Skip to main content
Log in

Comparative Study of Structure and Property Changes in Corrosive Media for Self-cleaning Superhydrophobic Magnesium Alloys

  • Metallic materials
  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

Magnesium alloys with superhydrophobicity are constructed by controlling rough surface structure and grafting long hydrophobic alkyl chains. Changes of morphology, phase structure, chemical composition as well as wettability, corrosion resistance of superhydrophobic magnesium alloy upon immersing in corrosive media are investigated comparatively. Meanwhile, the contaminating particles on as-prepared superhydrophobic surfaces can be taken away easily by rolling water droplets. Therefore, the results show that as-prepared superhydrophobic magnesium alloys exhibit enhanced corrosion resistance and self-healing performance. Finally, anti-corrosion and self-cleaning mechanisms are deduced. It can be concluded that it is an effective strategy of preparing superhydrophobic surfaces for improving the corrosion resistance and selfcleaning performance of magnesium alloys.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Rehman Z, Ahn B, Song J, et al. Effect of Na2SiF6 Concentration on the Plasma Electrolytic Oxidation of AZ31B Magnesium Alloy[J]. Int. J. Surf. Sci. Eng., 2016, 10(5): 456

    Article  Google Scholar 

  2. Feng LB, Zhu YL, Fan WB, et al. Fabrication and Corrosion Resistance of Superhydrophobic Magnesium Alloy[J]. Appl. Phys. A, 2015, 120(2): 561–570

    Article  Google Scholar 

  3. Bai Y, Wei R, Le Q, Zhang H. Effect of Start–up Levels on the Stressstrain Field and Cracking Tendency During Direct–chill Casting of Magnesium Aalloy AZ80[J]. Adv. Eng. Mater., 2016, 18(9): 1 600–1 608

    Article  Google Scholar 

  4. Li W, Kang ZX. Fabrication of Corrosion Resistant Superhydrophobic Surface with Self–cleaning Property on Magnesium Alloy and its Mechanical Stability[J]. Surf. Coat. Tech., 2014, 253: 205–213

    Article  Google Scholar 

  5. Cui XJ, Liu XZ, Liu CH, et al. Fabrication and Corrosion Resistance of a Hhydrophobic Micro–arc Oxidation Coating on AZ31 Mg Alloy[J]. Corros. Sci., 2015, 90: 402–412

    Article  Google Scholar 

  6. Jia J, Fan JF, Xu BS, et al. Microstructure and Properties of the Super–hydrophobic Films Fabricated on Magnesium Alloys[J]. J. Alloy. Comp., 2013, 554: 142–146

    Article  Google Scholar 

  7. Liu HX, Xu Q, Xiong DM, et al. Microstructure and Corrosion Resistance of AZ91D Magnesium Mlloy Treated by Hybrid Ion Implantation and Heat Treatment[J]. Vacuum., 2013, 89: 233–237

    Article  Google Scholar 

  8. She ZX, Li Q, Wang ZW, et al. Researching the Fabrication of Anticorrosion Superhydrophobic Surface on Magnesium Alloy and its Mechanical Stability and Durability[J]. Chem. Eng. J., 2013, 228: 415–424

    Article  Google Scholar 

  9. Chen KL, Zhou SX, Wu LM. Facile Fabrication of Self–repairing Superhydrophobic Coatings[J]. Chem. Commun., 2014, 50(80): 11 891–11 894

    Article  Google Scholar 

  10. Zhang F, Zhang CL, Song L, et al. Fabrication of the Superhydrophobic Surface on Magnesium Alloy and its Corrosion Resistance[J]. J. Mater. Sci. Technol., 2015, 31(11): 1 139–1 143

    Article  Google Scholar 

  11. Zhang JL, Gu CD, Tong YY, et al. A Smart Superhydrophobic Coating on AZ31B Magnesium Alloy with Self–healing Effect[J]. Adv. Mater. Interfaces, 2016, 3(14): 1 500 694

    Google Scholar 

  12. Nystrom D, Lindqvist J, Ostmark E, et al. Superhydrophobic and Self–cleaning Bio–fiber Surfaces via ATRP and Subsequent Post Functionalization[ J]. ACS. Appl. Mater. Inter., 2009, 1(4): 816–823

    Article  Google Scholar 

  13. Jung S, Dorrestijn M, Raps D, et al. Are Superhydrophobic Surfaces Best for Icephobicity[J]? Langmuir, 2011, 27(6): 3 059–3 066

    Article  Google Scholar 

  14. Wang ZW, Su YL, Li Q, et al. Researching a Highly Anti–corrosion Superhydrophobic Film Fabricated on AZ91D Magnesium Aalloy and its Anti–bacteria Adhesion Effect[J]. Mater. Charact., 2015, 99: 200–209

