Skip to main content

Advertisement

Log in

Experiment Study on the High-Temperature Thermal Treatment and Ultra-Low NOx Control of Solid Waste Coal Slime in Circulating Fluidized Bed

  • Published:
Journal of Thermal Science Aims and scope Submit manuscript

Abstract

Coal slime is a kind of solid waste and inferior fuel, which is urgently needed to utilize. In this paper, a high-temperature thermal treatment of coal slime in a circulating fluidized bed (CFB) was attempted to achieve resource utilization. In the experiment, the combustion characteristics of dried coal slime during high-temperature thermal treatment were investigated in a 0.5 MW pilot-scale CFB. The stable fluidized combustion of dried coal slime was realized. When the excess air ratio was closer to 1.0, the furnace temperatures would be uniform. The ignition method of dried coal slime was changed correspondingly while the feeding position changed. However, feeding coal slime to the loop seal was instrumental in decreasing NOx emissions. Moreover, the NOx emissions were tried to further control by the post-combustion technology. Post-combustion technology could significantly reduce NOx emissions below 50 mg·Nm3 while ensuring combustion efficiency. Besides, it was found that there was an optimum excess air ratio in CFB of about 0.9 resulting in minimum NOx emissions of coal slime. The experiment results could well guide the industrial-scale high temperature thermal treatment of coal slime.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Guerrero L.A., Maas G., Hogland W., Solid waste management challenges for cities in developing countries. Waste Management, 2013, 33(1): 220–232.

    Article  Google Scholar 

  2. Kelessidis A., Stasinakis A.S., Comparative study of the methods used for treatment and final disposal of sewage sludge in European countries. Waste Management, 2012, 32(6):1186–1195.

    Article  Google Scholar 

  3. Gui X., Liu J., Cao Y., et al., Coal preparation technology: status and development in China. Energy and Environment, 2015, 26 (6–7): 997–1013.

    Article  Google Scholar 

  4. Si Y., Du M., Research progress of slime utilization. Guangdong Chemical Industry, 2017, 44(4): 79–80.

    Google Scholar 

  5. Zhang Y., Zhao J., Ma Z., et al., Effect of oxygen concentration on oxy-fuel combustion characteristic and interactions of coal gangue and pine sawdust. Waste Management, 2019, 87: 288–294.

    Article  Google Scholar 

  6. Wang H., Liu S., Li X., et al., Morphological and structural evolution of bituminous coal slime particles during the process of combustion. Fuel, 2018, 218: 49–58.

    Article  Google Scholar 

  7. Song Z., Jing C., Yao L., et al., Microwave drying performance of single-particle coal slime and energy consumption analyses. Fuel Processing Technology, 2016, 143: 69–78.

    Article  Google Scholar 

  8. Song Z., Jing C., Yao L., et al., Coal slime hot air/microwave combined drying characteristics and energy analysis. Fuel Processing Technology, 2016, 156: 491–499.

    Article  Google Scholar 

  9. Song S., Yang Z., Na Y., et al., Investigation on the operating characteristics of a 350 MWe supercritical CFB boiler with a polygonal furnace. Applied Thermal Engineering, 2019, 156: 178–188.

    Article  Google Scholar 

  10. Zhang W., Liu J., Gao M., et al., A novel operation cost optimization system for mix-burning coal slime circulating fluidized bed boiler unit. Applied Thermal Engineering, 2019, 148: 620–631.

    Article  Google Scholar 

  11. Cliffe K.R., Patumsawad S., Co-combustion of waste from olive oil production with coal in a fluidised bed. Waste Management, 2001, 21(1): 49–53.

    Article  Google Scholar 

  12. Gong Z., Liu Z., Zhou T., et al., Combustion and NO emission of shenmu char in a 2 MW circulating fluidized bed. Energy & Fuels, 2015, 29(2): 1219–1226.

    Article  Google Scholar 

  13. Shi Y., Ma Y., The present conditions of circulating fluidized bed boiler for using coal slime in China. Applied Energy Technology, 2012, (06): 29–33.

  14. Wu J., Wang B., Cheng F., Thermal and kinetic characteristics of combustion of coal sludge. Journal of Thermal Analysis & Calorimetry, 2017, 129(3): 1899–1909.

    Article  Google Scholar 

  15. Zhou K., Lin Q., Hu H., et al., Ignition and combustion behaviors of single coal slime particles in CO2/O2 atmosphere. Combustion and Flame, 2018, 194: 250–263.

    Article  Google Scholar 

  16. Zhou K., Lin Q., Hu H., et al., The ignition characteristics and combustion processes of the single coal slime particle under different hot-coflow conditions in N2/O2 atmosphere. Energy, 2017, 136: 173–184.

    Article  Google Scholar 

  17. Wang H., Liu S., Wang X.Y., et al., Ignition and combustion behaviors of coal slime in air. Energy & Fuels, 2017, 31(10): 11439–11447.

    Article  Google Scholar 

  18. Yin W., Li B., Wu Y., et al., Model of coal slime combustion behavior in CFB boiler. MeitanXuebao/Journal of the China Coal Society, 2015, 40(7): 1628–1633.

