Abstract
A compositionally and structurally heterogeneous model for ferromagnetic alloys has been developed and applied to Fe-Ga alloys that exhibit giant magnetostriction. Our model assumes that the Fe-Ga bcc solid solution near its solubility limit is a coarsening-resistant nanodispersion of a DO3 phase that is formed due to coherency lifting by excess vacancies, as is known to be the case for chemically similar Fe-Al alloys. This compositionally heterogeneous state undergoes a cubic → tetragonal displacive transformation that brings the structure closer to an equilibrium fcc-based L12 ordered phase. The predictions of our theory are in agreement with existing electron microscopy and X-ray diffraction observations.
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Acknowledgments
This work was supported by the Office of Naval Research through Grant Nos. MURI N00014-06-1-0530 and N00014-06-1-0204 (DV). One of the authors (AGK) is also grateful for the support under NSF Grant No. DMR-0242619.
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Manuscript submitted January 10, 2007.
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Khachaturyan, A., Viehland, D. Structurally Heterogeneous Model of Extrinsic Magnetostriction for Fe-Ga and Similar Magnetic Alloys: Part I. Decomposition and Confined Displacive Transformation. Metall Mater Trans A 38, 2308–2316 (2007). https://doi.org/10.1007/s11661-007-9253-z
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DOI: https://doi.org/10.1007/s11661-007-9253-z