    Article  Google Scholar 

  15. Wang P, Zhang D, Qiu R, et al. Green Approach to Fabrication of a Super–hydrophobic Film on Copper and the Consequent Corrosion Resistance[ J]. Corros. Sci., 2014, 80: 366–373

    Article  Google Scholar 

  16. Liu LJ, Xu FY, Ma L. Facile Fabrication of a Superhydrophobic Cu Surface via a Selective Eetching of High–energy Facets[J]. J. Phys. Chem. C., 2012, 116(35): 18 722–18 727

    Article  Google Scholar 

  17. Gao R, Wang J, Zhang XF, et al. Fabrication of Superhydrophobic Magnesium Aalloy through Theoxidation of Hydrogen Peroxide[J]. Colloid. Surf. A., 2013, 436: 906–911

    Article  Google Scholar 

  18. Liu Y, Yin XM, Zhang JJ, et al. A Electro–deposition Process for Fabrication of Biomimetic Ssuperhydrophobic Surface and its Corrosion Resistance on Mmagnesium Alloy[J]. Electrochim. Acta., 2014, 125: 395–403

    Article  Google Scholar 

  19. Ishizaki T, Hieda J, Saito N, et al. Corrosion Resistance and Chemical Stability of Superhydrophobic Film Deposited on Magnesium Alloy AZ31 by Microwave Plasma–enhanced Chemical Vapor Deposition[J]. Electrochim. Acta., 2010, 55(23): 7 094–7 101

    Article  Google Scholar 

  20. Wang SH, Guo XW, Xie YJ, et al. Preparation of Superhydrophobic Silica Silm on Mg–Nd–Zn–Zr Magnesium Alloy with Enhanced Corrosion Resistance by Combining Micro–arc Oxidation and Sol–gel Method[J]. Surf. Coat. Tech., 2012, 213: 192–201

    Article  Google Scholar 

  21. Yuan ZQ, Chen H, Tang JX, et al. Facile Method to Fabricate Stable Superhydrophobic Polystyrene Surface by Adding Ethanol[J]. Surf. Coat. Tech., 2007, 201(16–17): 7 138–7 142

    Google Scholar 

  22. Liu Y, Lu GL, Liu JD, et al. Fabrication of Biomimetic Hydrophobic Films with Corrosion Resistance on Magnesium Alloy by Immersion Process[J]. Appl. Surf. Sci., 2013, 264: 527–532

    Article  Google Scholar 

  23. Ishizaki T, Sakamoto M. Facile Formation of Biomimetic Color–tuned Superhydrophobic Magnesium Alloy with Corrosion Resistance[J]. Langmuir, 2011, 27(6): 2 375–2 381

    Article  Google Scholar 

  24. She ZX, Li Q, Wang ZW, et al. Novel Method for Controllable Fabrication of a Superhydrophobic CuO Surface on AZ91D Magnesium Alloy[J]. ACS. Appl. Mater. Inter., 2012, 4(8): 4 348–4 356

    Article  Google Scholar 

  25. Huang YP, Zhang YF, Yu XQ, et al. Fabrication of Superhydrophobic Surface on Magnesium Alloy and Corrosion Resistance Analysis[J]. J. Southeast University, 2012, 42(5): 915–920

    Google Scholar 

  26. Feng LB, Che YH, Liu YHXH, et al. Fabrication of Superhydrophobic Aluminium Alloy Surface with Excellent Corrosion Resistance by a Facile and Environment–friendly Method[J]. Appl. Surf. Sci., 2013, 283: 367–374

    Article  Google Scholar 

  27. Liang CH, Wang SS, Huang NB, et al. Effects of Lanthanum and Cerium Mixed Rare Earth Metal on Abrasion and Corrosion Resistance of AM60 Magnesium Alloy[J]. Rare. Metal. Mat. Eng., 2015, 44(3): 521–526

    Article  Google Scholar 

  28. Brady MP, Rother G, Anovitz LM, et al. Film Breakdown and Nano–porous Mg(OH)2 Formation from Corrosion of Magnesium Alloys in Salt Solutions[J]. J. Electrochem. Soc., 2015, 162(4): C140–C149

    Google Scholar 

  29. Li JH, Liu Q, Wang YL, et al. Formation of a Corrosion–resistant and Anti–icing Superhydrophobic Surface on Magnesium Alloy via a Single–step Method[J]. J. Electrochem. Soc., 2016, 163(5): C213–C220

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Libang Feng  (冯利邦).

Additional information

Funded by the National Natural Science Foundation of China (No. 21161012)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shi, X., Zhu, Y., Liu, Y. et al. Comparative Study of Structure and Property Changes in Corrosive Media for Self-cleaning Superhydrophobic Magnesium Alloys. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 34, 410–416 (2019). https://doi.org/10.1007/s11595-019-2067-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-019-2067-1

Key words

Navigation