    Google Scholar 

  19. Ministry of Environmental Protection of People’s Republic of China Emission standard of air pollutants for thermal power plants (GB 13223-2011), 2011.

  20. Neuwahl F., Cusano G., Benavides J., et al., Best available techniques (BAT) reference document for waste incineration: industrial emissions directive 2010/75/EU (Integrated Pollution Prevention and Control). 2019.

  21. Hou Z., Xiao K., Yu Z., et al., Study on NOx emission characteristics in coal slime circulating fluidized bed boiler. Journal of Engineering for Thermal Energy & Power, 2017, 2(11): 68–72.

    Google Scholar 

  22. Gong Z., Zhou T., Lu Q., et al., Combustion and NOx emission characteristics of shenmu char in a circulating fluidized bed with post-combustion. Energy & Fuels, 2016, 30(1): 31–38.

    Article  Google Scholar 

  23. Zhou T., Gong Z., Lu Q., et al., Experimental study on enhanced control of NOx emission from circulating fluidized bed combustion. Energy & Fuels, 2015, 29(6): 3634–3639.

    Article  Google Scholar 

  24. Zhou T., Lu Q., Cao Y., et al., Study on the combustion and NOx emission characteristics of low rank coal in a circulating fluidized bed with post-combustion. Canadian Journal of Chemical Engineering, 2017, 95(12): 2333–2340.

    Article  Google Scholar 

  25. Song G., Xiao Y., Yang Z., et al., A comparative study on characteristics of ultra-low NOx emission and fly ash between Fugu bituminous and its semi-coke with post-combustion. Fuel Processing Technology, 2021, 211: 106618.

    Article  Google Scholar 

  26. Ponzio A., Senthoorselvan S., Yang W., et al., Ignition of single coal particles in high-temperature oxidizers with various oxygen concentrations. Fuel, 2008, 87(6): 974–987.

    Article  Google Scholar 

  27. Khatami R., Stivers C., Levendis Y., Ignition characteristics of single coal particles from three different ranks in O2/N2 and O2/CO2 atmospheres. Combustion & Flame, 2012, 159(12): 3554–3568.

    Article  Google Scholar 

  28. Riaza J., Khatami R., Levendis Y., et al., Single particle ignition and combustion of anthracite, semi-anthracite and bituminous coals in air and simulated oxy-fuel conditions. Combustion & Flame, 2014, 161(4): 1096–1108.

    Article  Google Scholar 

  29. Johnsson J.E., Formation and reduction of nitrogen oxides in fluidized-bed combustion. Fuel, 1994, 73: 1398–1415.

    Article  Google Scholar 

  30. Furusawa T., Tsunoda M., Tsujimura M., et al., Nitric oxide reduction by char and carbon monoxide: fundamental kinetics of nitric oxide reduction in fluidized bed combustion of coal. Fuel, 1985, 64(9): 1306–1309.

    Article  Google Scholar 

  31. Hayhurst A., Lawrence A., The amounts of NOx and N2O formed in a fluidized bed combustor during the burning of coal volatiles and also of char. Combustion & Flame, 1996, 105(3): 341–357

    Article  Google Scholar 

  32. Schönenbeck C., Gadiou R., Schwartz D., A kinetic study of the high temperature NO-char reaction. Fuel, 2004, 83(4–5): 443–450.

    Article  Google Scholar 

  33. He J., Song W., Gao S., et al., Experimental study of the reduction mechanisms of NO emission in decoupling combustion of coal. Fuel Processing Technology, 2006, 87(9): 803–810.

    Article  Google Scholar 

  34. Xu M., Li S., Wu Y., et al., Reduction of recycled NO over char during oxy-fuel fluidized bed combustion: Effects of operating parameters. Applied Energy, 2017, 199: 310–322.

    Article  Google Scholar 

  35. Xu M., Li S., Wu Y., et al., The characteristics of recycled NO reduction over char during oxy-fuelfluidized bed combustion. Applied Energy, 2017, 190: 553–562.

    Article  Google Scholar 

  36. Marek W., Pels J., Moulijn J., The fate of nitrogen functionalities in coal during pyrolysis and combustion. Fuel, 1995, 74(4): 507–516.

    Article  Google Scholar 

  37. Gong B., Buckley A., Lamb R., et al., XPS determination of the forms of nitrogen in coal pyrolysis chars. Surface and Interface Analysis, 1999, 28(1): 126–130.

    Article  Google Scholar 

  38. Pietrzak R., XPS study and physico-chemical properties of nitrogen-enriched microporous activated carbon from high volatile bituminous coal. Fuel, 2009, 88(10): 1871–1877.

    Article  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the National Key Research & Development Program of China (Grant No. 2018YFB0605002) and “Transformational Technologies for Clean Energy and Demonstration”, Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDA21040100).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Guoliang Song.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Song, G., Xiao, Y., Yang, Z. et al. Experiment Study on the High-Temperature Thermal Treatment and Ultra-Low NOx Control of Solid Waste Coal Slime in Circulating Fluidized Bed. J. Therm. Sci. 31, 2244–2251 (2022). https://doi.org/10.1007/s11630-022-1644-3

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11630-022-1644-3

Keywords

Navigation