this paper series, Austenite Formation and Decomposition, 2003.[1] Development of the Q&P process has continued through to the present, and the current status is highlighted in this article, along with some alternative approaches that are also receiving attention. Special emphasis is placed on the synthesis and interpretation of the fundamental phase transformation responses, perspectives related to alloying and processing, and the resulting microstructure and properties. Key mechanistic issues are discussed, including carbide formation and suppression, migration of the martensite/austenite interface, carbon partitioning, and partitioning kinetics.
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Notes
Although the ability to apply the desired thermal process signature consistently raises important issues being considered in industrial scale-up investigations (related to microstructure and property variability), these engineering aspects are not addressed in this article.
Substantial similarities also exist between (one-step) Q&P and some other processes proposed recently such as TRIP-dual,[23] Interrupted quenching plus tempering,[39] and TRIP aided bainitic ferrite.[40] These process variants incorporate a somewhat wider range of responses, including higher process temperatures where martensite formation is deemphasized and austempered carbide-free bainite is the primary constituent.
One might envision that a glissile austenite/martensite interface could have potentially even greater mobility,[54] but this situation has not yet been explored.
The characteristic behaviors in the figure are different than observed in similar work involving bainite transformation, and bainite formation would clearly be accompanied by an increase in the bcc fraction and a decrease in the face-centered cubic fraction.[58]
References
J.G. Speer, A.M. Streicher, D.K. Matlock, F. Rizzo, and G. Krauss: Austenite Formation and Decomposition, ISS/TMS, Warrendale, PA, 2003, pp. 505-22.
D.K. Matlock and J.G. Speer: Proc. of the 3rd International Conference on Structural Steels, Korean Institute of Metals and Materials, Seoul, South Korea, 2006, pp. 774-81.
O. Kwon, K. Lee, G. Kim, and K.G. Chin: Mater. Sci. Forum, 2010, vols. 638-42, pp. 136-41.
M.L. Brandt and G.B. Olson: Iron Steelmaker, 1993, vol. 20, no. 5, pp. 55-60.
P. Gibbs, E. De Moor, M. Merwin, B. Clausen, J.G. Speer, and D.K. Matlock: Metall. Mater. Trans. A, DOI:10.1007/s11661-011-0687-y.
D.K. Matlock and J.G. Speer: Microstructure and Texture in Steels and Other Materials, Springer, London, UK, 2009, pp. 185-205.
E. De Moor, P.J. Gibbs, J.G. Speer, D.K. Matlock, and J.G. Schroth: AIST Trans., 2010, vol. 7, no. 3, pp. 133-44.
H.N. Han, C.S. Oh, G. Kim, and O. Kwon: Mater. Sci. Eng. A, 2009, vol. A499, pp. 462-68.
M.J. Merwin: Mater. Sci. Forum, 2007, vols. 539-43, pp. 4327-32.
E. De Moor, D.K. Matlock, J.G. Speer, and M.J. Merwin: Scripta Mater., 2011, vol. 64, pp. 185-88.
E. De Moor, J.G. Speer, D.K. Matlock, J.H. Kwak, and S.B. Lee: ISIJ Int., 2011, vol. 51, no 1, pp. 137-44.
S. Lee, K. Lee, and B.C. De Cooman: Mater. Sci. Forum, 2010, vols. 654-56, pp. 286-89.
J. Shi, X. Sun, M. Wang, W. Hui, H. Dong, and W. Cao: Scripta Mater., 2010, vol. 63, pp. 815-18.
ISO 2566/1-1984(E): Steel—Conversion of Elongation Values – Part 1: Carbon and Low Alloy Steels, 1984, pp. 1–28.
O. Matsumura, Y. Sakuma, and H. Takechi: Trans. ISIJ, 1987, vol. 27, pp. 570-79.
F. Rizzo, A.R. Martins, J.G. Speer, D. Matlock, A. Streicher, and B. De Cooman: Mater. Sci. Forum, 2007, vols. 539-543, pp. 4476-81.
H.Y. Li, X.W. Lu, W.J. Li, and X.J. Jin: Metall. Mater. Trans. A, 2010, vol. 41A, pp. 1284-1300.
