Abstract
The effects of thermal aging on the microstructure and mechanical behavior of dual-phase, precipitation-hardened, powder metallurgy (PM) stainless steels of varying ferrite–martensite content were examined. Quantitative analyses of the inherent porosity and phase fractions were conducted on the steels, and no significant differences were noted with respect to aging temperature. Tensile strength, yield strength, and elongation to fracture all increased with increasing aging temperature reaching maxima at 811 K (538 °C) in most cases. Increased strength and decreased ductility were observed in steels of higher martensite content. Nanoindentation of the individual microconstituents was employed to obtain a fundamental understanding of the strengthening contributions. Both the ferrite and martensite nanohardness values increased with aging temperature and exhibited similar maxima to the bulk tensile properties.
Similar content being viewed by others
References
Introducing Powder Metallurgy (PM): www.mpif.org.
R.J. Boucier, D.A. Koss, R.E. Smelser, and O. Richmond: Acta Metall., 1986, vol. 34, no. 12, pp. 2443-53.
G. Straffelini: Powder Metall., 2005, vol. 48, no. 2, pp. 189-92.
J. Holmes and R.A. Queeney: Powder Metall., 1985, vol. 28, p. 231.
H.E. Exner and D. Pohl: Powder Metall., 1978, vol. 10, pp. 193-96.
X. Deng, G.B. Piotrowski, J.J. Williams, and N. Chawla: Int. J. Fatigue, 2005, vol. 27, pp. 1233-43.
A. Hadrboletz and B. Weiss: Int. Mater. Rev., 1997, vol. 42, pp. 1-44.
S.J. Polasik, J.J. Williams, and N. Chawla: Metall. Mater. Trans. A, 2002, vol. 33A, p. 73.
C.T. Schade, T.F. Murphy, A. Lawley, and R. Doherty: Int. J. Powder. Metall., 2009, vol. 45, no. 1, pp. 38-46.
H.J. Klaar, I.A. El-Sesy, and A.H.A. Hussein: Steel Res., 1990, vol. 61, no. 2, pp. 85-92.
B. Grushko and B.Z. Weiss: Scripta Metall., 1989, vol. 23, pp. 865-70.
D.K. Matlock, G. Krauss, L. Ramos, and G.S. Huppi: Structure and Properties of Dual-Phase Steels, American Institute of Mining, Metallurgical, and Petroleum Engineers, Littleton, CO, 1979, pp. 62-90.
M. Erdogan and R. Priestner: Mater. Sci. Technol., 1999, vol. 15, pp. 1273-84.
M.S. Rashid: Ann. Rev. Mater. Sci., 1981, vol. 11, pp. 245-66.
I. Tamura, Y. Tomata, A. Okao, Y. Yamaoha, H. Ozawa, and S. Kaotoni: Trans ISIJ, 1973, vol. 13, pp. 283-92.
G.R. Speich and R.L. Miller: Structure and Properties of Dual-Phase Steels, American Institute of Mining, Metallurgical, and Petroleum Engineers, Littleton, CO, 1979, pp. 145-82.
S. Gunduz, B. Demir, and R. Kacar: Ironmaking Steelmaking, 2008, vol. 35, no. 1, pp. 63-68.
Z. Jiang, Z. Guan, and J. Lian: Mater. Sci. Eng. A, 1995, vol. 190, pp. 55-64.
A. Gural, S. Tekeli, and T. Ando: J. Mater. Sci., 2006, vol. 41, pp. 7894-901.
M. Sarwar and R. Priestner: J. Mater. Sci., 1996, vol. 31, pp. 2091-95.
A. Bag, K.K. Ray, and E.S. Dwarakadasa: Metall. Mater. Trans. A, 1999, vol. 30A, pp. 1193-1202.
P.H. Chang and A.G. Preban: Acta Metall., 1985, vol. 35, no. 5, pp. 897-903.
K. Kocatepe, M. Cerah, and M. Erdogan: J. Mater. Process. Technol., 2006, vol. 178, pp. 44-51.
S.K. Ghosh, A. Haldar, and P.P. Chattopadhyay: J. Mater. Sci., 2009, vol. 44, pp. 580-90.
C.N. Hsaio, C.S. Chiou, and J.R. Yang: Mater. Chem. Phys., 2002, vol. 74, pp. 134-42.
S.K. Dhua, A. Ray, and D.S. Sarma: Mater. Sci. Eng. A, 2001, vol. 318, pp. 197-210.
T. Ohmura, K. Sawada, K. Kimura, and K. Tsuzaki: Mater. Sci. Eng. A, 2008, vol. 489, pp. 85-92.
L. Pussegoda and W.R. Tyson: Can. Metall. Q., 23, 1984, pp. 341–47.
J. Moon, S. Kim, J. Jang, J. Lee, and C. Lee: Mater. Sci. Eng. A, 2008, vol. 487, pp. 552-57.
M. Delince, P.J. Jacques, and T. Pardoen: Acta Mater., 2006, vol. 54, pp. 3395-404.
T. Ohmura, K. Tsuzaki, and S. Matsuoka: Scripta Mater., 2001, vol. 45, pp. 889-94.
Y. Choi, W.Y. Choo, and D. Kwon: Scripta Mater., 2001, vol. 45, pp. 1401-06.
T.H. Ahn, K.K. Um, J.K. Choi, D.H. Kim, K.H. Oh, M. Kim, and H.N. Han: Mater. Sci. Eng. A, 2009, vol. 523, pp. 173-77.
