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Distribution of rare earth elements of granitic regolith under the influence of climate

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Abstract

The distribution and anomalies of rare earth elements (REEs) of granitic regolith were studied in Inner Mongolia and Hainan Island, China. One profile showed slight REE enrichment of an upper layer and no obvious light REE/heavy REE (LREE/HREE) fractionation (LaN/YbN of 0.9). The second profile was significantly enriched in REEs and enriched in LREEs in the upper portion (LaN/YbN > 1.8). Eu, Ce, and Gd anomalies of the two profiles are different. Slightly negative Eu, Ce, and Gd anomalies in NMG-3-1 indicate slow dissolution of primary minerals and little secondary products; in contrast, a positive Eu anomaly in HN-2 suggests the vegetation cycle may contribute to soil. The Ce anomaly of HN-2 reflects oxidation of Ce and coprecipitation by Fe- and Mn-oxides and organic matter. Correlation between Ce and Gd anomalies in HN-2 suggests Ce and Gd are both influenced by redox-reduction.

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References

  • Aubert D, Stille P, Probst A (2001) REE fractionation during granite weathering and removal by waters and suspended loads: Sr and Nd isotopic evidence. Geochim Cosmochim Acta 65:387–406. doi:10.1016/S0016-7037(00)00546-9

    Article  Google Scholar 

  • Aubert D, Stille P, Probst A, Gauthier-lafaye F, Pourcelot L, Del Nero M (2002) Characterization and migration of atmospheric REE in soils and surface waters. Geochim Cosmochim Acta 66:3339–3350. doi:10.1016/S0016-7037(02)00913-4

    Article  Google Scholar 

  • Babechuk MG, Widdowson M, Kamber BS (2014) Quantifying chemical weathering intensity and trace element release from two contrasting basalt profiles, Deccan Traps, India. Chem Geol 363:56–75. doi:10.1016/j.chemgeo.2013.10.027

    Article  Google Scholar 

  • Bao ZW, Zhao ZH (2008) Geochemistry of mineralization with exchangeable REY in the weathering crusts of granitic rocks in South China. Ore Geol Rev 33:519–535. doi:10.1016/j.oregeorev.2007.03.005

    Article  Google Scholar 

  • Brioschi L, Steinmann M, Lucot E, Pierret MC, Stille P, Prunier J, Badot PM (2013) Transfer of rare earth elements (REE) from natural soil to plant systems: implications for the environmental availability of anthropogenic REE. Plant Soil 366:143–163. doi:10.1007/s11104-012-1407-0

    Article  Google Scholar 

  • Henderson P (1984) General geochemical properties and abundances of the rare earth elements. In: Henderson P (ed) Rare earth element geochemistry: developments in geochemistry, vol 2. Elsevier Science Publishers, Amsterdam

    Google Scholar 

  • Laveuf C, Cornu S (2009) A review on the potentiality of rare earth elements to trace pedogenetic processes. Geoderma 154:1–12. doi:10.1016/j.geoderma.2009.10.002

    Article  Google Scholar 

  • Ma J-L, Wei G-J, Xu Y-G, Long W-G, Sun W-D (2007) Mobilization and re-distribution of major and trace elements during extreme weathering of basalt in Hainan Island, South China. Geochim Cosmochim Acta 71:3223–3237. doi:10.1016/j.gca.2007.03.035

    Article  Google Scholar 

  • Möller P, Knappe A, Dulski P (2014) Seasonal variations of rare earths and yttrium distribution in the lowland Havel River, Germany, by agricultural fertilization and effluents of sewage treatment plants. Appl Geochem 41:62–72. doi:10.1016/j.apgeochem.2013.11.011

    Article  Google Scholar 

  • Rudnick RL, Gao S (2003) Composition of the continental crust. In: Holland HD, Turekian KK (eds) Treatise on geochemistry, vol 3. Pergamon, Oxford, pp 1–64. doi:10.1016/B0-08-043751-6/03016-4

    Chapter  Google Scholar 

  • Vazquez-Ortega A, Perdrial J, Harpold A, Zapata-Rios X, Rasmussen C, McIntosh J, Schaap M, Pelletier JD, Brooks PD, Amistadi MK, Chorover J (2015) Rare earth elements as reactive tracers of biogeochemical weathering in forested rhyolitic terrain. Chem Geol 391:19–32. doi:10.1016/j.chemgeo.2014.10.016

    Article  Google Scholar 

  • Vermeire M-L, Cornu S, Fekiacova Z, Detienne M, Delvaux B, Cornélis J-T (2016) Rare earth elements dynamics along pedogenesis in a chronosequence of podzolic soils. Chem Geol 446:163–174. doi:10.1016/j.chemgeo.2016.06.008

    Article  Google Scholar 

  • Yusoff ZM, Ngwenya BT, Parsons I (2013) Mobility and fractionation of REEs during deep weathering of geochemically contrasting granites in a tropical setting, Malaysia. Chem Geol 349–350:71–86. doi:10.1016/j.chemgeo.2013.04.016

    Article  Google Scholar 

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Acknowledgments

This work was jointly supported by the National Natural Science Foundation of China (Grant No. 41210004; 41661144042) and National Basic Research Program (973 project) of China (2013CB956401).

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Correspondence to Congqiang Liu or Zhiqi Zhao.

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11th International Symposium on Geochemistry of the Earth’s Surface.

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Mao, H., Liu, C., Zhao, Z. et al. Distribution of rare earth elements of granitic regolith under the influence of climate. Acta Geochim 36, 440–445 (2017). https://doi.org/10.1007/s11631-017-0186-y

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  • DOI: https://doi.org/10.1007/s11631-017-0186-y

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