M.J. Santofimia, T. Nguyen-Minh, L. Zhao, R. Petrov, I. Sabirov, and J. Sietsma: Mater. Sci. Eng. A, 2010, vol. A527, pp. 6429-39.
F.G. Caballero and H.K.D.H. Bhadeshia: Curr. Opin. Solid State Mater. Sci., 2004, vol. 8, pp. 251-57.
H.Y. Li, X.W. Lu, X.C. Wu, Y.A. Min, and X.J. Jin: Mater. Sci. Eng. A, 2010, vol. A527, pp. 6255-59.
N. Zhong, X.D. Wang, L. Wang, and Y.H. Rong: Mater. Sci. Eng., 2009, vol. 506, pp. 111-16.
H. Li and X. Jin: Chin. J. Mech. Eng., 2009, vol. 22, pp. 645-50.
H.J. Jun and N. Fonstein: Proc. Intl. Conf. on New Developments in Advanced High-Strength Sheet Steels, AIST, Warrendale, PA, 2008, pp. 155-68.
L. Wang and W. Feng: Advanced Steels, Springer-Verlag, New York, NY, 2011, pp. 255-58.
K.H. Kim: Patent Application WO2008KR7356A, 2008.
A.M. Streicher, J.G. Speer, D.K. Matlock, and B.C. De Cooman: Int. Conf. on Advanced High-Strength Sheet Steels for Automotive Applications Proceedings, AIST, Warrendale, PA, 2004, pp. 51-62.
G.A. Thomas, J.G. Speer, and D.K. Matlock: AIST Trans., 2008, vol. 5, no. 10, pp. 209-17.
G.A. Thomas, J.G. Speer, and D.K. Matlock: Metall. Mater. Trans. A, DOI:10.1007/s11661-011-0648-5.
M. Blankenau and R. Hughes: Private communication, June 9, 2004.
H. Liu, X. Lu, X. Jin, H. Dong, and J. Shi: Scripta Mater., 2011, vol. 64, pp. 749-52.
J.G. Speer, D.K. Matlock, B.C. De Cooman, and J.G. Schroth: Acta Mater., 2003, vol. 51, pp. 2611-22.
J.G. Speer, D.K. Matlock, B.C. De Cooman, and J.G. Schroth: Scripta Mater., 2005, vol. 52, pp. 83-85.
M. Hillert and J. Ågren: Scripta Mater., 2004, vol. 50, pp. 697-99.
J.G. Speer, R.E. Hackenberg, B.C. De Cooman, and D.K. Matlock: Phil. Mag. Lett, 2007, vol. 87, pp. 379-82.
M.F. Gallagher, J.G. Speer, D.K. Matlock, and N.M. Fonstein: 44th Mechanical Working and Steel Processing Conference Proc., 2002, Vol. XL, pp. 153–72.
F.L.H. Gerdemann, J.G. Speer, and D.K. Matlock: Proc. Materials Science and Technology 2004, TMS/AIST, Warrendale, PA, 2004, pp. 439-49.
D.V. Edmonds, K. He, F.C. Rizzo, B.C. De Cooman, D.K. Matlock, and J.G. Speer: Mater. Sci. Eng. A, 2006, vols. A438-40, pp. 25-34.
A.J. Shutts, J.G. Speer, D.K. Matlock, D.V. Edmonds, F. Rizzo, and E.B. Damm: Int. Conf. on New Developments in Long and Forged Products: Metallurgy and Applications, AIST, Warrendale, PA, 2006, pp. 191-202.
S. Cobo, C. Colin, and S. Allain: New Developments on Metallurgy and Applications of High Strength Steels, vol. 1, TMS, Warrendale, PA, 2008, pp. 209–21.
K. Sugimoto, M. Murata, and S.M. Song: ISIJ Int., 2010, vol. 50, pp. 162-68.
D.V. Edmonds, K. He, F.C. Rizzo, J.G. Speer, and D.K. Matlock: New Developments on Metallurgy and Applications of High Strength Steels, vol. 2, TMS, Warrendale, PA, 2008, pp. 829–41.