J. Jang: J. Mater. Res., 2007, vol. 22, no. 1, pp. 175-85.
T. Ohmura and K. Tsuzaki: J. Phys. D: Appl. Phys., 2008, vol. 41, pp. 1-6.
T.B. Britton, D. Randman, and A.J. Wilkinson: J. Mater. Res., 2009, vol. 24, no. 3, pp. 607-15.
T. Ohmura, T. Hara, and K. Tsuzaki: Scripta Mater., 2003, vol. 49, pp. 1157-62.
T. Ohmura, K. Tsuzaki, and S. Matsuoka: Phil. Mag. A, 2002, vol. 82, pp. 1903-10.
V.H.B. Hernandez, S.K. Panda, Y. Okita, and N.Y. Zhou: J. Mater. Sci., 2010, vol. 45, pp. 1638-47.
V.H.B. Hernandez, S.K. Panda, M.L Kuntz, and Y. Zhou: Mater. Lett., 2010, vol. 64, pp. 207-10.
G.F. Vander Voort, G.M. Lucas, and E.P. Manilova: Metallography and Microstructures of Stainless Steels and Maraging Steels, ASM Handbook 9, 2004, pp. 670–700.
W.C. Oliver and G.M. Pharr: J. Mater. Res., 1992, vol. 7, p. 1564.
N. Chawla and X. Deng: Mater. Sci. Eng. A, 2005, vol. 390, pp. 98-112.
K.M. Vedula and R.W. Heckel: Modern Developments in Powder Metallurgy, Metal Powder Industries Federation, Princeton, NJ, 1981.
R.E. Reed-Hill and R. Abbaschian: Physical Metallurgy Principles, 3rd ed. PWS Publishing Company, Boston, MA, 1994.
T. Marcu, A. Molinari, G. Straffelini, and S. Berg: Int. J. Powder Metall., 2004, vol. 40, no. 3, pp. 57-64.
W.A. Spitzig, R.E. Smelser, and O. Richmond: Acta Metall., 1988, vol. 36, no. 5, pp. 1201-11.
A. Salak: Ferrous Powder Metallurgy, Cambridge International Science Publishing, Cambridge, UK, 1997.
N. Chawla, F. Ochoa, V.V. Ganesh, and X. Deng: J. Mater. Sci. Mater. Electron., 2004, vol. 15, pp. 385-88.
N. Ramakrishnan and V.S. Arunachalam: J. Am. Ceram. Soc., 1993, vol. 76, pp. 2745.
Q. Furnemont, M. Kempf, P.J. Jacques, M. Goken, and F. Delannay: Mater. Sci. Eng. A, 2002, vol. 328, pp. 26-32.
P. Abramowitz and R.A. Moll: Metall. Trans., 1970, vol. 1, pp. 1773-75.
M. Mazinani and W.J. Poole: Metall. Mater. Trans. A, 2007, vol. 38A, pp. 328-39.
K.K. Chawla, P.R. Rios, and J.R.C. Guimaraes: J. Mater. Sci. Lett., 1983, vol. 2, pp. 94-98.
H.P. Shen, T.C. Lei, and J.Z. Liu: Mater. Sci. Technol., 1987, vol. 3, pp. 415-21.
F.M. Al-Abbasi and J.A. Nemes: Int. J. Mech. Sci., 2003, vol. 45, pp. 1449-65.
E. Maire, O. Bouaziz, M. Di Michiel, and C. Verdu: Acta Mater., 2008, vol. 56, pp. 4954-64.
X. Sun, K.S. Choi, W.N. Liu, and M.A. Khaleel: Int. J. Plast., 2009, vol. 25, pp. 1888-1909.
R.K. Ray: Scripta Metall., 1984, vol. 18, pp. 1205-09.
Acknowledgments
The authors acknowledge the Hoeganaes Corporation for providing the materials and financial support for this research. We would also like to thank C. Schade and T. Murphy for stimulating discussions related to this work.
Author information
Authors and Affiliations
Corresponding author
Additional information
Manuscript submitted April 8, 2011.
Rights and permissions
About this article
Cite this article
Stewart, J.L., Williams, J.J. & Chawla, N. Influence of Thermal Aging on the Microstructure and Mechanical Behavior of Dual-Phase, Precipitation-Hardened, Powder Metallurgy Stainless Steels. Metall Mater Trans A 43, 124–135 (2012). https://doi.org/10.1007/s11661-011-0844-3
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11661-011-0844-3