M.J. Santofimia, T. Nguyen-Minh, L. Zhao, D.N. Hanlon, T.A. Kop, and J. Sietsma: Proc. of the Intl. Conf. on New Developments in Advanced High-Strength Sheet Steels, AIST, Warrendale, PA, 2008, pp. 191-98.
E. De Moor, J. Penning, C. Föjer, A.J. Clarke, and J.G. Speer: Proc. of the Intl. Conf. on New Developments in Advanced High-Strength Sheet Steels, AIST, Warrendale, PA, 2008, pp. 199-207.
A.J. Clarke, J.G. Speer, M.K. Miller, R.E. Hackenberg, D.V. Edmonds, D.K. Matlock, F.C. Rizzo, K.D. Clarke, and E. De Moor: Acta Mater., 2008, vol. 56, pp. 16-22.
D.H. Kim, J. Speer, H.S. Kim, and B. De Cooman: Metall. Mater. Trans. A, 2009, vol. 40A, pp. 2048-60.
M.J. Santofimia, J.G. Speer, A. Clarke, L. Zhao, and J. Sietsma: Acta Mater., 2009, vol. 57, pp. 4548-57.
M. Hillert, L. Hoglund, and J. Ågren: Acta Metall. Mater., 1993, vol. 41, pp. 1951-57.
F. Rizzo, D Edmonds, K. He, J. Speer, D. Matlock, and A.M. Streicher: Solid-to-Solid Phase Transformations in Inorganic Materials 2005, vol. 1, TMS, Warrendale, PA, 2005, pp. 535–44.
A. Clarke, J.G. Speer, D.K. Matlock, F.C. Rizzo, D.V. Edmonds, and K. He: Solid-to-Solid Phase Transformations in Inorganic Materials 2005, vol. 2, TMS, Warrendale, PA, 2005, pp. 99–108.
D. Kalish and M. Cohen: Mater. Sci. Eng., 1970, vol. 6, pp. 156-66.
A.J. Clarke, J.G. Speer, D.K. Matlock, F.C. Rizzo, D.V. Edmonds, and M.J. Santofimia: Scripta Mater., 2009, vol. 61, pp. 149-52.
M.J. Santofimia, L. Zhao, and J. Sietsma: Scripta Mater., 2008, vol. 59, pp. 159-62.
M.J. Santofimia, L. Zhao, and J. Sietsma: Metall. Mater. Trans. A, DOI:10.1007/s11661-011-0706-z.
G.R. Purdy: Personal communication, May 11, 2011.
Y. Cao, F. Ernst, and G.M. Michal: Acta Mater., 2003, vol. 51, pp. 4171-81.
T.D. Bigg, D.K. Matlock, J.G. Speer, and D.V. Edmonds: Solid State Phenom., 2011, vols. 172-4, pp. 827-32.
D.V. Edmonds, D.K. Matlock, and J.G. Speer: Proc. 1st Int. Conf. Advanced Steels, Metallurgical Industry Press, Beijing, China, 2010, pp. 229-41.
H.J. Stone, M.J. Peet, H.K.D.H. Bhadeshia, P.J. Withers, S.S. Babu, and E.D. Specht: Proc. R. Soc. A, 2008, vol. 464, pp. 1009-27.
F. Danoix: unpublished research, Universite de Rouen, 2011.
E. De Moor, C. Föjer, J. Penning, A.J. Clarke, and J.G. Speer: Phys. Rev. B, 2010, vol. 82, pp. 104210-1-5.
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The authors gratefully acknowledge the sponsors of the Advanced Steel Processing and Products Research Center, an industry/university cooperative research center at the Colorado School of Mines, and the National Science Foundation through award number CMMI-0729114.
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Manuscript submitted February 16, 2011.
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Speer, J.G., De Moor, E., Findley, K.O. et al. Analysis of Microstructure Evolution in Quenching and Partitioning Automotive Sheet Steel. Metall Mater Trans A 42, 3591–3601 (2011). https://doi.org/10.1007/s11661-011-0869-7
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DOI: https://doi.org/10.1007/s11661-011-0869-7